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1.
This study aims to estimate the three greenhouse gas (GHG) emissions (i.e. CO2, CH4, N2O) from a vertical subsurface flow constructed wetland (VSSF CW, 1000 m2) and a cluster of conventional wastewater treatment plants (WWTPs) in the city of Changzhou, China. The two estimated emissions are set up for comparison. The results show that the WWTP system emits 7.3 kg CO2-eq to remove 1 kg BOD in the studied life cycle, while the VSSF system only emits 3.18 kg CO2-eq, which is only half of the amount given off by the WWTP system. Especially at the treatment stage, the WWTP system's GHG emissions are almost 7 times higher than the VSSF system's. N2O emissions in both systems are only a minor fraction of the total emissions. Therefore, this study has concluded that the VSSF system is an effective option for GHG emissions mitigation in the wastewater sector. The study further suggests that developing countries like China should extensively build up VSSF systems for decentralized wastewater treatment, which could also potentially reduce GHG emissions by 8-17 million ton CO2-eq per year compared with the centralized scenario.  相似文献   

2.
Wetlands can influence global climate via greenhouse gas (GHG) exchange of carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O). Few studies have quantified the full GHG budget of wetlands due to the high spatial and temporal variability of fluxes. We report annual open‐water diffusion and ebullition fluxes of CO2, CH4, and N2O from a restored emergent marsh ecosystem. We combined these data with concurrent eddy‐covariance measurements of whole‐ecosystem CO2 and CH4 exchange to estimate GHG fluxes and associated radiative forcing effects for the whole wetland, and separately for open‐water and vegetated cover types. Annual open‐water CO2, CH4, and N2O emissions were 915 ± 95 g C‐CO2 m?2 yr?1, 2.9 ± 0.5 g C‐CH4 m?2 yr?1, and 62 ± 17 mg N‐N2O m?2 yr?1, respectively. Diffusion dominated open‐water GHG transport, accounting for >99% of CO2 and N2O emissions, and ~71% of CH4 emissions. Seasonality was minor for CO2 emissions, whereas CH4 and N2O fluxes displayed strong and asynchronous seasonal dynamics. Notably, the overall radiative forcing of open‐water fluxes (3.5 ± 0.3 kg CO2‐eq m?2 yr?1) exceeded that of vegetated zones (1.4 ± 0.4 kg CO2‐eq m?2 yr?1) due to high ecosystem respiration. After scaling results to the entire wetland using object‐based cover classification of remote sensing imagery, net uptake of CO2 (?1.4 ± 0.6 kt CO2‐eq yr?1) did not offset CH4 emission (3.7 ± 0.03 kt CO2‐eq yr?1), producing an overall positive radiative forcing effect of 2.4 ± 0.3 kt CO2‐eq yr?1. These results demonstrate clear effects of seasonality, spatial structure, and transport pathway on the magnitude and composition of wetland GHG emissions, and the efficacy of multiscale flux measurement to overcome challenges of wetland heterogeneity.  相似文献   

3.
《Global Change Biology》2018,24(5):1843-1872
Central European grasslands are characterized by a wide range of different management practices in close geographical proximity. Site‐specific management strategies strongly affect the biosphere–atmosphere exchange of the three greenhouse gases (GHG) carbon dioxide (CO2), nitrous oxide (N2O), and methane (CH4). The evaluation of environmental impacts at site level is challenging, because most in situ measurements focus on the quantification of CO2 exchange, while long‐term N2O and CH4 flux measurements at ecosystem scale remain scarce. Here, we synthesized ecosystem CO2, N2O, and CH4 fluxes from 14 managed grassland sites, quantified by eddy covariance or chamber techniques. We found that grasslands were on average a CO2 sink (−1,783 to −91 g CO2 m−2 year−1), but a N2O source (18–638 g CO2‐eq. m−2 year−1), and either a CH4 sink or source (−9 to 488 g CO2‐eq. m−2 year−1). The net GHG balance (NGB) of nine sites where measurements of all three GHGs were available was found between −2,761 and −58 g CO2‐eq. m−2 year−1, with N2O and CH4 emissions offsetting concurrent CO2 uptake by on average 21 ± 6% across sites. The only positive NGB was found for one site during a restoration year with ploughing. The predictive power of soil parameters for N2O and CH4 fluxes was generally low and varied considerably within years. However, after site‐specific data normalization, we identified environmental conditions that indicated enhanced GHG source/sink activity (“sweet spots”) and gave a good prediction of normalized overall fluxes across sites. The application of animal slurry to grasslands increased N2O and CH4 emissions. The N2O‐N emission factor across sites was 1.8 ± 0.5%, but varied considerably at site level among the years (0.1%–8.6%). Although grassland management led to increased N2O and CH4 emissions, the CO2 sink strength was generally the most dominant component of the annual GHG budget.  相似文献   

4.
Drained organic soils are among the most risky soil types as far as their greenhouse gas emissions are considered. Reed canary grass (RCG) is a potential bioenergy crop in the boreal region, but the atmospheric impact of its cultivation is unknown. The fluxes of N2O and CH4 were measured from an abandoned peat extraction site (an organic soil) cultivated with RCG using static chamber and snow gradient techniques. The fluxes were measured also at an adjacent site which is under active peat extraction and it is devoid of any vegetation (BP site). The 4-year average annual N2O emissions were low being 0.1 and 0.01 g N2O m−2 a−1 at the RCG and BP sites, respectively. The corresponding mean annual CH4 emissions from the RCG and BP sites were also low (0.4 g and 0.9 g CH4 m−2 a−1). These results highlight for the first time that there are organic soils where cultivation of perennial bioenergy crops is possible with low N2O and CH4 emissions.  相似文献   

5.
Rapid, precise, and globally comparable methods for monitoring greenhouse gas (GHG) fluxes are required for accurate GHG inventories from different cropping systems and management practices. Manual gas sampling followed by gas chromatography (GC) is widely used for measuring GHG fluxes in agricultural fields, but is laborious and time‐consuming. The photo‐acoustic infrared gas monitoring system (PAS) with on‐line gas sampling is an attractive option, although it has not been evaluated for measuring GHG fluxes in cereals in general and rice in particular. We compared N2O, CO2, and CH4 fluxes measured by GC and PAS from agricultural fields under the rice–wheat and maize–wheat systems during the wheat (winter), and maize/rice (monsoon) seasons in Haryana, India. All the PAS readings were corrected for baseline drifts over time and PAS‐CH4 (PCH4) readings in flooded rice were corrected for water vapor interferences. The PCH4 readings in ambient air increased by 2.3 ppm for every 1000 mg cm?3 increase in water vapor. The daily CO2, N2O, and CH4 fluxes measured by GC and PAS from the same chamber were not different in 93–98% of all the measurements made but the PAS exhibited greater precision for estimates of CO2 and N2O fluxes in wheat and maize, and lower precision for CH4 flux in rice, than GC. The seasonal GC‐ and PAS‐N2O (PN2O) fluxes in wheat and maize were not different but the PAS‐CO2 (PCO2) flux in wheat was 14–39% higher than that of GC. In flooded rice, the seasonal PCH4 and PN2O fluxes across N levels were higher than those of GC‐CH4 and GC‐N2O fluxes by about 2‐ and 4fold, respectively. The PAS (i) proved to be a suitable alternative to GC for N2O and CO2 flux measurements in wheat, and (ii) showed potential for obtaining accurate measurements of CH4 fluxes in flooded rice after making correction for changes in humidity.  相似文献   

6.
The magnitude, temporal, and spatial patterns of soil‐atmospheric greenhouse gas (hereafter referred to as GHG) exchanges in forests near the Tropic of Cancer are still highly uncertain. To contribute towards an improvement of actual estimates, soil‐atmospheric CO2, CH4, and N2O fluxes were measured in three successional subtropical forests at the Dinghushan Nature Reserve (hereafter referred to as DNR) in southern China. Soils in DNR forests behaved as N2O sources and CH4 sinks. Annual mean CO2, N2O, and CH4 fluxes (mean±SD) were 7.7±4.6 Mg CO2‐C ha?1 yr?1, 3.2±1.2 kg N2O‐N ha?1 yr?1, and 3.4±0.9 kg CH4‐C ha?1 yr?1, respectively. The climate was warm and wet from April through September 2003 (the hot‐humid season) and became cool and dry from October 2003 through March 2004 (the cool‐dry season). The seasonality of soil CO2 emission coincided with the seasonal climate pattern, with high CO2 emission rates in the hot‐humid season and low rates in the cool‐dry season. In contrast, seasonal patterns of CH4 and N2O fluxes were not clear, although higher CH4 uptake rates were often observed in the cool‐dry season and higher N2O emission rates were often observed in the hot‐humid season. GHG fluxes measured at these three sites showed a clear increasing trend with the progressive succession. If this trend is representative at the regional scale, CO2 and N2O emissions and CH4 uptake in southern China may increase in the future in light of the projected change in forest age structure. Removal of surface litter reduced soil CO2 effluxes by 17–44% in the three forests but had no significant effect on CH4 absorption and N2O emission rates. This suggests that microbial CH4 uptake and N2O production was mainly related to the mineral soil rather than in the surface litter layer.  相似文献   

7.
Denitrification beds are a simple approach for removing nitrate (NO3) from a range of point sources prior to discharge into receiving waters. These beds are large containers filled with woodchips that act as an energy source for microorganisms to convert NO3 to nitrogen (N) gases (N2O, N2) through denitrification. This study investigated the biological mechanism of NO3 removal, its controlling factors and its adverse effects in a large denitrification bed (176 m × 5 m × 1.5 m) receiving effluent with a high NO3 concentration (>100 g N m−3) from a hydroponic glasshouse (Karaka, Auckland, New Zealand). Samples of woodchips and water were collected from 12 sites along the bed every two months for one year, along with measurements of gas fluxes from the bed surface. Denitrifying enzyme activity (DEA), factors limiting denitrification (availability of carbon, dissolved organic carbon (DOC), dissolved oxygen (DO), temperature, pH, and concentrations of NO3, nitrite (NO2) and sulfide (S2−)), greenhouse gas (GHG) production - as nitrous oxide (N2O), methane (CH4), carbon dioxide (CO2) - and carbon (C) loss were determined. NO3-N concentration declined along the bed with total NO3-N removal rates of 10.1 kg N d−1 for the whole bed or 7.6 g N m−3 d−1. NO3-N removal rates increased with temperature (Q10 = 2.0). In laboratory incubations, denitrification was always limited by C availability rather than by NO3. DO levels were above 0.5 mg L−1 at the inlet but did not limit NO3-N removal. pH increased steadily from about 6 to 7 along the length of the bed. Dissolved inorganic carbon (C-CO2) increased in average about 27.8 mg L−1, whereas DOC decreased slightly by about 0.2 mg L−1 along the length of the bed. The bed surface emitted on average 78.58 μg m−2 min−1 N2O-N (reflecting 1% of the removed NO3-N), 0.238 μg m−2 min−1 CH4 and 12.6 mg m−2 min−1 CO2. Dissolved N2O-N increased along the length of the bed and the bed released on average 362 g dissolved N2O-N per day coupled with N2O emission at the surface about 4.3% of the removed NO3-N as N2O. Mechanisms to reduce the production of this GHG need to be investigated if denitrification beds are commonly used. Dissolved CH4 concentrations showed no trends along the length of the bed, ranging from 5.28 μg L−1 to 34.24 μg L−1. Sulfate (SO42−) concentrations declined along the length of the bed on three of six samplings; however, declines in SO42− did not appear to be due to SO42− reduction because S2− concentrations were generally undetectable. Ammonium (NH4+) (range: <0.0007 mg L−1 to 2.12 mg L−1) and NO2 concentrations (range: 0.0018 mg L−1 to 0.95 mg L−1) were always very low suggesting that anammox was an unlikely mechanism for NO3 removal in the bed. C longevity was calculated from surface emission rates of CO2 and release of dissolved carbon (DC) and suggested that there would be ample C available to support denitrification for up to 39 years.This study showed that denitrification beds can be an efficient tool for reducing high NO3 concentrations in effluents but did produce some GHGs. Over the course of a year NO3 removal rates were always limited by C and temperature and not by NO3 or DO concentration.  相似文献   

8.
Background and aims

The litter layer is a major source of CO2, and it also influences soil-atmosphere exchange of N2O and CH4. So far, it is not clear how much of soil greenhouse gas (GHG) emission derives from the litter layer itself or is litter-induced. The present study investigates how the litter layer controls soil GHG fluxes and microbial decomposer communities in a temperate beech forest.

Methods

We removed the litter layer in an Austrian beech forest and studied responses of soil CO2, CH4 and N2O fluxes and the microbial community via phospholipid fatty acids (PLFA). Soil GHG fluxes were determined with static chambers on 22 occasions from July 2012 to February 2013, and soil samples collected at 8 sampling events.

Results

Litter removal reduced CO2 emissions by 30 % and increased temperature sensitivity (Q10) of CO2 fluxes. Diffusion of CH4 into soil was facilitated by litter removal and CH4 uptake increased by 16 %. This effect was strongest in autumn and winter when soil moisture was high. Soils without litter turned from net N2O sources to slight N2O sinks because N2O emissions peaked after rain events in summer and autumn, which was not the case in litter-removal plots. Microbial composition was only transiently affected by litter removal but strongly influenced by seasonality.

Conclusions

Litter layers must be considered in calculating forest GHG budgets, and their influence on temperature sensitivity of soil GHG fluxes taken into account for future climate scenarios.

  相似文献   

9.
In order to identify the effects of land-use/cover types, soil types and soil properties on the soil-atmosphere exchange of greenhouse gases (GHG) in semiarid grasslands as well as provide a reliable estimate of the midsummer GHG budget, nitrous oxide (N2O), methane (CH4) and carbon dioxide (CO2) fluxes of soil cores from 30 representative sites were determined in the upper Xilin River catchment in Inner Mongolia. The soil N2O emissions across all of the investigated sites ranged from 0.18 to 21.8 μg N m-2 h-1, with a mean of 3.4 μg N m-2 h-1 and a coefficient of variation (CV, which is given as a percentage ratio of one standard deviation to the mean) as large as 130%. CH4 fluxes ranged from -88.6 to 2,782.8 μg C m-2 h-1 (with a CV of 849%). Net CH4 emissions were only observed from cores taken from a marshland site, whereas all of the other 29 investigated sites showed net CH4 uptake (mean: -33.3 μg C m-2 h-1). CO2 emissions from all sites ranged from 3.6 to 109.3 mg C m-2 h-1, with a mean value of 37.4 mg C m-2 h-1 and a CV of 66%. Soil moisture primarily and positively regulated the spatial variability in N2O and CO2 emissions (R2?=?0.15–0.28, P?<?0.05). The spatial variation of N2O emissions was also influenced by soil inorganic N contents (P?<?0.05). By simply up-scaling the site measurements by the various land-use/cover types to the entire catchment area (3,900 km2), the fluxes of N2O, CH4 and CO2 at the time of sampling (mid-summer 2007) were estimated at 29 t CO2-C-eq d-1, -26 t CO2-C-eq d-1 and 3,223 t C d-1, respectively. This suggests that, in terms of assessing the spatial variability of total GHG fluxes from the soils at a semiarid catchment/region, intensive studies may focus on CO2 exchange, which is dominating the global warming potential of midsummer soil-atmosphere GHG fluxes. In addition, average GHG fluxes in midsummer, weighted by the areal extent of these land-use/cover types in the region, were approximately -30.0 μg C m-2 h-1 for CH4, 2.4 μg N m-2 h-1 for N2O and 34.5 mg C m-2 h-1 for CO2.  相似文献   

10.
Greenhouse gases (GHG) can be affected by grazing intensity, soil, and climate variables. This study aimed at assessing GHG emissions from a tropical pasture of Brazil to evaluate (i) how the grazing intensity affects the magnitude of GHG emissions; (ii) how season influences GHG production and consumption; and (iii) what are the key driving variables associated with GHG emissions. We measured under field conditions, during two years in a palisade-grass pasture managed with 3 grazing intensities: heavy (15 cm height), moderate (25 cm height), and light (35 cm height) N2O, CH4 and CO2 fluxes using static closed chambers and chromatographic quantification. The greater emissions occurred in the summer and the lower in the winter. N2O, CH4, and CO2 fluxes varied according to the season and were correlated with pasture grazing intensity, temperature, precipitation, % WFPS (water-filled pores space), and soil inorganic N. The explanatory variables differ according to the gas and season. Grazing intensity had a negative linear effect on annual cumulative N2O emissions and a positive linear effect on annual cumulative CO2 emissions. Grazing intensity, season, and year affected N2O, CH4, and CO2 emissions. Tropical grassland can be a large sink of N2O and CH4. GHG emissions were explained for different key driving variables according to the season.  相似文献   

11.
Sheepfolds represent significant hot spot sources of greenhouse gases (GHG) in semi-arid grassland regions, such as Inner Mongolia in China. However, the annual contribution of sheepfolds to regional GHG emissions is still unknown. In order to quantify its annual contribution, we conducted measurements of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) fluxes at two sheepfold sites in the Baiyinxile administrative region of Inner Mongolia for 1 year, using static opaque chamber and gas chromatography methods. Our data show that, at an annual scale, both sheepfolds functioned as net sources of CO2, CH4 and N2O. Temperatures primarily determined the seasonal pattern of CO2 emission; 60–84% of the CO2 flux variation could be explained by temperature changes. High rates of net CH4 emissions from sheepfold soils were only observed when animals (sheep and goats) were present. While nitrous oxide emissions were also stimulated by the presence of animals, pulses of N2O emissions were also be related to rainfall and spring-thaw events. The total annual cumulative GHG emissions in CO2 equivalents (CO2: 1; CH4: 25; and N2O: 298) were quantified as 87.4?±?18.4 t ha?1 for the sheepfold that was used during the non-grazing period (i.e., winter sheepfold) and 136.7?±?15.9 t ha?1 used during the grazing period (i.e., summer sheepfold). Of the annual total GHG emissions, CH4 release accounted for approximately 1% of emissions, while CO2 and N2O emissions contributed to approximately 59% and 40%, respectively. The total GHG emission factor (CO2?+?CH4?+?N2O) per animal for the sheepfolds investigated in this study was 30.3 kg CO2 eq yr?1 head?1, which translates to 0.3, 18.8 and 11.2 kg CO2 eq yr?1 head?1 for CH4, CO2 and N2O, respectively. Sheepfolds accounted for approximately 34% of overall N2O emissions in the Baiyinxile administrative region, a typical steppe region within Inner Mongolia. The contribution of sheepfolds to the regional CO2 or CH4 exchange is marginal.  相似文献   

12.
Zhang W  Mo J M  Fang Y T  Lu X K  Wang H 《农业工程》2008,28(5):2309-2319
Nitrogen (N) deposition can alter the rates of microbial N- and C- turnover, and thus can affect the fluxes of greenhouse gases (GHG, e.g., CO2, CH4, and N2O) from forest soils. The effects of N deposition on the GHG fluxes from forest soils were reviewed in this paper. N deposition to forest soils have shown variable effects on the soil GHG fluxes from forest, including increases, decreases or unchanged rates depending on forest type, N status of the soil, and the rate and type of atmospheric N deposition. In forest ecosystems where biological processes are limited by N supply, N additions either stimulate soil respiration or have no significant effect, whereas in “N saturated” forest ecosystems, N additions decrease CO2 emission, reduce CH4 oxidation and elevate N2O flux from the soil. The mechanisms and research methods about the effects of N deposition on GHG fluxes from forest soils were also reviewed in this paper. Finally, the present and future research needs about the effects of N deposition on the GHG fluxes from forest soils were discussed.  相似文献   

13.
To investigate the water-air diffusive greenhouse gases (GHGs) fluxes from the Three Gorges Reservoir (TGR), a field experiment on carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) fluxes from water surface was carried out from March 2011 to August 2012 by floating static chamber method. The results showed that CO2 was released to the atmosphere all the time and was less in autumn than in other seasons (P < 0.05). CH4 was also released to the atmosphere throughout the year but more in summer than other three seasons (P < 0.05). N2O flux was higher in autumn than other seasons (P < 0.05), and N2O was absorbed from the atmosphere mainly in summer. Moreover, correlation analysis illustrated that CO2 flux had significantly negative correlation with wind velocity (P < 0.05), whereas positive correlation with pH (P < 0.01) had been found. There was no significant correlation between CH4 (or N2O) flux and the measured environmental variables respectively (P > 0.05). Additionally, the annual fluxes of CO2, CH4 and N2O were 140.45 ± 12.57 mg CO2·m?2 h?1, 1.35 ± 0.14 mg CH4·m?2 h?1 and 34.34 ± 11.64 μg N2O·m?2 h?1, respectively. When compared to other reservoirs worldwide, the CO2 and N2O fluxes from TGR were higher than those from boreal and temperate reservoirs, but much lower than those from tropical reservoirs. CH4 flux was lower than those from boreal, temperate and most tropical reservoirs. In our study, the surface area of the TGR emitted 1.42 × 106 t CO2, 1.19 × 104 t CH4 and 589.93 t N2O in a year. The total GWP was 17.68 t CO2-eq ha?1 yr?1, of which CO2 flux was dominant (74.38%). Therefore, CO2 was the main contributor of GHGs fluxes in our study and thus future researches should focus on how to reduce CO2 fluxes from the surface of the TGR. TGR has a considerable contribution to regional GHG emissions.  相似文献   

14.
Rapid climate change and intensified human activities have resulted in water table lowering (WTL) and enhanced nitrogen (N) deposition in Tibetan alpine wetlands. These changes may alter the magnitude and direction of greenhouse gas (GHG) emissions, affecting the climate impact of these fragile ecosystems. We conducted a mesocosm experiment combined with a metagenomics approach (GeoChip 5.0) to elucidate the effects of WTL (?20 cm relative to control) and N deposition (30 kg N ha?1 yr?1) on carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) fluxes as well as the underlying mechanisms. Our results showed that WTL reduced CH4 emissions by 57.4% averaged over three growing seasons compared with no‐WTL plots, but had no significant effect on net CO2 uptake or N2O flux. N deposition increased net CO2 uptake by 25.2% in comparison with no‐N deposition plots and turned the mesocosms from N2O sinks to N2O sources, but had little influence on CH4 emissions. The interactions between WTL and N deposition were not detected in all GHG emissions. As a result, WTL and N deposition both reduced the global warming potential (GWP) of growing season GHG budgets on a 100‐year time horizon, but via different mechanisms. WTL reduced GWP from 337.3 to ?480.1 g CO2‐eq m?2 mostly because of decreased CH4 emissions, while N deposition reduced GWP from 21.0 to ?163.8 g CO2‐eq m?2, mainly owing to increased net CO2 uptake. GeoChip analysis revealed that decreased CH4 production potential, rather than increased CH4 oxidation potential, may lead to the reduction in net CH4 emissions, and decreased nitrification potential and increased denitrification potential affected N2O fluxes under WTL conditions. Our study highlights the importance of microbial mechanisms in regulating ecosystem‐scale GHG responses to environmental changes.  相似文献   

15.
Biochar application to soils may increase carbon (C) sequestration due to the inputs of recalcitrant organic C. However, the effects of biochar application on the soil greenhouse gas (GHG) fluxes appear variable among many case studies; therefore, the efficacy of biochar as a carbon sequestration agent for climate change mitigation remains uncertain. We performed a meta‐analysis of 91 published papers with 552 paired comparisons to obtain a central tendency of three main GHG fluxes (i.e., CO2, CH4, and N2O) in response to biochar application. Our results showed that biochar application significantly increased soil CO2 fluxes by 22.14%, but decreased N2O fluxes by 30.92% and did not affect CH4 fluxes. As a consequence, biochar application may significantly contribute to an increased global warming potential (GWP) of total soil GHG fluxes due to the large stimulation of CO2 fluxes. However, soil CO2 fluxes were suppressed when biochar was added to fertilized soils, indicating that biochar application is unlikely to stimulate CO2 fluxes in the agriculture sector, in which N fertilizer inputs are common. Responses of soil GHG fluxes mainly varied with biochar feedstock source and soil texture and the pyrolysis temperature of biochar. Soil and biochar pH, biochar applied rate, and latitude also influence soil GHG fluxes, but to a more limited extent. Our findings provide a scientific basis for developing more rational strategies toward widespread adoption of biochar as a soil amendment for climate change mitigation.  相似文献   

16.
梁东哲  赵雨森  曹杰  辛颖 《生态学报》2019,39(21):7950-7959
为研究大兴安岭重度火烧迹地在不同恢复方式下林地土壤CO2、CH4和N2O排放特征及其影响因素,采用静态箱/气相色谱法,在2017年生长季(6月-9月)对3种恢复方式(人工更新、天然更新和人工促进天然更新)林地土壤温室气体CO2、CH4、N2O通量进行了原位观测。研究结果表明:(1)3种恢复方式林地土壤在生长季均为大气CO2、N2O的源,CH4的汇;生长季林地土壤CO2排放通量大小关系为人工促进天然更新((634.40±246.52)mg m-2 h-1) > 人工更新((603.63±213.22)mg m-2 h-1) > 天然更新((575.81±244.12)mg m-2 h-1),3种恢复方式间无显著差异;人工更新林地土壤CH4吸收通量显著高于人工促进天然更新;天然更新林地土壤N2O排放通量显著高于其他两种恢复方式。(2)土壤温度是影响3种恢复方式林地土壤温室气体通量的关键因素;土壤水分仅对人工更新林地土壤N2O通量有极显著影响(P < 0.01);3种恢复方式林地土壤CO2通量与大气湿度具有极显著的响应(P < 0.01);土壤pH仅与天然更新林地土壤CO2通量显著相关(P < 0.05);土壤全氮含量仅与人工促进天然更新林地土壤CH4通量显著相关(P < 0.05)。(3)基于100年尺度,由3种温室气体计算全球增温潜势得出,人工促进天然更新(1.83×104 kg CO2/hm2) > 人工更新(1.74×104 kg CO2/hm2) > 天然更新(1.67×104 kg CO2/hm2)。(4)阿木尔地区林地土壤年生长季CO2和N2O排放量为8.85×106 t和1.88×102 t,CH4吸收量为1.05×103 t。  相似文献   

17.
Oilseed rape (OSR, Brassica napus L.) is an important feedstock for biodiesel; hence, carbon dioxide (CO2), methane (CH4) and particularly fertilizer‐derived nitrous oxide (N2O) emissions during cultivation must be quantified to assess putative greenhouse gas (GHG) savings, thus creating an urgent and increasing need for such data. Substrates of nitrification [ammonium (NH4)] and denitrification [nitrate (NO3)], the predominant N2O production pathways, were supplied separately and in combination to OSR in a UK field trial aiming to: (i) produce an accurate GHG budget of fertilizer application; (ii) characterize short‐ to medium‐term variation in GHG fluxes; (iii) establish the processes driving N2O emission. Three treatments were applied twice, 1 week apart: ammonium nitrate fertilizer (NH4NO3, 69 kg‐N ha?1) mimicking the farm management, ammonium chloride (NH4Cl, 34.4 kg‐N ha?1) and sodium nitrate (NaNO3, 34.6 kg‐N ha?1). We deployed SkyLine2D for the very first time, a novel automated chamber system to measure CO2, CH4 and N2O fluxes at unprecedented high temporal and spatial resolution from OSR. During 3 weeks following the fertilizer application, CH4 fluxes were negligible, but all treatments were a net sink for CO2 (ca. 100 g CO2 m?2). Cumulative N2O emissions (ca. 120 g CO2‐eq m?2) from NH4NO3 were significantly greater (P < 0.04) than from NaNO3 (ca. 80 g CO2‐eq m?2), but did not differ from NH4Cl (ca. 100 g CO2‐eq m?2) and reduced the carbon sink of photosynthesis so that OSR was a net GHG source in the fertilizer treatment. Diurnal variation in N2O emissions, peaking in the afternoon, was more strongly associated with photosynthetically active radiation (PAR) than temperature. This suggests that the supply of carbon (C) from photosynthate may have been the key driver of the observed diurnal pattern in N2O emission and thus should be considered in future process‐based models of GHG emissions.  相似文献   

18.
《Inorganica chimica acta》2004,357(9):2561-2569
Ni(II), Cu(II), Zn(II) and Cd(II) complexes of an N4-donor Schiff base, containing (CH2)2 as spacer, have been prepared. The X-ray crystal structures of monohelical Ni(ETs) · H2O and the homochirally crystallised Δ-Cu(ETs), as well as the meso-helicate Zn2(ETs)2 · MeCN [H2ETs: N,N-bis(2-tosylaminobenzylidene)-1,2-diaminoethane] have been solved. In the latter, the ligand behaves as bis-bidentate, displaying a “C”-type arrangement, instead of the typical “S”-type fashion present in bis-helical dinuclear complexes.  相似文献   

19.
The effects of nitrogen (N) deposition on soil organic carbon (C) and greenhouse gas (GHG) emissions in terrestrial ecosystems are the main drivers affecting GHG budgets under global climate change. Although many studies have been conducted on this topic, we still have little understanding of how N deposition affects soil C pools and GHG budgets at the global scale. We synthesized a comprehensive dataset of 275 sites from multiple terrestrial ecosystems around the world and quantified the responses of the global soil C pool and GHG fluxes induced by N enrichment. The results showed that the soil organic C concentration and the soil CO2, CH4 and N2O emissions increased by an average of 3.7%, 0.3%, 24.3% and 91.3% under N enrichment, respectively, and that the soil CH4 uptake decreased by 6.0%. Furthermore, the percentage increase in N2O emissions (91.3%) was two times lower than that (215%) reported by Liu and Greaver (Ecology Letters, 2009, 12:1103–1117). There was also greater stimulation of soil C pools (15.70 kg C ha?1 year?1 per kg N ha?1 year?1) than previously reported under N deposition globally. The global N deposition results showed that croplands were the largest GHG sources (calculated as CO2 equivalents), followed by wetlands. However, forests and grasslands were two important GHG sinks. Globally, N deposition increased the terrestrial soil C sink by 6.34 Pg CO2/year. It also increased net soil GHG emissions by 10.20 Pg CO2‐Geq (CO2 equivalents)/year. Therefore, N deposition not only increased the size of the soil C pool but also increased global GHG emissions, as calculated by the global warming potential approach.  相似文献   

20.
温带针阔混交林土壤碳氮气体通量的主控因子与耦合关系   总被引:3,自引:0,他引:3  
中高纬度森林地区由于气候条件变化剧烈,土壤温室气体排放量的估算存在很大的不确定性,并且不同碳氮气体通量的主控因子与耦合关系尚不明确。以长白山温带针阔混交林为研究对象,采用静态箱-气相色谱法连续4a(2005—2009年)测定土壤二氧化碳(CO2)、甲烷(CH4)和氧化亚氮(N2O)净交换通量以及温度、水分等相关环境因子。研究结果表明:温带针阔混交林土壤整体上表现为CO2和N2O的排放源和CH4的吸收汇。土壤CH4、CO2和N2O通量的年均值分别为-1.3 kg CH4hm-2a-1、15102.2 kg CO2hm-2a-1和6.13 kg N2O hm-2a-1。土壤CO2通量呈现明显的季节性规律,主要受土壤温度的影响,水分次之;土壤CH4通量的季节变化不明显,与土壤水分显著正相关;土壤N2O通量季节变化与土壤CO2通量相似,与土壤水分、温度显著正相关。土壤CO2通量和CH4通量不存在任何类型的耦合关系,与N2O通量也不存在耦合关系;土壤CH4和N2O通量之间表现为消长型耦合关系。这项研究显示温带针阔混交林土壤碳氮气体通量主要受环境因子驱动,不同气体通量产生与消耗之间存在复杂的耦合关系,下一步研究需要深入探讨环境变化对其耦合关系的影响以及内在的生物驱动机制。  相似文献   

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