Taking into account water use impacts in the LCA of biofuels: an Argentinean case study

Purpose  

The assessment of biofuels has until now mainly focused on energy demand and greenhouse gas emissions. Only little attention has been given to other impacts, although the general importance of water use for the life cycle assessment (LCA) of agricultural products has been recognized in recent publications. The aim of this work is to assess in detail the water consumption along a biofuel production chain taking into account irrigation efficiencies, levels of water scarcity, and type of feedstock, and to integrate those results in a full LCA. Furthermore, we compare the results for biofuels from various feedstocks and regions with conventional petrol.     

Assessing environmental impacts associated with freshwater consumption along the life cycle of animal products: the case of Dutch milk production in Noord-Brabant

Purpose

The assessment of water footprints of a wide range of products has increased awareness on preserving freshwater as a resource. The water footprint of a product was originally defined by Hoekstra and Hung (2002) as the sum of the volumetric water use in terms of green, blue and grey water along the entire life cycle of a product and, as such, does not determine the environmental impact associated with freshwater use. Recently, several papers were published that describe building blocks that enable assessment of the site-specific environmental impact associated with freshwater use along the life cycle of a global food chain, such as the impact on human health (HH), ecosystem quality (EQ) or resource depletion (RD). We integrated this knowledge to enable an assessment of the environmental impact associated with freshwater use along the life cycle of milk production, as a case for a global food chain.

Material and methods

Our approach innovatively combined knowledge about the main impact pathways of freshwater use in life cycle assessment (LCA), knowledge about site-specific freshwater impacts and knowledge about modelling of irrigation requirements of global feed crops to assess freshwater impacts along the life cycle of milk production. We evaluated a Dutch model farm situated on loamy sand in the province of Noord-Brabant, where grass and maize land is commonly irrigated.

Results and discussion

Production of 1 kg of fat-and-protein corrected milk (FPCM) on the model farm in Noord-Brabant required 66 L of consumptive water. About 76 % of this water was used for irrigation during roughage cultivation, 15 % for production of concentrates and 8 % for drinking and cleaning services. Consumptive water use related to production of purchased diesel, gas, electricity and fertiliser was negligible (i.e. total 1 %). Production of 1 kg of FPCM resulted in an impact on HH of 0.8?×?10^?9 disability adjusted life years, on EQ of 12.9?×?10^?3 m²?×?year and on RD of 6.7 kJ. The impact of producing this kilogram of FPCM on RD, for example, was caused mainly by cultivation of concentrate ingredients, and appeared lower than the average impact on RD of production of 1 kg of broccoli in Spain.

Conclusions

Integration of existing knowledge from diverse science fields enabled an assessment of freshwater impacts along the life cycle of a global food chain, such as Dutch milk production, and appeared useful to determine its environmental hotspots. Results from this case study support earlier findings that LCA needs to go beyond simple water volume accounting when the focus is on freshwater scarcity. The approach used, however, required high-resolution inventory global data (i.e. especially regarding crop yield, soil type and root depth), and demonstrated a trade-off between scientific quality of results and applicability of the assessment method.     

Land use impacts on biodiversity in LCA: a global approach

Purpose

Land use is a main driver of global biodiversity loss and its environmental relevance is widely recognized in research on life cycle assessment (LCA). The inherent spatial heterogeneity of biodiversity and its non-uniform response to land use requires a regionalized assessment, whereas many LCA applications with globally distributed value chains require a global scale. This paper presents a first approach to quantify land use impacts on biodiversity across different world regions and highlights uncertainties and research needs.

Methods

The study is based on the United Nations Environment Programme (UNEP)/Society of Environmental Toxicology and Chemistry (SETAC) land use assessment framework and focuses on occupation impacts, quantified as a biodiversity damage potential (BDP). Species richness of different land use types was compared to a (semi-)natural regional reference situation to calculate relative changes in species richness. Data on multiple species groups were derived from a global quantitative literature review and national biodiversity monitoring data from Switzerland. Differences across land use types, biogeographic regions (i.e., biomes), species groups and data source were statistically analyzed. For a data subset from the biome (sub-)tropical moist broadleaf forest, different species-based biodiversity indicators were calculated and the results compared.

Results and discussion

An overall negative land use impact was found for all analyzed land use types, but results varied considerably. Different land use impacts across biogeographic regions and taxonomic groups explained some of the variability. The choice of indicator also strongly influenced the results. Relative species richness was less sensitive to land use than indicators that considered similarity of species of the reference and the land use situation. Possible sources of uncertainty, such as choice of indicators and taxonomic groups, land use classification and regionalization are critically discussed and further improvements are suggested. Data on land use impacts were very unevenly distributed across the globe and considerable knowledge gaps on cause–effect chains remain.

Conclusions

The presented approach allows for a first rough quantification of land use impact on biodiversity in LCA on a global scale. As biodiversity is inherently heterogeneous and data availability is limited, uncertainty of the results is considerable. The presented characterization factors for BDP can approximate land use impacts on biodiversity in LCA studies that are not intended to directly support decision-making on land management practices. For such studies, more detailed and site-dependent assessments are required. To assess overall land use impacts, transformation impacts should additionally be quantified. Therefore, more accurate and regionalized data on regeneration times of ecosystems are needed.     

Characterisation of social impacts in LCA. Part 2: implementation in six company case studies

Background, aim and scope

A characterisation model based on multi-criteria indicators has been developed for each of four impact categories representing the labour rights according to the conventions of the International Labour Organisation (ILO) covering: forced labour, discrimination, restrictions of freedom of association and collective bargaining and child labour (Dreyer et al., Int J Life Cycle Assess, 2010a, in press). These impact categories are considered by the authors to be among the obligatory impact categories in a Social LCA. The characterisation models combine information about the way a company manages its behaviour towards some of its important stakeholders, its employees, with information about the geographical location and branch of industry of the company and the risk of violations of these workers' rights inherent in the setting of the company. The result is an indicator score which for each impact category represents the risk that violations occur in the company. In order to test the feasibility and relevance of the developed methodology, it is tested on real cases.

Materials and methods

The developed characterisation models are applied to six cases representing individual manufacturing companies from three different continents. Five of the case companies are manufacturing companies while the sixth is a knowledge company. The application involves scoring the management efforts of the case company in a multi-criteria scorecard and translating the scores into an aggregated performance score, which represents the effort of the management in order to prevent violations of the workers' rights to occur in the company. The company performance score is multiplied by a contextual adjustment score which reflects the risk of violations taking place in the context (in terms of geographical location or industrial branch or sector) of the company. The resulting indicator score represents the risk that violations take place of the labour right represented by the impact category.

Results

The social impact characterisation is performed for each of the six case studies using the methodology earlier developed. The procedure and outcome are documented through all the intermediary results shown for all four obligatory impact categories for each of the six case studies.

Discussion

The results are judged against the risk which was observed during visits and interviews at each of the six case companies, and their realism and relevance are discussed. They are found to be satisfactory for all four impact categories for the manufacturing companies, but there are some problems for two of the impact categories in the case company which represents knowledge work, and it is discussed how these problems may be addressed through change of the underlying scorecard or the way in which the scoring is translated into a company performance score.

Conclusions

It is concluded that it is feasible to perform a characterisation of the impacts related to the four obligatory impact categories representing the labour rights according to the conventions of the ILO covering: forced labour, discrimination, restrictions of freedom of association and collective bargaining and child labour. When compared with the observed situation in the companies, the results are also found to be relevant and realistic.

Recommendations and perspectives

The proposed characterisation method is rather time-consuming and cannot realistically be applied to all companies in the product system. It must therefore be combined with less time-requiring screening methods which can help identify the key companies in the life cycle for which a detailed analysis is required. The possibility to apply country- or industry sector-based information is discussed, and while it is found useful to identify low-risk companies and eliminate them from more detailed studies, the ability of the screening methods to discriminate between companies located in medium and high-risk contexts is questionable.     

Assessing freshwater ecotoxicity of agricultural products in life cycle assessment (LCA): a case study of wheat using French agricultural practices databases and USEtox model

Purpose  

A life cycle assessment (LCA) was conducted on winter wheat, based on real agricultural practices databases, on a sample divided into four production scenarios. The main objectives of this study are (1) to assess the environmental impact of winter wheat, using an LCA covering field practices, and the transport and storage of grain until it is sold to a miller; (2) to use the USEtox model (Rosenbaum et al. in Int J Life Cycle Assess 13:532–546, 2008) to assess the part of the total freshwater ecotoxicity impact due to pesticide use, its variability among plots, and to identify the active ingredients with the strongest impact; (3) and with the help of fungicide, insecticide, herbicide experts, to identify active ingredients to replace these high-impact pesticides and estimate the effect of such a substitution on total freshwater ecotoxicity.     

Assessing the impacts of biochar-blended urea on nitrogen use efficiency and soil retention in wheat production

Improving nitrogen (N) use efficiency (NUE) in crop plants is important to reduce the negative impact of excessive N on the environment. Although biochar-blended fertilizer had been increasingly tested in crop production, the fate of fertilized N in soil and plant had not been elucidated in field conditions. In this study, a novel biochar-blended urea (BU) was prepared by pelleting maize straw biochar, bentonite, sepiolite, carboxymethylcellulose sodium, and chitosan with urea (commercial urea without biochar [CU]). N fertilization in a winter wheat field was treated with BU and CU at both 265 kg N ha^?1 (HL) and 186 kg N ha^?1 (LN). Within a treatment plot, a microplot was fertilized with ¹⁵N-labeled urea at a relevant N level. We investigated the influence of fertilizer management on biomass, grain yield, bioaccumulation of nutrient, soil properties, ¹⁵N isotopic abundance, and greenhouse gas emissions. Microscopic and spectroscopic analysis showed that micro/nanonetwork of biochar could bind N to form a loss control agglomerated particle, and organo-mineral coatings on BU may protect N from quick release. Compared with CU, BU significantly increased grain yield by 13% and 38%, and grain N allocation by 19% and 55%, respectively, at HN and LN level. The total recovery of urea ¹⁵N in wheat plant (¹⁵N based NUE) was 32.8% under CU regardless of N rates but increased to 41.7% (HN rate) and 56.3% (LN rate) under BU. Whereas, the soil proportion (soil residual ¹⁵N) was 20.1% and 13.4% under CU but 32.5% and 18.8% under BU, in 0-20cm topsoil, respectively, at HN and LN rate. Compared with the CU, BU had no effect on CO₂ and CH₄ emissions but significantly reduced the total N₂O emission by 23%–28%. These important findings suggested that BU can be beneficial to uplift plant NUE to reduce reactive N loading but boost crop production.     

Assessing potential desertification environmental impact in life cycle assessment. Part 2: agricultural case study in Spain and Argentina

Purpose

Land use in dry lands can result in a final stage where land is completely depleted or entirely degraded causing the desertification phenomenon. The first part (part 1) of this series of two articles proposed a methodology to include desertification in life cycle assessment (LCA). A set of variables to be measured in the life cycle inventory, characterization factors, and an impact assessment method for the life cycle impact assessment phase were proposed. This second part (part 2) aims at showing the application of the model proposed in part 1 on two case studies of agricultural activities.

Methods

The impact model proposed is applied to plots of land devoted to agricultural activities in two countries: Argentina and Spain. In the agricultural plots of Spain (1SP to 9SP), two crops were analyzed: winter wheat (Triticum aestivum) and rapeseed (RS, Brassica napus). Two crops were considered in the Argentinean case study: rapeseed (RS, B. napus) and digit grass (Digitaria eriantha) (10AR to 17AR). A bare soil state is considered in both countries as a reference state. Both case studies consider only the agricultural stage in the inventory of a complete life cycle assessment study. Both also consider only one impact category in life cycle environmental assessment: desertification impact due to land occupation.

Results and discussion

On the basis of the obtained results, it can be inferred that cultivating 1 ha of rapeseed and 1 ha of wheat has the same impact on the analyzed plots in Spain and improves the reference state conditions in 50 % of the cases. Moreover, rapeseed grown in Mendoza produces almost the same impact as in some of the Spanish plots. Normalized areas of plots could be useful to compare results in different regions of the world to avoid the influence of the area of occupation in results.

Conclusions

The proposed model implies a contribution of significant importance because so far there has not been an impact assessment tool for land use in dry lands within the LCA framework. The main strength of the proposed model is that it allows a simple way to quantify the desertification impact. Also, it is emphasized that the model can be adapted virtually without difficulty to the evaluation of all types of crops with different management practices in different regions in the life cycle impact assessment stage.     

Developing characterisation factors for land fragmentation impacts on biodiversity in LCA: key learnings from a sugarcane case study

Purpose

Habitat change was identified by the Millennium Ecosystem Assessment as the main direct driver of biodiversity loss. However, while habitat loss is already implemented in Life Cycle Impact Assessment (LCIA) methods, the additional impact on biodiversity due to habitat fragmentation is not assessed yet. Thus, the goal of this study was to include fragmentation effects from land occupation and transformation at both midpoint and endpoint levels in LCIA.

Methods

One promising metric, combining the landscape spatial configuration with species characteristics, is the metapopulation capacity λ, which can be used to rank landscapes in terms of their capacity to support viable populations spatially structured. A methodology to derive worldwide regionalised fragmentation indexes based on λ was used and combined with the Species Fragmented-Area Relationship (SFAR), which relies on λ to assess a species loss due to fragmentation. We adapted both developments to assess fragmentation impacts due to land occupation and transformation at both midpoint and endpoint levels in LCIA. An application to sugarcane production occurring in different geographical areas, more or less sensitive to land fragmentation, was performed.

Results and discussion

The comparison to other existing LCIA indicators highlighted its great potential for complementing current assessments through fragmentation effect inclusion. Last, both models were discussed through the evaluation grid used by the UNEP-SETAC land use LCIA working group for biodiversity impact assessment models.

Conclusions

Midpoint and endpoint characterisation factors were successfully developed to include the impacts of habitat fragmentation on species in LCIA. For now, they are provided for bird species in all forest ecoregions belonging to the biodiversity hotspots. Further work is required to develop characterisation factors for all taxa and all terrestrial ecoregions.

     

National inventory of organic wastes for use as growing media for ornamental potted plant production: case study in Spain

An inventory of materials suitable for use as growing media for ornamental potted plant production in Spain has been prepared. Special attention has been paid to solid organic wastes generated by production, industrial and consumer activities. Information obtained from this study has been organised into two data bases. Data base 1 contains the "General Characteristics" file of more than 105 materials. In this file, data are available regarding generation points, material availability, uses, cost, disposal expenses, etc. Data base 2 is comprised of the "Specific Properties" file of 63 materials selected from data base 1. The main physical, chemical and biological properties of these materials as container media have been characterised, and the results obtained have been compiled. Finally, a computerised data bank has been created which can be found in the home page of the Spanish Ministry of Agriculture, Fisheries and Food (http://agritel2.mapya.es/sustratos/).     

Land use impacts on biodiversity in LCA: proposal of characterization factors based on functional diversity

Purpose

The focus of land use modeling in life cycle impact assessment has been mainly on taxonomic measures of biodiversity, namely species richness (SR). However, increasing availability of trait data for species has led to the use of functional diversity (FD) as a promising metric to reflect the distinctiveness of species; this paper proposes the use of an FD index to calculate characterization factors (CFs) for land use impacts. Furthermore, we compare the results of the CFs to current practice and assess the increase in complexity introduced by the use of the new indicator.

Methods

The model proposed is based on data compiled by previous regional meta-analysis on SR and FD, in different land use types in the Americas. The taxonomic groups included were mammals, birds, and plants. Within each study, calculated values for FD for different land use types were compared with the natural or close-to-natural state, taken as the reference situation. FD values among different land uses were standardized, and CFs were calculated. The final results were then analyzed and compared by analysis of variance and post hoc tests. A sensitivity analysis was also applied to verify the influence on the choice of the reference state.

Results and discussion

The results show that significant differences exist between CFs for SR and FD metrics. Across all taxa, CFs differ significantly between land use types. The results support the use of CF for FD, as a complement to current practice. Distinct CFs should be applied for at least six groups of land use categories. The choice of reference land use type did not significantly alter the results but can be a source of variability. A sensitivity analysis evaluating the impact of alternate land use types as reference types found only few significant changes on the results.

Conclusions and recommendations

Given the results, we believe the use of CFs based on FD can help on the establishment of possible links between species loss and key ecosystem functions, i.e., on the association between the midpoint indicator (e.g., biodiversity loss) and the damage caused to ecosystem quality, in terms of functions lost. Basing CFs on FD is not without challenges. Such indices are data hungry (requiring species composition and traits) require more complex calculations than current common practice, including decisions on the choice of a method to calculate FD and the selection of traits.     

转基因逃逸及其环境生物安全评价研究进展——抗虫水稻案例分析

转基因技术研发为提高我国水稻产量和减少劳动力投入提供了巨大机遇。我国对转基因水稻研发进行了大量的投入,目前已培育了具有不同新性状的转基因水稻品系,许多品系已进入生物安全评价阶段。风险评价对转基因水稻的安全生产至关重要,是其商品化生产之前必须解决的问题,其中包括转基因逃逸及其潜在环境影响。对水稻抗虫转基因逃逸及其潜在环境风险的评价包括3个重要环节：（1）通过田间试验和模型模拟检测转基因漂移到非转基因栽培稻及其野生近缘种的频率;（2）检测转基因在栽培稻和野生近缘种后代中的表达;（3）确定转基因对野生近缘种群体适合度和进化潜力的影响。大量研究表明,在近距离的空间范围内栽培稻品种之间的基因漂移频率很低（〉0.1%）,但栽培稻与其野生近缘种的基因漂移频率变异很大。进一步研究还表明,Bt抗虫转基因在栽培稻与普通野生稻后代中均能正常表达,但在其不同生长阶段,表达量有很大变异。在有较高水平的害虫虫压下,含有抗虫转基因的栽培稻及野生近缘种杂交后代与不含转基因的对照相比,抗虫性显著提高且适合度利益明显;但是,在虫害发生水平较低时,含有抗虫转基因的群体与不含抗虫转基因的群体相比没有显著的适合度优势。综上,转基因逃逸到非转基因水稻的频率极低,并且可以通过空间隔离阻断其逃逸。虽然抗虫转基因向杂草稻以及与栽培稻距离较近的野生稻群体的逃逸无法避免,但是野生稻和杂草稻群体周围环境中的总体虫压较低,所以基因漂移带来的环境影响应十分有限。     

Potential for optimized production and use of rapeseed biodiesel. Based on a comprehensive real-time LCA case study in Denmark with multiple pathways

Purpose

Several factors contribute to the current increased focus on alternative fuels such as biodiesel, including an increasing awareness of the environmental impact of petrochemical (PC) oil products such as PC diesel, the continuously increasing price of PC oil, and the depletion of PC oil. For these reasons, the European Union has enacted a directive requiring each member state to ensure that the share of energy from renewable sources in transport be at least 10 % of the final consumption of energy by 2020 (The European Parliament and the Council 2009). This LCA study assesses the specific environmental impacts from the production and use of biodiesel as it is today (real-time), based on rapeseed oil and different types of alcohols, and using technologies that are currently available or will be available shortly. Different options are evaluated for the environmental improvement of production methods. The modeling of the LCA is based on a specific Danish biodiesel production facility.

Methods

The functional unit is “1,000 km transportation for a standard passenger car.” All relevant process stages are included, such as rapeseed production including carbon sequestration and N₂O balances, and transportation of products used in the life cycle of biodiesel. System expansion has been used to handle allocation issues.

Results and discussion

The climate change potential from the production and use of biodiesel today is 57 kg CO₂-eq/1,000 km, while PC diesel is 214 kg CO₂-eq/1,000 km. Options for improvement include the increased use of residual straw from rapeseed fields for combustion in a power plant where carbon sequestration is considered, and a change in transesterification from a conventional process to an enzymatic process when using bioethanol instead of PC methanol. This research also evaluates results for land use, respiratory inorganics potential, human toxicity (carc) potential, ecotoxicity (freshwater) potential, and aquatic eutrophication (N) potential. Different sources for uncertainty are evaluated, and the largest drivers for uncertainty are the assumptions embedded into the substitution effects. The results presented should not be interpreted as a blueprint for the increased production of biodiesel but rather as a benchmarking point for the present, actual impact in a well-to-wheels perspective of biodiesel, with options for improving production and use.

Conclusions

Based on this analysis, we recommend investigating additional options and incentives regarding the increased use of rape straw, particularly considering the carbon sequestration issues (from the perspective of potential climate change) of using bioalcohol instead of PC alcohol for the transesterification process.     

Estimation of shadow prices of soil organic carbon depletion and freshwater depletion for use in LCA

The International Journal of Life Cycle Assessment - The interpretation of differences between alternative systems in life cycle assessment (LCA) can be problematic when different impact categories...     

Life cycle environmental impacts and costs of beer production and consumption in the UK

Purpose

Global beer consumption is growing steadily and has recently reached 187.37 billion litres per year. The UK ranked 8th in the world, with 4.5 billion litres of beer produced annually. This paper considers life cycle environmental impacts and costs of beer production and consumption in the UK which are currently unknown. The analysis is carried out for two functional units: (i) production and consumption of 1 l of beer at home and (ii) annual production and consumption of beer in the UK. The system boundary is from cradle to grave.

Methods

Life cycle impacts have been estimated following the guidelines in ISO 14040/44; the methodology for life cycle costing is congruent with the LCA approach. Primary data have been obtained from a beer manufacturer; secondary data are sourced from the CCaLC, Ecoinvent and GaBi databases. GaBi 4.3 has been used for LCA modelling and the environmental impacts have been estimated according to the CML 2001 method.

Results and discussion

Depending on the type of packaging (glass bottles, aluminium and steel cans), 1 l of beer requires for example 10.3–17.5 MJ of primary energy and 41.2–41.8 l of water, emits 510–842 g of CO₂ eq. and has the life cycle costs of 12.72–14.37 pence. Extrapolating the results to the annual consumption of beer in the UK translates to a primary energy demand of over 49,600 TJ (0.56 % of UK primary energy consumption), water consumption of 1.85 bn hl (5.3 % of UK demand), emissions of 2.16 mt CO₂ eq. (0.85 % of UK emissions) and the life cycle costs of £553 million (3.2 % of UK beer market value). Production of raw materials is the main hotspot, contributing from 47 to 63 % to the impacts and 67 % to the life cycle costs. The packaging adds 19 to 46 % to the impacts and 13 % to the costs.

Conclusions

Beer in steel cans has the lowest impacts for five out of 12 impact categories considered: primary energy demand, depletion of abiotic resources, acidification, marine and freshwater toxicity. Bottled beer is the worst option for nine impact categories, including global warming and primary energy demand, but it has the lowest human toxicity potential. Beer in aluminium cans is the best option for ozone layer depletion and photochemical smog but has the highest human and marine toxicity potentials.

     

Assessing the public health impacts of legalizing recreational cannabis use: the US experience

The sale of cannabis for adult recreational use has been made legal in nine US states since 2012, and nationally in Uruguay in 2013 and Canada in 2018. We review US research on the effects of legalization on cannabis use among adults and adolescents and on cannabis‐related harms; the impact of legalizing adult recreational use on cannabis price, availability, potency and use; and regulatory policies that may increase or limit adverse effects of legalization. The legalization of recreational cannabis use in the US has substantially reduced the price of cannabis, increased its potency, and made cannabis more available to adult users. It appears to have increased the frequency of cannabis use among adults, but not so far among youth. It has also increased emergency department attendances and hospitalizations for some cannabis‐related harms. The relatively modest effects on cannabis use to date probably reflect restrictions on the number and locations of retail cannabis outlets and the constraints on commercialization under a continued federal prohibition of cannabis. Future evaluations of legalization should monitor: cannabis sales volumes, prices and content of tetrahydrocannabinol; prevalence and frequency of cannabis use among adolescents and adults in household and high school surveys; car crash fatalities and injuries involving drivers who are cannabis‐impaired; emergency department presentations related to cannabis; the demand for treatment of cannabis use disorders; and the prevalence of regular cannabis use among vulnerable young people in mental health services, schools and the criminal justice system. Governments that propose to legalize and regulate cannabis use need to fund research to monitor the impacts of these policy changes on public health, and take advantage of this research to develop ways of regulating can­nabis use that minimize adverse effects on public health.     

Development of a dynamic LCA approach for the freshwater ecotoxicity impact of metals and application to a case study regarding zinc fertilization

Purpose

Temporal variability is a major source of uncertainty in current life cycle assessment (LCA) practice. In this paper, the recently developed dynamic LCA approach is adapted to assess freshwater ecotoxicity impacts of metals. The objective is to provide relevant information regarding the distribution and magnitude of metal impacts over time and to show whether the dynamic approach significantly influences the conclusions of an LCA. An LCA of zinc fertilization in agriculture was therefore carried out.

Methods

Dynamic LCA is based on the temporal disaggregation of the inventory, which is then assessed using time-horizon-dependent characterization factors. The USEtox multimedia fate model is used to develop time-horizon-dependent characterization factors for the freshwater ecotoxicity impact of 18 metals. Mass balance equations are solved dynamically to obtain fate factors as a function of time, providing both instantaneous (impact at time t following a pulse emission) and cumulative (total time-integrated impact following a pulse emission) characterization factors (CFs).

Results and discussion

Time-horizon-dependent CFs for freshwater ecotoxicity depend on the emission compartment and the metal itself. The two variables clearly influence metal fate aspects such as the maximum mass loading reaching freshwater and the persistence time of metals into this compartment. The time needed to reach the total impact for each metal may exceed thousands of years, so the time horizon used in the analysis constitutes a determining factor. The case study reveals that the results of a classical LCA are always higher than those obtained from a dynamic LCA, especially for short time horizons. For instance, at the end of a 100-year fertilization treatment, only 25 % of the impacts obtained through traditional LCA occurred.

Conclusions

Results show that dynamic LCA enables assessing freshwater ecotoxicity impacts of metals over time, allowing decision makers to test the sensitivity of their results to the choice of a time horizon. For the particular case study of zinc fertilization over a period of 20 years, the use of time-horizon-dependent CFs is more important in determining the dynamics of impacts than the timing of emission.     

Integrating human health impact from indoor emissions into an LCA: a case study evaluating the significance of the use stage

Purpose

Indoor emissions of toxic substances from products can have a negative effect on human health. These are typically not considered in a life cycle assessment (LCA), potentially underestimating the importance of the use stage. The purpose of this paper is to develop a method that, based on a set of measured emission rates, calculates the impact on human health during the use stage of products that are used indoors and that emit volatile organic compounds (VOCs).

Methods

Emissions from a product are measured in a test chamber and reported as a set of emission rates (microgrammes per hour) at specific points in time (hour/day). Constrained non-linear regression (CNLR) analysis is then used to determine parameters for three emission models, and a model is selected based on goodness of fit with the measured emission rates (R ² and expert judgement). The emission model is integrated over a defined time period to estimate the total use stage emissions per functional unit (FU). The total emissions are subsequently integrated in a homogeneously mixed one-box model within the USEtox model. Intake fraction (iF) is calculated based on size of residential home, inhalation rate, exposure time, ventilation rate, mixing factor and number of people exposed.

Results and discussion

The method is tested in a case study of a chair, with the results showing that the impacts in the use stage are in most cases significantly higher than from the production and disposal stages combined. The sensitivity to parameter variations is evaluated. Intake fraction (factor of 761), replacement frequency (factor of 70) and emission model (factor of 24) are found to be the most important model parameters. Limiting early exposure (>14 % of emissions may occur in the first month and >50 % in the first year) and replacing furniture less frequently will reduce exposure.

Conclusions

The case study shows that the impact on human health from indoor emissions can be of significance, when compared to the impact on human health from total outdoor emissions. Without specific exposure data (e.g. ventilation rates) the uncertainty will be high. The developed method is applicable to all products that emit VOCs, provided that the emission rate can be modelled using an exponential decay model and that the product amount is related to a meaningful functional unit. It is recommended that when performing an LCA of products that emit VOCs, the indoor use stage is included in the life cycle impact assessment.