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1.
1. The distribution of trace metals among body parts of the freshwater amphipod Gammarus fasciatus was investigated and the effect of depuration on the total body burden was assessed.
2. Concentrations of Cr, Fe, Mn and Ni were one order of magnitude higher in the gut contents than in the various body parts, accounting for 40–72% of the total body burdens of amphipods. Depuration caused a decrease of total metal concentrations of 35–88%.
3. Levels of Cd and Cu were higher in the hepatopancreas than in other body parts, whereas levels of Zn were relatively constant throughout the body. For Cd, Cu and Zn, depuration had no effect on mean body concentrations.
4. For Pb, an important fraction of the total body burden was associated with the exoskeleton; depuration caused a decrease in Pb body concentrations.
5. Regression between amphipod metal concentrations before and after depuration is a potential tool for correcting for the effect of gut contents. This correcting method was found to be promising for Cd, Cu, Mn and Zn, with R 2 varying between 0.66 and 0.98. It was less efficient for Cr, Fe and Pb, and was useless for Ni.  相似文献   

2.
Metal determination in human tissues is the most common application of biological monitoring for screening, diagnosis and assessment of metal exposures and their risks. Various biopsy-materials may be used. This paper deals with the quantitative determination of Cd, Pb, Cr, Mn, Fe, Ni, Cu, and Zn concentrations in nails of male subjects exposed to these metals alongwith their respective controls, while working in locomotive, carriage and roadways workshops, and lead battery factories. The levels of Cd, Pb, Cr, Mn, Fe, Ni, Cu and Zn in fingernails, assayed by atomic absorption spectrophotometry, were compared with their respective controls by student ‘t’ test. All the obtained values were correlated to the personal and medical history of the subjects under study. Significantly high levels of Cd, Pb, Cr, Fe, Ni, Cu and Zn were present in smokers, compared to nonsmokers. The concentrations of Cd, Pb, Cr, Mn and Fe were not significantly high in vegetarian subjects. It was also observed that there is no contribution of liquor towards nail-metal concentration. Significant correlations were observed between skin disease and Cr, Mn, Fe, Cu; hypertension and Cd, Mn, Cu; mental stress and Cd, Pb, Mn, Ni, Cu, Zn; diabetes and Cr, Mn, Ni; chest pain and Pb; respiratory trouble and Cr, Mn, Fe, Ni, Zn; tuberculosis and Zn; acidity and Cd; and ophthalmic problems and Mn, Fe, Ni, and Zn  相似文献   

3.
We analysed the concentrations of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn in the water, sediments, fish and plants of the River Hindon, U.P., India, at seven sampling stations, in the year 1982. Considerable variation in concentration between water, sediments, fish and plants were noted. The concentration in the water was in the order Fe > Zn > Cr > Mn > Cu > Pb > Ni > Co > Cd, in the sediments, Fe > Mn > Zn > Ni > Cr > - Co > Cu > Pb > Cd; in a fish (Heteropnuestes fossilis) Fe > Zn > Mn > Pb > Ni > Co > Cu > Cd > Cr, and in a plant (Eicchornia crassipes) Fe > Mn > Zn > Ni > Cu > Cr > Pb > Co > Cd.  相似文献   

4.
Heavy metal contamination of agricultural soils resulting from rapid industrialization and urbanization is of great concern because of potential health risk due to dietary intake of contaminated vegetables. The present study aims to evaluate the status of heavy metals contamination of agricultural soils and food crops around an urban-industrial region in India. Transfer factor values of Cu, Cr, Pb, Cd, Zn, and Ni from soil to vegetable was estimated. The mean heavy metal concentrations (mg/kg) in agricultural soils (Cu: 17.8, Cr: 27.3, Pb: 29.8, Cd: 0.43, Zn: 87, Mn: 306.6, Fe: 16984, and Ni: 53.8) were within allowable concentrations for Indian agricultural soil. The concentrations of Pb, Cd, Zn, and Ni in crops/vegetables exceeded the World Health Organization/Food and Agriculture Organization safe limits. Relative orders of transfer of metals from soil to edible parts of the crops/vegetables were Cd > Pb > Ni > Zn > Cu > Cr. The enrichment factors of heavy metals in soil indicated minor to moderately severe enrichment for Pb, Cd, and Ni; minor to moderate enrichment for Zn; no enrichment to minor enrichment for Mn; and no enrichment to moderate enrichment for Cu at different sites. Ecological risk index of soil showed considerable contamination in one of the wastewater irrigated sites.  相似文献   

5.
Selected trace metals were analyzed in human malignant and nonmalignant (benign) breast tissue samples by the flame atomic absorption spectrophotometric method. In malignant tissues, dominant mean concentrations were revealed by Na, K, Ca, Mg, Fe, Zn, and Al at 927, 552, 231, 61.7, 36.5, 18.3, and 8.94 microg/g, respectively, while the mean metal levels in benign tissues were 903, 435, 183, 63.3, 24.7, 14.5, and 10.1 microg/g, respectively. Average concentrations of Cd, Co, Cr, Cu, Fe, Mn, K, Ca, and Zn were noted to be significantly higher in the malignant tissues compared with the benign tissues. Significantly strong correlations (r > 0.50) in malignant tissues were observed between Mn and Co, Mn and Cd, Cd and Cr, Fe and Mn, Cd and Co, Fe and Co, Mg and Pb, Cd and Fe, Mg and Ni, Pb and Ni, Ni and Sr, and Fe and Pb, whereas, Cd and Co, Cd and Mn, Co and Mg, Co and Mn, Cu and Mn, Co and Ni, Mg and Ni, Cd and Cu, Cd and Ni, Ca and Mg, Mn and Pb, Cu and Ni, Fe and Ni, Cd and Mg, Co and Cu, Cr and Na, and Cd and Cr revealed strong and significant relationships in benign tissues at p < 0.001. Principal component analysis of the metals data yielded six principal components for malignant tissues and five principal components for benign tissues, with considerably different loadings, duly supported by cluster analysis. The study revealed a considerably different pattern of distribution and mutual correlations of trace metals in the breast tissues of benign and cancerous patients.  相似文献   

6.
Abstract

A total of 83 dust samples were collected from the streets of Urumqi city in NW China and analyzed for the concentrations of As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, and Zn elements. The spatial distribution, contamination levels, main sources, and potential health risks of these trace elements were determined based on geostatistical analysis, geo-accumulation index, multivariate analysis, and the health risk assessment model introduced by the USEPA, respectively. The obtained results indicate that the average concentrations of Cd, Cr, Cu, Hg, Ni, Pb, and Zn exceed the corresponding background values determined in Xinjiang soils by factors of 2.0, 1.35, 1.38, 8.24, 1.28, 2.09, and 3.26, respectively. The spatial distribution patterns of the nine trace elements in street dust were found to be substantially heterogeneous, and the contamination level decreased in the following order: Hg?>?Zn?>?Pb?>?Cd?>?Cr?>?Cu?>?As?>?Ni?>?Mn. Based on the identified concentrations, the collected dust samples were found to be moderately polluted by Hg, and not polluted by As, Cr, Cu, Mn, and Ni. The remaining elements, Cd, Pb, and Zn lie on the borderline between non-pollution and moderate pollution levels. Furthermore, it was shown that Mn and Zn in street dusts originate from both, natural and anthropogenic sources, while As, Cd, Cr, Cu, Hg, Ni, and Pb are mainly produced by anthropogenic sources. Overall, the carcinogenic and non-carcinogenic health risks of the analyzed elements, instigated primarily by oral ingestion of street dusts, were found to be within the acceptable range for both, children and adults. As and Cr are the main non-carcinogenic elements, whereas Cr is the major carcinogenic element among the investigated dust-bound metals in the study area.  相似文献   

7.
为探索刺楸对受污染土壤重金属的富集和修复效应, 以南京栖霞山的乡土树种刺楸及其根际周边土壤为研究对象, 截取其根基部年轮盘及根际土壤样本, 采用ICP-AES法测定年轮及土壤样本中重金属(Cu、Cd、Cr、Mn、Ni、Pb、Zn)元素含量。结果表明: 栖霞山样地中的土壤受Mn、Pb和Zn污染最为严重, 存在Cu、Cd、Mn、Pb、Zn元素的高度复合污染, Cd、Cr、Cu、Ni、Zn在土壤和年轮中存在相关性, Mn和Pb则没有表现出明显的相关性; 刺楸修复受Cd、Mn、Pb、Zn污染的土壤效果并不显著, 更适用于Cr、Cu、Ni污染的土壤修复; 鉴于Cu元素含量变化特征, 刺楸也可以作为反映当地污染历史的记录载体; 刺楸年轮中的重金属元素之间存在交互作用, 其中Cd与Zn元素含量高度相关(r=0.984, p<0.01), 在刺楸年轮吸收重金属元素的过程中, Cu与Cd、Cr、Mn、Zn元素具有协同作用, Mn元素对其他元素有一定的拮抗作用。  相似文献   

8.
A total of 455 agricultural soil samples from four nonferrous mines/smelting sites in Shaoguan City, China, were investigated for concentrations of 10 heavy metals (As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, and Zn). The mean concentrations of the metals were 72.4, 5.16, 13.3, 54.8, 84.5, 1.52, 425, 28.2, 529, and 722 mg kg?1, respectively. The values for As, Cd, Hg, Pb, and Zn were more than 8 and 1.5 times higher than their background values in this region and the limit values of Grade II soil quality standard in China, respectively. Estimated ecological risks based on contamination factors and potential ecological risk factors were also high or very high for As, Cd, Hg, and Pb. Multivariate analysis (Pearson's correlation analysis, hierarchical cluster analysis, and principal component analysis) strongly implied three distinct groups; i.e., As/Cu/Hg/Zn, Co/Cr/Mn/Ni, and Cd/Pb. Local anomalies for As, Cu, Hg, and Zn by a probably anthropogenic source (identified as mining activity), Co, Cr, Mn, and Ni by natural contribution, and a mixed source for Cd and Pb, were identified. This is one of the few studies with a focus on potential sources of heavy metals in agricultural topsoil around mining/smelting sites, providing evidence for establishing priorities in the reduction of ecological risks posed by heavy metals in Southern China and elsewhere.  相似文献   

9.
Enrichment of trace elements in groundwater poses considerable risks to human health. The concentrations of seven trace elements (Cr, Mn, Ni, Cu, Zn, Cd, and Pb) in 34 samples of shallow groundwater from the study area were estimated. We assessed the concentrations of the trace elements and health risks with statistical analysis and the US Environment Protection Agency (USEPA) model. The results showed that the mean concentrations of trace elements decreased as follows: Mn > Zn > Ni > Cr > Cu > Cd > Pb. Apart from Mn at one sampling point, the concentrations of all trace elements were below the guideline values of the World Health Organization for drinking water. Correlation and cluster analysis indicated that the trace elements fell into groups, with Ni and Cu in one group, and Mn, Zn, and Cd in another, which suggested that the trace elements grouped together had similar sources. The total non-carcinogenic risk values ranged from 8.52 × 10?4 to 1.27 × 10?1. The total carcinogenic risk caused by Cr and Cd averaged 1.62 × 10?6, which exceeded the acceptable level of 1 × 10?6 recommended by the USEPA. The carcinogenic risk of Cr accounted for 75.93% of Rtotal.  相似文献   

10.
为探讨油茶(Camellia oleifera)产地土壤和油茶果实中金属元素分布和富集特征,在油茶果实成熟期,对浙江5个油茶产地土壤及油茶果实中金属元素进行污染分析和富集能力评价.结果表明,浙江油茶产地土壤中Pb、Cr、Cd、As、Hg、Ni、Cu和Zn含量低于农用地土壤污染风险筛选值,综合污染等级为安全.个别产区常山...  相似文献   

11.
The present research was conducted to determine heavy metals in agricultural soils from Çanakkale, Turkey, using a sequential extraction procedure (acid soluble, reducible, oxidizable, and residual) as proposed by the Community Bureau of Reference (BCR) of the European Commission. Soil samples were taken from 12 different cultivated sites and analyzed for Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn concentrations. The results revealed an order of Mn > Cd > Pb > Co > Ni > Cu > Zn > Cr for the heavy metals based on the sum of the first three fractions (acid soluble + reducible + oxidizable). The relationships between soil properties and each metal fraction were identified through Pearsons's correlation analysis. Hierarchical cluster analysis was performed to determine the behaviors and similarities of metals in each fraction. While Mn, Pb, and Zn exhibited subjective behaviors in the acid-soluble fraction, Cd, Co, Cu, Cr, and Ni exhibited similar behaviors with each other.  相似文献   

12.
In this study, the content characteristics, comprehensive pollution assessment, and morphological distribution characteristics of heavy metals (Mn, Cd, Cr, Pb, Ni, Zn, and Cu) were researched based on the processes of field investigation, sample collection, and experimental analysis. Results showed that the mean concentrations of Mn, Pb, Cr, Cu, Cd, Zn, and Ni in surface soils were 522.77, 22.56, 55.10, 25.41, 0.25, 57.02, and 48.47 mg kg?1, respectively. The surface soil from Sunan mining area was contaminated by Cu, Cd, and Ni in different degrees, and high CV values of Cd, Zn, Pb, and Ni were influenced by local human activities possibly. The evaluation results suggested that the mean Igeo values were in the sequence of Cd (0.657) > Ni (0.052) > Cu (?0.293) > Mn (?0.626) > Zn (?0.761) > Cr (?0.884) > Pb (?0.899). Besides, Cd was the most significant potential risk factor among all elements. Nevertheless, the Cd of bioavailable speciations with higher proportion had stronger migration and toxicity, and was more easier to be absorbed and enriched than other elements by some crops (e.g., vegetables, rice), and being at a relatively higher potential ecological risk in soil.  相似文献   

13.
行道树毛白杨树干中重金属元素分布   总被引:3,自引:1,他引:2  
王荣芬  邱尔发  唐丽清 《生态学报》2014,34(15):4212-4222
采用电感耦合等离子体发射光谱法(ICP),测定分析首都机场高速公路旁毛白杨(Populus tomentosa Carr.)树干中Pb、Cd、Cr、Cu、Zn、Ni和Mn 7种重金属元素的含量及积累量,比较分析树干不同组织、不同方位、不同龄级年轮重金属含量差异及与交通量、关键气候因子的相关性。结果表明:树干木质部中各重金属平均含量由大到小依次为Zn、Cu、Cr、Mn、Ni、Pb、Cd,树皮中依次为Zn、Mn、Cr、Pb、Cu、Cd、Ni,树皮中各重金属元素的含量明显高于木质部;同一树干木质部中,各重金属元素在不同方位的分布有所差异,其中,靠近车道一侧的各重金属元素含量均高于背离车道一侧,南北向比较中,Ni、Zn为南侧含量高于北侧,其他5种重金属元素均为北侧高于南侧;以5a为一个龄级将年轮划分为5个龄组,各龄级年轮中重金属含量随时间的变化趋势各异,其中Pb、Cd、Cu、Zn总体呈递减趋势,且与年降水量、最低气温、日照时数、雨天日数和大风日数呈正相关趋势,与年平均气温和最高气温呈负相关趋势;各元素在毛白杨树干木质部中的积累量表现为ZnCrCuMnPbNiCd。  相似文献   

14.
Instead of total metal concentration measurements in seafood, bioaccessibility is a more important parameter for human health risk assessment. Therefore, bioaccessibility of Cd, Cr, Cu, Mn, Ni, Pb, and Zn in the edible soft tissues of rapa whelk (Rapana venosa Valenciennes, 1846) collected along the southern Black Sea coast were investigated using an in vitro digestion model. Zn was detected at the highest concentration, whereas Ni was the lowest for total metal concentrations. Total Cd and Pb concentration in the tissues were found to be higher than maximum permissible limits set by European Commission. The bioaccessibility of metals in the tissues was found to be decreased in the order: Cu (77.11%) > Cd (70.13%) > Zn (64.52%) > Ni (61.27%) > Pb (50.53%) > Cr (43.41%) > Mn (22.59%). While significant positive linear regressions were observed between the total and bioaccessible concentrations for Mn, Pb, and Ni, significant negative linear regressions were found for Cd in the tissues (p < 0.05). The hazard quotients (HQ) calculated using bioaccessible heavy metal amount were detected lower than the limit value (HQ < 1), which may not pose a potential hazard to humans declared by US Environmental Protection Agency. However, the consumption of rapa whelk may cause a potential risk concerning human health for the Cd and Pb levels in case of increased serving sizes and portions.  相似文献   

15.
为了了解渭河陕西段河道沉积物重金属空间分布特征,本研究对渭河陕西段干流及其支流17个采样点沉积物中的10种重金属元素(Cd、Sb、As、Co、Cu、Pb、Ni、Cr、Zn、Mn)含量进行测定及来源辨析。结果表明: 重金属元素Cd、Sb、As、Co、Cu、Pb、Ni、Cr、Zn、Mn的平均含量分别为0.10、1.24、11.73、11.95、24.90、24.91、29.31、54.18、72.74、626.85 mg·kg-1, 除Cd的变异系数大于1以外,其他元素的变异系数均低于0.5。其中,Cd、Pb、Cr含量于灞河入渭处达到峰值,Co和Mn在黑河入渭处达到峰值,Cu和Zn在清姜河入渭处达到峰值, Sb、As和Ni分别于沙王渡、咸阳铁桥和林家村处达到峰值。相关性分析、主成分分析和聚类分析表明,Cd、Co、Cu、Pb、Ni、Cr、Zn、Mn主要来源于以工业源和生活源为主的污染源;Sb、As主要来源于农业和地球化学污染源。  相似文献   

16.
Water and muscle tissue samples from two morphotypes of the African large barb Labeobarbus intermedius collected from three sites in Lake Hawassa in 2012–2013 were analysed for eight heavy metals, including Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn. Five metals (Cr, Cu, Mn, Ni and Zn) were detected in fish muscle samples, whereas only Cr, Cu and Ni were detected in water samples. Of the five metals detected in the muscle samples, Cu and Zn were present in higher concentrations in the golden morphotype, whereas Cr, Mn and Ni were found in higher concentrations in the silver morphotype. Bioaccumulation factor (BAF) values indicated that Cr, Cu and Ni have a tendency to accumulate in fish muscle in amounts exceeding those in water. In both morphotypes the highest concentrations of Zn and Mn were detected at the Hospital site, whereas the concentrations of Cr, Cu and Ni were highest at the Tikur Wuha site. Chromium, Cu and Ni concentrations recorded in fish muscle at all sampling sites exceeded the safe limits recommended by FAO/WHO and UNESCO, suggesting that water and fish from Lake Hawassa are contaminated with heavy metals originating from factories, a hospital and agricultural activities in proximity to the lake.  相似文献   

17.
Accumulation of different metals and metalloids was assessed in two vegetables radish (Raphanus sativus L.) and spinach (Spinacea oleracea L.) irrigated with domestic wastewater in the peri-urban areas of Khushab City, Pakistan. In general, the metal and metalloid concentrations in radish and spinach were higher at site-II treated with sewage water than those found at site-I treated with canal water. In case of radish at both sites the levels of metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Cd, and Pb) were below the permissible level except those of Mn, Ni, Mo, Cd, and Pb. At both sites, the transfer factor ranged from 0.047–228.3 mg kg?1 with Cr having the highest transfer factor. The metal pollution index in soil was in the following order: As > Fe > Ni > Zn > Cd > Mo > Se > Co > Pb > Mn > Cr > Cu, respectively. While in case of spinach at both sites, the concentrations of metals and metalloids in vegetable samples irrigated with canal and sewage water were observed below the permissible level except Mn, Ni, Zn, Mo, and Pb. At both sites, the transfer factor ranged from 0.038–245.4 mg kg?1 with Cr having the highest transfer factor. The metal pollution index in soil was in the following order: Cd > Ni > Co > Se > Mn > Zn > Mo > Pb > Fe > Cr > As > Cu, respectively.  相似文献   

18.
Concentrations of Pb, Zn, Cd, Ni, Cu, Cr, and Mn were determined to assess the impact of automobiles on heavy metal contamination of roadside soil. Soil samples at four polluted sites and a control site were collected at a depth of 0, 2, 5, 10, 15, 20, 30?cm. A comparison of elemental levels between polluted and control sites exhibited exceptionally higher concentrations at the former sites. The Pb levels in polluted sites varied from 70 to 280.5?µgg?1and it rapidly decreased with depth. Similarly, mean concentrations of Zn, Cd, Ni, Cu, Cr, and Mn were significantly higher at polluted sites and followed a decreasing trend with the increase in depth. Correlation coefficients between heavy metals and traffic density were positively significant except for nickel. Profile samples showed that Pb, Zn, Cd, Cu, and Mn were largely concentrated in the top 5?cm confirming airborne contamination. The vertical movement and partitioning of metals, except Ni and Cr, exhibited predominant association with soil pH and organic carbon. The results have been presented using Heavy Metal Index.  相似文献   

19.
The concentrations of metals (Mn, Pb, Fe, Zn, Cu, Cd,Co, Ni, Cr, Na, K, Ca, Mg) were determined in thegreen alga Ulva rigida, in the sediment andseawater of Thermaikos Gulf (Greece) during monthlysamplings in 1994–1995. This Gulf is the recipientof domestic and industrial effluents. Pb, Fe, Cu, Coand Cr concentrations in U. rigida at the studyarea were higher than those 13 years earlier andapparently came from different sources than those forZn, Cd and Ni. The relative abundance of metals inthe alga decreased in the order: Mg > Na > K >Ca > Pb > Fe > Mn > Zn > Cr, Cu > Ni >Co > Cd. Only Cu concentrations in the alga fromKalochori and Cd ones from Viamyl showed significantseasonal changes. Cu and Cd concentrations ingeneral followed the same pattern of variation, withminimum values in winter-spring. This pattern isdiscussed in relation to growth dynamics and tissueage. Only Pb concentrations in the alga showed asignificant positive correlation with concentrationsin the seawater. There were both positive andnegative correlations among some metals in the alga. It is concluded that U. rigida can be used as anindicator species, especially for Pb.  相似文献   

20.
The issue of heavy metal pollution is of high concern due to its potential health risks and detrimental effects on human beings, animals, and plants. In this study, farmland soil samples from 79 sampling sites were collected in Karashahar–Baghrash oasis, northwest China, and the contents of eight heavy metal elements (As, Cd, Cr, Cu, Mn, Ni, Pb, and Zn) were determined by standard methods. The spatial distribution, pollution, and ecological risks of heavy metals were analyzed based on Geographical Information System (GIS) technology, contamination factor (CF), pollution load index (PLI), and potential ecological risk index (RI). Results indicated that: (1) The average contents of Cd, Cr, Ni, Pb, and Zn exceeded the background values of irrigation soils of Xinjiang by 54.0, 1.34, 1.39, 3.44, and 5.01 times, respectively. The average contents of Cd exceeded the national standard of China by 10.80 times; (2) The pollution order of CF was ranked as Cd > Zn > Pb > Ni > Cr > Cu > As > Mn, and the ecological risk order of Eri was ranked as Cd > Ni > As > Cu > Ni > Pb > Cr > Zn. The average PLI of the study area showed heavy pollution level, and the average RI of the study area fell into considerable risk; (3) The moderately polluted areas with moderate potential ecological risks distributed in the northern parts, whereas heavily polluted areas with considerable potential ecological risks distributed in the southern parts of the study area; (4) Cr, Cu, and Mn of farmland soils were mainly originated from natural factors. Cd, Ni, and Pb were mainly originated from anthropogenic factors. As and Zn may be associated with both natural and anthropogenic factors. Cd contributed most to the PLI and RI of the farmland soils in the study area.  相似文献   

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