共查询到3条相似文献,搜索用时 0 毫秒
1.
2.
A Flexible Porous Carbon Nanofibers‐Selenium Cathode with Superior Electrochemical Performance for Both Li‐Se and Na‐Se Batteries 下载免费PDF全文
Linchao Zeng Wencong Zeng Yu Jiang Xiang Wei Weihan Li Chenglong Yang Yanwu Zhu Yan Yu 《Liver Transplantation》2015,5(4)
A flexible and free‐standing porous carbon nanofibers/selenium composite electrode (Se@PCNFs) is prepared by infiltrating Se into mesoporous carbon nanofibers (PCNFs). The porous carbon with optimized mesopores for accommodating Se can synergistically suppress the active material dissolution and provide mechanical stability needed for the film. The Se@PCNFs electrode exhibits exceptional electrochemical performance for both Li‐ion and Na‐ion storage. In the case of Li‐ion storage, it delivers a reversible capacity of 516 mAh g?1 after 900 cycles without any capacity loss at 0.5 A g?1. Se@PCNFs still delivers a reversible capacity of 306 mAh g?1 at 4 A g?1. While being used in Na‐Se batteries, the composite electrode maintains a reversible capacity of 520 mAh g?1 after 80 cycles at 0.05 A g?1 and a rate capability of 230 mAh g?1 at 1 A g?1. The high capacity, good cyclability, and rate capability are attributed to synergistic effects of the uniform distribution of Se in PCNFs and the 3D interconnected PCNFs framework, which could alleviate the shuttle reaction of polyselenides intermediates during cycling and maintain the perfect electrical conductivity throughout the electrode. By rational and delicate design, this type of self‐supported electrodes may hold great promise for the development of Li‐Se and Na‐Se batteries with high power and energy densities. 相似文献
3.
3D Porous Carbon Sheets with Multidirectional Ion Pathways for Fast and Durable Lithium–Sulfur Batteries 下载免费PDF全文
In this work, unique porous carbon sheets (PCSs) are developed via a facile synthesis. The obtained PCS delivers long‐range conductive framework, abundant active interfaces, rich element doping, and notably a high inner porosity that builds up an admirable 3D network for multidirectional ion transfer. Such unique architecture and surface chemistry enable ultrafast sulfur electrochemistry as well as high‐efficiency inhibition on polysulfide shuttling via the dually physical and chemical sulfur confinement. The PCS‐based sulfur electrodes achieve superb rate capability up to 10 C, outstanding cyclability over 1000 cycles, and high areal capacity of 4.8 mA h cm?2. This work offers an appealing model of material engineering for fast and reliable lithium–sulfur batteries, as well as guidance for rational structural design in extended energy storage and conversion systems. 相似文献