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1.
Rechargeable sodium–iodine batteries represent a promising scalable electrochemical energy storage alternative as sodium and iodine are both low cost and widely abundant elements. Here, the authors demonstrate a rechargeable sodium–iodine battery that employs free‐standing iodine quantum dots (IQDs) decorated reduced graphene oxide (IQDs@RGO) as the cathode. Consistent with the density functional theory the authors find the Na+ ions to intercalate into the I unit cell forming stable NaI, and the battery exhibits high capacity, outstanding cycle stability (with a reversible specific capacity of 141 mA h g?1 after 500 cycles at current density of 100 mA g?1), and high rate performance (170, 146, 127, 112, and 95 mA h g?1 at current densities of 100, 200, 400, 600, and 1000 mA g?1, respectively). The reversible reactions, I2/I3 ? and I3 ?/I? redox couples on insertion of Na+ ions, are confirmed via in situ Raman spectroscopy. Notably, even after 500 cycles the morphology and structure of the IQDs exhibit no noticeable change implying their use as a stable cathode material for sodium–iodine batteries. Moreover, the IQDs based flexible full‐cells also exhibit high capacity and long cycle life (the capacity with 123 mA h g?1 at current density of 100 mA g?1 after 100 cycles).  相似文献   

2.
A cathode‐flow lithium‐iodine (Li–I) battery is proposed operating by the triiodide/iodide (I3?/I?) redox couple in aqueous solution. The aqueous Li–I battery has noticeably high energy density (≈0.28 kWh kg?1cell) because of the considerable solubility of LiI in aqueous solution (≈8.2 m ) and reasonably high power density (≈130 mW cm?2 at a current rate of 60 mA cm?2, 328 K). In the operation of cathode‐flow mode, the Li–I battery attains high storage capacity (≈90% of the theoretical capacity), Coulombic efficiency (100% ± 1% in 2–20 cycles) and cyclic performance (>99% capacity retention for 20 cycles) up to total capacity of 100 mAh.  相似文献   

3.
Aqueous zinc batteries are considered as promising alternatives to lithium ion batteries owing to their low cost and high safety. However, the developments of state‐of‐the‐art zinc‐ion batteries (ZIB) and zinc–air batteries (ZAB) are limited by the unsatisfied capacities and poor cycling stabilities, respectively. It is of significance in utilizing the long‐cycle life of ZIB and high capacity of ZAB to exploit advanced energy storage systems. Herein, a bulk composite of graphene oxide and vanadium oxide (V5O12·6H2O) as cathode material for aqueous Zn batteries in a mild electrolyte is employed. The battery performance is demonstrated to arise from a combination of the reversible cations insertion/extraction in vanadium oxide and especially the electrochemical redox reactions on the surface functional groups of graphene oxide (named as pseudo‐Zn–air mechanism). Along with adjusting the hydroxyl content on the surface of graphene oxide, the specific capacity is significantly increased from 342 mAh g?1 to a maximum of 496 mAh g?1 at 100 mA g?1. The surface‐controlled kinetics occurring in the bulk composite ensure a high areal capacity of 10.6 mAh cm?2 at a mass loading of 26.5 mg cm?2, and a capacity retention of 84.7% over 10 000 cycles at a high current density of 10 A g?1.  相似文献   

4.
New energy storage and conversion systems require large‐scale, cost‐effective, good safety, high reliability, and high energy density. This study demonstrates a low‐cost and safe aqueous rechargeable lithium‐nickel (Li‐Ni) battery with solid state Ni(OH)2/NiOOH redox couple as cathode and hybrid electrolytes separated by a Li‐ion‐conductive solid electrolyte layer. The proposed aqueous rechargeable Li‐Ni battery exhibits an approximately open‐circuit potential of 3.5 V, outperforming the theoretic stable window of water 1.23 V, and its energy density can be 912.6 W h kg‐1, which is much higher than that of state‐of‐the‐art lithium ion batteries. The use of a solid‐state redox couple as cathode with a metallic lithium anode provides another postlithium chemistry for practical energy storage and conversion.  相似文献   

5.
Sodium ion batteries have attracted much attention in recent years, due to the higher abundance and lower cost of sodium, as an alternative to lithium ion batteries. However, a major challenge is their lower energy density. In this work, we report a novel multi‐electron cathode material, KVOPO4, for sodium ion batteries. Due to the unique polyhedral framework, the V3+ ? V4+ ? V5+ redox couple was for the first time fully activated by sodium ions in a vanadyl phosphate phase. The KVOPO4 based cathode delivered reversible multiple sodium (i.e. maximum 1.66 Na+ per formula unit) storage capability, which leads to a high specific capacity of 235 Ah kg?1. Combining an average voltage of 2.56 V vs. Na/Na+, a high practical energy density of over 600 Wh kg?1 was achieved, the highest yet reported for any sodium cathode material. The cathode exhibits a very small volume change upon cycling (1.4% for 0.64 sodium and 8.0% for 1.66 sodium ions). Density functional theory (DFT) calculations indicate that the KVOPO4 framework is a 3D ionic conductor with a reasonably, low Na+ migration energy barrier of ≈450 meV, in line with the good rate capability obtained.  相似文献   

6.
Mn‐based hexacyanoferrate NaxMnFe(CN)6 (NMHFC) has been attracting more attention as a promising cathode material for sodium ion storage owing to its low cost, environmental friendliness, and its high voltage plateau of 3.6 V, which comes from the Mn2+/Mn3+ redox couple. In particular, the Na‐rich NMHFC (x > 1.40) with trigonal phase is considered an attractive candidate due to its large capacity of ≈130 mAh g?1, delivering high energy density. Its unstable cycle life, however, is holding back its practical application due to the dissolution of Mn2+ and the trigonal‐cubic phase transition during the charge–discharge process. Here, a novel hexacyanoferrate (Na1.60Mn0.833Fe0.167[Fe(CN)6], NMFHFC‐1) with Na‐rich cubic structure and dual‐metal active redox couples is developed for the first time. Through multiple structural modulation, the stress distortion is minimized by restraining Mn2+ dissolution and the trigonal‐cubic phase transition, which are common issues in manganese‐based hexacyanoferrate. Moreover, NMFHFC‐1 simultaneously retains an abundance of Na ions in the framework. As a result, Na1.60Mn0.833Fe0.167[Fe(CN)6] electrode delivers high energy density (436 Wh kg?1) and excellent cycle life (80.2% capacity retention over 300 cycles), paving the way for the development of novel commercial cathode materials for sodium ion storage.  相似文献   

7.
Transition metal sulfides hold promising potentials as Li‐free conversion‐type cathode materials for high energy density lithium metal batteries. However, the practical deployment of these materials is hampered by their poor rate capability and short cycling life. In this work, the authors take the advantage of hollow structure of CuS nanoboxes to accommodate the volume expansion and facilitate the ion diffusion during discharge–charge processes. As a result, the hollow CuS nanoboxes achieve excellent rate performance (≈371 mAh g?1 at 20 C) and ultra‐long cycle life (>1000 cycles). The structure and valence evolution of the CuS nanobox cathode are identified by scanning electron microscopy, transmission electron microscopy, and X‐ray photoelectron spectroscopy. Furthermore, the lithium storage mechanism is revealed by galvanostatic intermittent titration technique and operando Raman spectroscopy for the initial charge–discharge process and the following reversible processes. These results suggest that the hollow CuS nanobox material is a promising candidate as a low‐cost Li‐free cathode material for high‐rate and long‐life lithium metal batteries.  相似文献   

8.
Cathode materials with high energy density, long cycle life, and low cost are of top priority for energy storage systems. The Li‐rich transition metal (TM) oxides achieve high specific capacities by redox reactions of both the TM and oxygen ions. However, the poor reversible redox reaction of the anions results in severe fading of the cycling performance. Herein, the vacancy‐containing Na4/7[Mn6/7(?Mn)1/7]O2 (?Mn for vacancies in the Mn? O slab) is presented as a novel cathode material for Na‐ion batteries. The presence of native vacancies endows this material with attractive properties including high structural flexibility and stability upon Na‐ion extraction and insertion and high reversibility of oxygen redox reaction. Synchrotron X‐ray absorption near edge structure and X‐ray photoelectron spectroscopy studies demonstrate that the charge compensation is dominated by the oxygen redox reaction and Mn3+/Mn4+ redox reaction separately. In situ synchrotron X‐ray diffraction exhibits its zero‐strain feature during the cycling. Density functional theory calculations further deepen the understanding of the charge compensation by oxygen and manganese redox reactions and the immobility of the Mn ions in the material. These findings provide new ideas on searching for and designing materials with high capacity and high structural stability for novel energy storage systems.  相似文献   

9.
Potassium‐ion hybrid capacitors (PIHCs) hold the advantages of high‐energy density of batteries and high‐power output of supercapacitors and thus present great promise for the next generation of electrochemical energy storage devices. One of the most crucial tasks for developing a high‐performance PIHCs is to explore a favorable anode material with capability to balance the kinetics mismatch between battery‐type anodes and capacitor‐type cathode. Herein, a reliable route for fabricating sulfur and nitrogen codoped 3D porous carbon nanosheets (S‐N‐PCNs) is reported. Systematic characterizations coupled with kinetics analysis indicate that the doped heteroatoms of sulfur and nitrogen and the amplified graphite interlayer can provide ample structural defects and redox active sites that are beneficial for improving pseudocapacitive activity, enabling fast kinetics toward efficient potassium‐ion storage. The S‐N‐PCNs are demonstrated to exhibit superior potassium storage capability with a high capacity of 107 mAh g?1 at 20 A g?1 and long cycle stability. The as‐developed PIHCs present impressive electrochemical performance with an operating voltage as high as 4.0 V, an energy density of 187 Wh kg?1, a power density of 5136 W kg?1, and a capacity retention of 86.4% after 3000 cycles.  相似文献   

10.
Dye‐sensitized solar cells (DSCs) are considered to be a promising alternative to Si‐based photovoltaic cells. The electrolyte of the DSC primarily uses triiodide/iodide (I3?/I?) as a redox couple. Therefore, it is essential to understand the regeneration and recombination kinetics of the I3?/I? redox couples in the device. In this context, controlling the total and local concentrations of the I3?/I? redox couples is an important parameter that can influence the DSC performance. Here, we propose that the introduction of a sodium bis (2‐ethylhexyl) sulfosuccinate (AOT)/water system to the I3?/I? electrolyte enables the control of the concentration of the redox couples, which consequently achieves a high power conversion efficiency of ~11% for ~1000 h (under 1 sun illumination) owing to the enhanced dye‐regeneration efficiency and the reduced recombination rate. This novel concept assists in the comprehension of the regeneration and recombination kinetics and develops highly efficient DSCs.  相似文献   

11.
Rechargeable aqueous zinc‐ion batteries (ZIBs) are promising for cheap stationary energy storage. Challenges for Zn‐ion insertion hosts are the large structural changes of the host structure upon Zn‐ion insertion and the divalent Zn‐ion transport, challenging cycle life and power density respectively. Here a new mechanism is demonstrated for the VO2 cathode toward proton insertion accompanied by Zn‐ion storage through the reversible deposition of Zn4(OH)6SO4·5H2O on the cathode surface, supported by operando X‐ray diffraction, X‐ray photoelectron spectroscopy, neutron activation analysis, and density functional theory simulations. This leads to an initial discharge capacity of 272 mAh g?1 at a current density of 3.0 A g?1, of which 75.5% is maintained after 945 cycles. It is proposed that the competition between proton and Zn‐ion insertion in the VO2 host is determined by the solvation energy of the salt anion and proton insertion energetics, where proton insertion has the advantage of minimal structural distortion leading to a long cycle life. As the discharge kinetics are capacitive for the first half of the process and diffusion limited for the second half, the VO2 cathode takes the middle road possessing both fast kinetics and high practical capacities revealing a reaction mechanism that provides new perspective for the development of aqueous ZIBs.  相似文献   

12.
Driven by increasing demand for high‐energy‐density batteries for consumer electronics and electric vehicles, substantial progress is achieved in the development of long‐life lithium–sulfur (Li–S) batteries. Less attention is given to Li–S batteries with high volume energy density, which is crucial for applications in compact space. Here, a series of elastic sandwich‐structured cathode materials consisting of alternating VS2‐attached reduced graphene oxide (rGO) sheets and active sulfur layers are reported. Due to the high polarity and conductivity of VS2, a small amount of VS2 can suppress the shuttle effect of polysulfides and improve the redox kinetics of sulfur species in the whole sulfur layer. Sandwich‐structured rGO–VS2/S composites exhibit significantly improved electrochemical performance, with high discharge capacities, low polarization, and excellent cycling stability compared with their bare rGO/S counterparts. Impressively, the tap density of rGO–VS2/S with 89 wt% sulfur loading is 1.84 g cm?3, which is almost three times higher than that of rGO/S with the same sulfur content (0.63 g cm?3), and the volumetric specific capacity of the whole cell is as high as 1182.1 mA h cm?3, comparable with the state‐of‐the‐art reported for energy storage devices, demonstrating the potential for application of these composites in long‐life and high‐energy‐density Li–S batteries.  相似文献   

13.
Rechargeable magnesium batteries (RMBs) are attractive candidates for large‐scale energy storage owing to the high theoretical specific capacity, rich earth abundance, and good safety characteristics. However, the development of desirable cathode materials for RMBs is constrained by the high polarity and slow intercalation kinetics of Mg2+ ions. Herein, it is demonstrated that 2‐ethylhexylamine pillared vanadium disulfide nanoflowers (expanded VS2) with enlarged interlayer distances exhibit greatly boosted electrochemical performance as a cathode material in RMBs. Through a one‐step solution‐phase synthesis and in situ 2‐ethylhexylamine intercalation process, VS2 nanoflowers with ultralarge interlayer spacing are prepared. A series of ex situ characterizations verify that the cathode of expanded VS2 nanoflowers undergoes a reversible intercalation reaction mechanism, followed by a conversion reaction mechanism. Electrochemical kinetics analysis reveal a relatively fast Mg‐ion diffusivity of expanded VS2 nanoflowers in the order of 10?11–10?12 cm2 s?1, and the pseudocapacitive contribution is up to 64% for the total capacity at 1 mV s?1. The expanded VS2 nanoflowers show highly reversible discharge capacity (245 mAh g?1 at 100 mA g?1), good rate capability (103 mAh g?1 at 2000 mA g?1), and stable cycling performance (90 mAh g?1 after 600 cycles at 1000 mA g?1).  相似文献   

14.
Potassium‐ion hybrid capacitors (PIHCs), elaborately integrate the advantages of high output power as well as long lifespan of supercapacitors and the high energy density of batteries, and exhibit great possibilities for the future generations of energy storage devices. The critical next step for future implementation lies in exploring a high‐rate battery‐type anode with an ultra‐stable structure to match the capacitor‐type cathode. Herein, a “dual‐carbon” is constructed, in which a three‐dimensional nitrogen‐doped microporous carbon polyhedron (NMCP) derived from metal‐organic frameworks is tightly wrapped by two‐dimensional reduced graphene oxide (NMCP@rGO). Benefiting from the synergistic effect of the inner NMCP and outer rGO, the NMCP@rGO exhibits a superior K‐ion storage capability with a high reversible capacity of 386 mAh g?1 at 0.05 A g?1 and ultra‐long cycle stability with a capacity of 151.4 mAh g?1 after 6000 cycles at 5.0 A g?1. As expected, the as‐assembled PIHCs with a working voltage as high as 4.2 V present a high energy/power density (63.6 Wh kg?1 at 19 091 W kg?1) and excellent capacity retention of 84.7% after 12 000 cycles. This rational construction of advanced PIHCs with excellent performance opens a new avenue for further application and development.  相似文献   

15.
Despite their high theoretical energy density and low cost, lithium–sulfur batteries (LSBs) suffer from poor cycle life and low energy efficiency owing to the polysulfides shuttle and the electronic insulating nature of sulfur. Conductivity and polarity are two critical parameters for the search of optimal sulfur host materials. However, their role in immobilizing polysulfides and enhancing redox kinetics for long‐life LSBs are not fully understood. This work has conducted an evaluation on the role of polarity over conductivity by using a polar but nonconductive platelet ordered mesoporous silica (pOMS) and its replica platelet ordered mesoporous carbon (pOMC), which is conductive but nonpolar. It is found that the polar pOMS/S cathode with a sulfur mass fraction of 80 wt% demonstrates outstanding long‐term cycle stability for 2000 cycles even at a high current density of 2C. Furthermore, the pOMS/S cathode with a high sulfur loading of 6.5 mg cm?2 illustrates high areal and volumetric capacities with high capacity retention. Complementary physical and electrochemical probes clearly show that surface polarity and structure are more dominant factors for sulfur utilization efficiency and long‐life, while the conductivity can be compensated by the conductive agent involved as a required electrode material during electrode preparation. The present findings shed new light on the design principles of sulfur hosts towards long‐life and highly efficient LSBs.  相似文献   

16.
Aqueous rechargeable zinc ion batteries are considered a promising candidate for large‐scale energy storage owing to their low cost and high safety nature. A composite material comprised of H2V3O8 nanowires (NWs) wrapped by graphene sheets and used as the cathode material for aqueous rechargeable zinc ion batteries is developed. Owing to the synergistic merits of desirable structural features of H2V3O8 NWs and high conductivity of the graphene network, the H2V3O8 NW/graphene composite exhibits superior zinc ion storage performance including high capacity of 394 mA h g?1 at 1/3 C, high rate capability of 270 mA h g?1 at 20 C and excellent cycling stability of up to 2000 cycles with a capacity retention of 87%. The battery offers a high energy density of 168 W h kg?1 at 1/3 C and a high power density of 2215 W kg?1 at 20 C (calculated based on the total weight of H2V3O8 NW/graphene composite and the theoretically required amount of Zn). Systematic structural and elemental characterization confirm the reversible Zn2+ and water cointercalation electrochemical reaction mechanism. This work brings a new prospect of designing high‐performance aqueous rechargeable zinc ion batteries for grid‐scale energy storage.  相似文献   

17.
Delivery of high‐energy density with long cycle life is facing a severe challenge in developing cathode materials for rechargeable sodium‐ion batteries (SIBs). Here a composite Na0.6MnO2 with layered–tunnel structure combining intergrowth morphology of nanoplates and nanorods for SIBs, which is clearly confirmed by micro scanning electron microscopy, high‐resolution transmission electron microscopy as well as scanning transmission electron microscopy with atomic resolution is presented. Owing to the integrated advantages of P2 layered structure with high capacity and that of the tunnel structure with excellent cycling stability and superior rate performance, the composite electrode delivers a reversible discharge capacity of 198.2 mAh g?1 at 0.2C rate, leading to a high‐energy density of 520.4 Wh kg?1. This intergrowth integration engineering strategy may modulate the physical and chemical properties in oxide cathodes and provide new perspectives on the optimal design of high‐energy density and high‐stable materials for SIBs.  相似文献   

18.
Na‐based batteries have long been regarded as an inexpensive, sustainable candidate for large‐scale stationary energy storage applications. Unfortunately, the market penetration of conventional Na‐NiCl2 batteries is approaching its limit for several reasons, including limited rate capability and high Ni cost. Herein, a Na‐FeCl2 battery operating at 190 °C is reported that allows a capacity output of 116 mAh g?1 at an extremely high current density of 33.3 mA cm?2 (≈0.6C). The superior rate performance is rooted in the intrinsically fast kinetics of the Fe/Fe2+ redox reaction. Furthermore, it is demonstrated that a small amount of Ni additive (10 mol%) effectively mitigates capacity fading of the Fe/NaCl cathode caused by Fe particle pulverization during long‐term cycling. The modified Fe/Ni cathode exhibits excellent cycling stability, maintaining a discharge energy density of over 295 Wh kg?1 for 200 cycles at 10 mA cm?2 (≈C/5).  相似文献   

19.
The use of selenium as a cathode in rechargeable sodium–selenium batteries is hampered by low Se loading, inferior electrode kinetics, and polyselenide shuttling between the cathode and anode. Here a high‐performance sodium–selenium cell is presented by coupling a binder‐free, self‐interwoven carbon nanofiber–selenium cathode with a light‐weight carbon‐coated bifunctional separator. With this strategy, electrodes with a high Se mass loading (4.4 mg cm?2) render high reversible capacities of 599 mA h g?1 at 0.1C rate and 382 mA h g?1 at 5C rate. In addition, this novel cell offers good shelf‐life with a low self‐discharge, retaining 93.4% of its initial capacity even after resting for six months. As evidenced by experimental and density functional theory analysis, the remarkable dynamic (cycle life) and static (shelf‐life) stabilities originate from the high electrical conductivity, improved Na‐ion accessibility through the 3D interconnected open channels, and highly restrained polyselenide shuttle. The results demonstrate the viability of high‐performance sodium–selenium batteries with high selenium loading.  相似文献   

20.
Sodium‐ion batteries are considered as a promising technology for large‐scale energy storage applications, owing to their low cost. However, there are many challenges for developing sodium‐ion batteries with high capacity, long cycle life, and high‐rate capability. Herein, the development of high‐performance sodium‐ion batteries using ZnS nanospheres as anode material and an ether‐based electrolyte, which exhibit improved electrochemical performance over the pure alkyl carbonate electrolytes, is reported. ZnS nanospheres deliver a high specific capacity of 1000 mA h g?1 and high initial Columbic efficiency of 90%. Electrochemical testing and first‐principle calculations demonstrate that the ether‐based solvent can facilitate charge transport, reduce the energy barrier for sodium‐ion diffusion, and thus enhance electrochemical performances. Ex situ measurements (X‐ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) mapping) reveal that ZnS nanospheres maintain structural integrity during the charge and discharge processes over 100 cycles. As anode material for sodium‐ion batteries, ZnS nanospheres deliver high reversible sodium storage capacity, high Coulombic efficiencies, and extended cycle life.  相似文献   

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