典型固体废物中冶金微生物及其浸出机理研究进展

典型固体废物(废电器、废电池、污泥、焚烧飞灰、废催化剂等)含有大量金属资源，回收再利用的价值极高。微生物浸出典型固体废物受多因素影响。对不同微生物浸出金属的菌种筛选、浸出规律和机理的掌握，有助于典型固体废物中金属资源的绿色高效回收，可为我国“双碳”目标作出贡献。本文综述了从典型固体废物中浸出金属的各类微生物，分析了冶金微生物的作用机制，并展望了微生物冶金的应用前景，以期为微生物冶金技术在典型固体废物中的高效应用提供理论参考。     

异养微生物在金属生物淋滤技术中的应用

生物淋滤技术主要应用于低品位矿石金属选矿、煤气脱硫、废弃物中金属回收和污染介质中金属离子毒性的去除等方面。作为生物淋滤技术中的主体微生物之一,异养微生物可通过其产生的酸性代谢物还原、酸化及络合,提取或者溶解非硫化矿、固体废弃物、污水污泥及土壤中的金属,有助于解决目前的资源短缺问题,还可对污染环境治理提供技术支持,具有重要的理论意义和实践价值。应用于异养微生物淋滤技术中的常见微生物包括细菌(以假单胞菌为主)和真菌(以曲霉菌和青霉菌应用最为广泛)。淋滤过程涉及酸解、络合、还原及碱化等。目前,异养微生物淋滤技术主要应用于生物冶金、固体废弃物处理、污水处理和污染土壤修复等。本文分析了异养微生物金属淋滤过程中的问题,并提出了未来研究的发展方向。     

Bio-recycling of metals: Recycling of technical products using biological applications

The increasing demand of different essential metals as a consequence of the development of new technologies, especially in the so called “low carbon technologies” require the development of innovative technologies that enable an economic and environmentally friendly metal recovery from primary and secondary resources. There is serious concern that the demand of some critical elements might exceed the present supply within a few years, thus necessitating the development of novel strategies and technologies to meet the requirements of industry and society. Besides an improvement of exploitation and processing of ores, the more urgent issue of recycling of strategic metals has to be enforced. However, current recycling rates are very low due to the increasing complexity of products and the low content of certain critical elements, thus hindering an economic metal recovery. On the other hand, increasing environmental consciousness as well as limitations of classical methods require innovative recycling methodologies in order to enable a circular economy. Modern biotechnologies can contribute to solve some of the problems related to metal recycling. These approaches use natural properties of organisms, bio-compounds, and biomolecules to interact with minerals, materials, metals, or metal ions such as surface attachment, mineral dissolution, transformation, and metal complexation. Further, modern genetic approaches, e.g. realized by synthetic biology, enable the smart design of new chemicals. The article presents some recent developments in the fields of bioleaching, biosorption, bioreduction, and bioflotation, and their use for metal recovery from different waste materials. Currently only few of these developments are commercialized. Major limitations are high costs in comparison to conventional methods and low element selectivity. The article discusses future trends to overcome these barriers. Especially interdisciplinary approaches, the combination of different technologies, the inclusion of modern genetic methods, as well as the consideration of existing, yet unexplored natural resources will push innovations in these fields.     

Effects of key parameters in recycling of metals from petroleum refinery waste catalysts in bioleaching process

Environmental laws concerning spent catalysts disposal have become increasingly more severe in recent years. Due to the toxic nature of spent catalysts, their disposal can pollute the environment. The recovery of heavy metals decreases the environmental impact of the waste catalysts and the recycled product can be further used for industrial purposes. Bio-hydrometallurgical approaches, such as bioleaching, appear to offer good prospects for recovering valuable metals from spent refinery catalysts. Currently, identifying and modifying the parameters that influenced the efficiency of bioleaching is important for industrial sector. The biological system can be further improved through optimizing the bioleaching parameters, such as the nutrient culture media, amount of oxygen and carbon dioxide, pH, temperature, inoculum, metal resistance of microorganisms, chemistry of solid waste, particle size of solid waste, solid liquid ratio, bioleaching period, size of substrate, shaking speed, and also the development of more effective bioleaching microorganisms. In our previous review (Asghari et al. in J Ind Eng Chem 19:1069–1081, 2013), information available in the literature on the bioleaching fundamentals of spent catalysts with a focus on recent developments was reviewed in detail. In this study, the effects of most important factors that influence an efficient bioleaching process of spent refinery catalysts with the hope that these valuable and useful data can help determine the most efficient process will be discussed. The details of metals recovery with a focus on the effects of different variables in the bioleaching such as reaction time, pulp density, initial pH, particle size, nutrient concentration, temperature and buffer will also be presented.     

Energy Intensity of the Catalan Construction Sector

We used a thermodynamic framework to characterize the resource consumption of the construction sector in 2001 in Catalonia, the northeast region of Spain. The analysis was done with a cradle‐to‐product life cycle approach using material flow analysis (MFA) and exergy accounting methodologies to quantify the total material and energy inputs in the sector. The aim was to identify the limitations of resource metabolism in the sector and to pinpoint the opportunities for improved material selection criteria, processing, reuse, and recycling for sustainable resource use. The results obtained from MFA showed that nonrenewables such as minerals and natural rocks, cement and derivatives, ceramics, glass, metals, plastics, paints and other chemicals, electric and lighting products, and bituminous mix products accounted for more than 98% of the input materials in the construction sector. The exergy analysis quantified a total 113.1 petajoules (PJ) of exergy inputs in the sector; utilities accounted for 57% of this exergy. Besides exergy inputs, a total of 6.85 million metric tons of construction and demolition waste was generated in 2001. With a recycling rate of 6.5%, the sector recovered 1.3 PJ of exergy. If the sector were able to recycle 80% of construction and demolition waste, then exergy recovery would be 10.3 PJ. Hence the results of this analysis indicate that improvements are required in manufacturing processes and recycling activities, especially of energy‐intensive materials, in order to reduce the inputs of utilities and the extraction of primary materials from the environment.     

长江经济带典型锌冶炼园区不同固废处置模式生态效率研究

我国铜铅锌有色冶炼固废种类多、存量大,富含多种环境毒害元素如镉铬汞砷等,而目前固废末端处置方式单一,对其所含的大量铜铅锌银镍等有价金属组分也未能有效分离,固废污染防控与高效资源化利用问题突出,已成为制约产业绿色可持续发展的关键因素。以长江经济带典型铜铅锌综合冶炼基地为例,设置直接处理(情景1)、内部循环(情景2)和协同利用(情景3)三种锌冶炼固废处置情景模式,结合物质投入产出法、层次分析法与熵值法,构建资源能耗、环境风险、物质循环与经济效益的多维生态效率指标核算方法体系,对三种情景模式开展生态效率综合评估分析。结果表明,情景3因加强了锌冶炼固废在铜、铅冶炼系统间的协同转化,其生态效率综合评价指数最高,为0.2246,较情景1和情景2分别高出313.6%和25.5%;从资源能耗角度来看,情景2单位产品能耗最高,达0.3086;而从物质循环和经济效益角度来看,情景3固废综合利用率最高,达97.6%,铜铅锌三种有价金属回收率达97.2%,利润总额达48131.3万元;但在环境风险方面,尽管情景3固废中重金属污染排放减少1470.4 t/a,但废气中铅砷镉汞等重金属污染排放却比情景1增加了3倍...     

Bioleaching review part B:

This review describes the historical development and current state of metals leaching and sulfide mineral biooxidation by the minerals industries. During the past 20 years commercial processes employing microorganisms for mineral recovery have progressed from rather uncontrolled copper dump leaching to mineral oxidation and leaching in designed bioheaps for oxidation of refractory gold ores and for copper recovery. Also during this period of time, stirred tank bioleaching has been commercialized for cobalt recovery and for biooxidation of refractory gold ores. Chalcopyrite bioleaching in stirred tanks is on the verge of commercialization. Commercial applications of biohydrometallurgy have advanced due to favorable process economics and, in some cases, reduced environmental problems compared to conventional metal recovery processes such as smelting. Process development has included recognition of the importance of aeration of bioheaps, and improvements in stirred tank reactor design and operation. Concurrently, knowledge of the key microorganisms involved in these processes has advanced, aided by advances in molecular biology to characterize microbial populations.     

Urban Mining's Potential to Relieve China's Coming Resource Crisis

China's mineral resource consumption has gone through multiple increases since 1980, resulting in the inadequacy of important strategic resources and a high level of external dependence. Some developed countries have already reduced primary resources consumption through urban mining. Can China also break through the bottleneck of the resource shortage and continue its economic and social development through strengthening of urban mining? This article selected copper (Cu), aluminum (Al), lead (Pb), and iron (Fe) as case studies and established predictive models for metal demand, recycling, and stock, based on stock analysis, material flow analysis, and a life distribution model, and then analyzed the metabolism of the four resources and compared the environmental effects of three scenarios. The study indicates that the urban mining potential of Cu, Fe, Al, and Pb will attain 8.1, 711.6, 37.0, and 12.1 million tonnes, respectively, in 2040. Compared with 2010, the substitution rate (secondary metals substituting primary metals) of Cu and Fe increase by 25.4% and 59.9%, whereas external dependence decreases by 30.8% and 25.7%. However, substitution is not obvious regarding Al and Pb. The low resource scenario decreases resources use, which will reduce external dependence in the short term, whereas the strengthened recovery scenario increases resource recovery and has a larger effect in reducing external dependence in the long term. So, in line with urban mining in the future, China should change its environment and resource strategy, further strengthen layout and construction of urban mining demonstration bases, and encourage the use of recyclable resources to provide a better foundation for urban mining.     

Evaluating heavy metal contents in nine composts using four digestion methods

The production and application of compost potentially contaminate the environment with heavy metals. The heavy metal contents of composts must be exactly determined. Therefore, this study aims to understand the heavy metal contents in composts, using different digestion methods and to recommend the most appropriate digestion method making this measurement. Nine composts from different sources, including swine manure, poultry litter, food waste, municipal sewage sludge, soybean meal, wood residues, flesh-bone dust, fish-bone meal and guano, were selected to be digested by four methods to determine the contents of Cd, Cr, Cu, Mn, Ni, Pb and Zn by AAS. The four digestion methods were nitric acid, dry ashing, nitric-perchloric acid and sulfuric acid methods. Analytical results indicated that the nitric acid procedure was the most efficient for recovering Cd, Mn and Ni from most compost samples. The sulfuric acid procedure yielded the lowest recovery of Pb from the certified reference material (BCR 146) and the compost samples, especially from the composts with high pH and EC values potentially high in Ca. The nitric acid procedure was recommended as the method for digesting the composts herein, based on recovery analysis, cost and time taken. Dry ashing was recommended as a flexible method. Nitric-perchloric acid procedure was not recommended because perchloric acid is potentially hazardous during digestion and it recovers relatively little heavy metal.     

重庆溶溪锰矿区土壤重金属污染评价及植物吸收特征

对重庆溶溪锰矿尾渣堆积区土壤、优势植物以及周边农田土壤的重金属含量(Mn、Cd、Cu、Zn和Pb)进行测定分析,并以重庆市土壤背景值为评价标准,应用Hakanson潜在生态危害指数法对土壤中重金属的潜在生态危害进行了评价。结果表明:该锰矿尾渣堆积区土壤中Mn、Cd、Cu、Zn和Pb的平均含量分别为48382.5、3.91、79.97、131.23和80.68 mg/kg,受到Mn、Cd的严重污染,Mn为强或很强生态危害,Cd为极强生态危害,而Cu、Zn、Pb为轻微生态危害,各尾矿渣堆积区的综合潜在生态危害指数(RI)均远大于720,为极强生态危害。对优势植物重金属含量的分析显示,绝大部分植物地上部Mn、Cd含量都超出正常范围的上限值,而Cu、Zn和Pb含量基本都在正常范围内;根据植物对重金属的吸收特征,将植物分为三类:将重金属主要累积于地上部分的富集型,如垂序商陆(Phytolacca americana L.)和酸模叶蓼(Polygonum lapathifolium Linn.),适用于重金属复合污染土壤的植物修复;将重金属主要累积于根部的根部囤积型,如芒(Miscanthus sinensis Anderss.)和乌蕨(Stenoloma chusanum Ching);重金属含量较低的规避型,如黄花蒿(Artemisia annua L.)、长波叶山蚂蝗(Desmodium sequax Wall.)及钻形紫苑(Aster subulatus Michx.);后两种类型的植物可种植在重金属污染严重且使用价值相对较低的矿山废弃地上,同时规避型植物对于研究植物的重金属排斥机理具有重要价值。溶溪锰矿区周边农田土壤主要受到Cd的严重污染,Cd为很强或极强生态危害。     

Fungal transformation of natural and synthetic cobalt-bearing manganese oxides and implications for cobalt biogeochemistry

Manganese oxide minerals can become enriched in a variety of metals through adsorption and redox processes, and this forms the basis for a close geochemical relationship between Mn oxide phases and Co. Since oxalate-producing fungi can effect geochemical transformation of Mn oxides, an understanding of the fate of Co during such processes could provide new insights on the geochemical behaviour of Co. In this work, the transformation of Mn oxides by Aspergillus niger was investigated using a Co-bearing manganiferous laterite, and a synthetic Co-doped birnessite. A. niger could transform laterite in both fragmented and powder forms, resulting in formation of biomineral crusts that were composed of Mn oxalates hosting Co, Ni and, in transformed laterite fragments, Mg. Total transformation of Co-doped birnessite resulted in precipitation of Co-bearing Mn oxalate. Fungal transformation of the Mn oxide phases included Mn(III,IV) reduction by oxalate, and may also have involved reduction of Co(III) to Co(II). These findings demonstrate that oxalate-producing fungi can influence Co speciation in Mn oxides, with implications for other hosted metals including Al and Fe. This work also provides further understanding of the roles of fungi as geoactive agents which can inform potential applications in metal bioremediation, recycling and biorecovery.     

Bioleaching of chalcopyrite by pure and mixed cultures of Acidithiobacillus spp. and Leptospirillum ferriphilum

Bioleaching is an economical method for the recovery of metals that requires low investment and operation costs. Furthermore, it is generally more environmentally friendly than many physicochemical metal extraction processes. The bioleaching of chalcopyrite in shake flasks was investigated with pure and mixed cultures of Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans, Acidithiobacillus caldus, and Leptospirillum ferriphilum. The mixed cultures containing both iron- and sulfur-oxidizing bacteria were more efficient than the pure culture alone. The presence of sulfur-oxidizing bacteria positively increased the dissolution rate and the percentage recovery of copper from chalcopyrite. Mixed cultures consisting of moderately thermophilic L. ferriphilum and A. caldus leached chalcopyrite more effectively than mesophilic A. ferrooxidans pure and mixed cultures. The decrease of the chalcopyrite dissolution rate in leaching systems containing A. ferrooxidans after 12–16 days coincided with the formation of jarosite precipitation as a passivation layer on the mineral surface during bioleaching. Low pH significantly reduces jarosite formation in pure and mixed cultures of L. ferriphilum and A. caldus.     

城市住宅建筑系统流量-存量动态模拟——以北京市为例

地面建筑物的累积与更新是城市化过程的结果与显性特征之一。城市建筑系统在不同层面上与外部环境系统进行着物质能量交换,对这种交互产生的资源压力与环境胁迫的关注,使其成为城市代谢研究领域中的热点问题。系统分析与模拟城市建筑物流量-存量的动态变化过程及其资源环境响应,对于揭示城市建筑系统代谢机理,提高城市总体规划精准性、强化资源系统韧性管理、提升废弃物处置效率等宏观战略具有重要意义。以北京市为例,基于Stella建模平台,构建了城市居民住宅建筑系统流量-存量的动态模拟模型,定量模拟了不同管理情景下钢材需求量与建筑拆除垃圾产生量的变化区间。结果表明:(1)基准情景下,北京住宅建筑新建流量前期增速较快,2005年达到峰值3024.1万m~2,而拆除流量约于2057年达到峰值,拆除面积为2073.14万m~2;城市住宅建筑存量最高值出现在2075年左右,面积为7.51亿m~2;(2)与基准情景相比,如果人均住宅建筑面积提高到45 m~2,从现在到模拟期结束(2019—2100)将增加钢铁需求量3251.65万t;而如果延长住宅建筑寿命至设计值,同期可减少钢铁需求量3022.9万t;(3)基准情景、大面积情景以及长寿命情景下,北京市城镇住宅建筑拆除垃圾峰值产生量分别为0.29亿t、0.39亿t、0.20亿t,政府管理部门应采取有针对性的应对措施,提前做出综合利用和处理处置方案。     

江苏省南通市农村生物质能资源潜力估算及地区分布

摸清农村生物质能资源潜力对南通市农村能源建设具有重大意义。以南通市为实证区域,利用草谷比、收集系数、折标系数、副产物系数并根据南通市可能源化利用的实际情况,从县域层面较为全面地估算了包括秸秆、农业加工副产品、人畜粪便等可能源化利用的生物质能资源总量。估算结果表明:(1)南通市每年提供的可能源化利用秸秆资源量约为105万t标煤,以稻秸、麦秸和油菜秸为主;农业加工副产品资源量约为20万t标煤,以稻壳、玉米芯、棉籽等为主;人禽粪便资源量为108万t标煤,以猪粪和禽粪为主,约占到资源总量的1/2。(2)南通市拥有较为丰富的生物质能资源,其中可能源化利用的生物质资源总量为年均233万t标煤,并且其资源总量呈增长趋势;预计在短期内其资源总量将增加到240万t标煤。(3)南通市生物质资源的地区分布极不均匀,从生物质能资源总量、单位国土面积生物质能资源量、人均生物质能资源量看,海安县、如东县和如皋市等经济比较薄弱的县市均具有明显优势,其中海安县在南通各县市中凭借其规模渐增的养殖业、种植业产生的生物质资源而遥遥领先;此外如东县的秸秆资源也具有重要地位。(4)南通市生物质资源的季节分布也不均匀,这种季节分布不均主要是由秸秆资源引起的,因为秸秆资源主要集中在秋季和春季,约占到60%—75%;而夏季和冬季则很少。这就给农村能源的持续开发利用带来一定难度。建议:需要针对各县市的生物质能开发利用的实际情况因地制宜合理开发生物质资源,科学布局避免恶性竞争,并及时做好秸秆资源的收集、转运与储存工作以避免资源的浪费和严重的环境污染,从而促进南通农村能源建设的健康发展。     

Enhancing Manganese Recovery from Low-Grade Ores by Using Mixed Culture of Indigenously Isolated Bacterial Strains

Conventional leaching methods for manganese (Mn) recovery require strong acids and are threatening to the environment. Alternatively, the use of microbes for Mn recovery is environment friendly in nature. The present investigation compares the capacity of pure and mixed cultures of native bacterial strains for bioleaching of low-grade Mn ores. The ability of the isolated microorganisms to recover Mn was evaluated in shake flasks for 20 days under optimized conditions of pulp density (2%), sucrose concentration (2 g/100 mL), initial pH 6.5, and 30°C incubation temperature. In pure culture form, Acinetobacter sp. MSB 5 (70%) was found to have a higher bioleaching potential than Lysinibacillus sp. MSB 11 (67%). Mixed culture of Acinetobacter sp. MSB 5 and Lysinibacillus sp. MSB 11 was found to perform better than the pure cultures with 74% extraction of Mn. The presence of mixed culture increased the dissolution rate and the recovery percentage of Mn. The respective growth pattern of the cultures was in synchronization to their Mn bioleaching performances. This study underlines the importance of mixed cultures and Mn solubilizing activity of native bacterial strains for efficient Mn biorecovery.     

Metal Removal from Contaminated Soils Through Bioleaching with Oxidizing Bacteria and Rhamnolipid Biosurfactants

The use of surfactants as a method for solubilization and removal of heavy metal contamination from soil has been reported before. Biosurfactants produced by some microorganisms are able to modify the surface of various metals and aggregate on interphases favoring the metal separation process from contaminated environments. We evaluated the feasibility of enhancing the removal of metal ions from mineral waste/contaminated soils using alternate cycles of treatment with rhamnolipid biosurfactants and bioleaching with a mixed bacterial culture of Acidithiobacillus thiooxidans and Acidithiobacillus ferrooxidans. Bioleaching alone removed 50% Zn and 19% Fe. When rhamnolipids were used at low concentration (0.4 mg/mL), 11% Fe and 25% Zn were removed, while at 1 mg/mL 19% Fe and 52% Zn removal were achieved. When using a cyclic treatment combining bioleaching and biosurfactants, metal removal reached up to 36% for Fe and 63% to 70% for Zn.     

Extraction of manganese from electrolytic manganese residue by bioleaching

Extraction of manganese from electrolytic manganese residues using bioleaching was investigated in this paper. The maximum extraction efficiency of Mn was 93% by sulfur-oxidizing bacteria at 4.0 g/l sulfur after bioleaching of 9days, while the maximum extraction efficiency of Mn was 81% by pyrite-leaching bacteria at 4.0 g/l pyrite. The series bioleaching first by sulfur-oxidizing bacteria and followed by pyrite-leaching bacteria evidently promoted the extraction of manganese, witnessing the maximum extraction efficiency of 98.1%. In the case of sulfur-oxidizing bacteria, the strong dissolution of bio-generated sulfuric acid resulted in extraction of soluble Mn2+, while both the Fe2+ catalyzed reduction of Mn4+ and weak acidic dissolution of Mn2+ accounted for the extraction of manganese with pyrite-leaching bacteria. The chemical simulation of bioleaching process further confirmed that the acid dissolution of Mn2+ and Fe2+ catalyzed reduction of Mn4+ were the bioleaching mechanisms involved for Mn extraction from electrolytic manganese residues.     

Progress in bioleaching: fundamentals and mechanisms of bacterial metal sulfide oxidation—part A

Bioleaching of metal sulfides is performed by a diverse group of microorganisms. The dissolution chemistry of metal sulfides follows two pathways, which are determined by the mineralogy and the acid solubility of the metal sulfides: the thiosulfate and the polysulfide pathways. Bacterial cells can effect this metal sulfide dissolution via iron(II) ion and sulfur compound oxidation. Thereby, iron(III) ions and protons, the metal sulfide-attacking agents, are available. Cells can be active either in planktonic state or in forming biofilms on the mineral surface; however, the latter is much more efficient in terms of bioleaching kinetics. In the case of Acidithiobacillus ferrooxidans, bacterial exopolymers contain iron(III) ions, each complexed by two uronic acid residues. The resulting positive charge allows an electrostatic attachment to the negatively charged pyrite. Thus, the first function of complexed iron(III) ions is the mediation of cell attachment, while their second function is oxidative dissolution of the metal sulfide, similar to the role of free iron(III) ions in non-contact leaching. In both cases, the electrons extracted from the metal sulfide reduce molecular oxygen via a redox chain forming a supercomplex spanning the periplasmic space and connecting both outer and inner membranes. In this review, we summarize some recent discoveries relevant to leaching bacteria which contribute to a better understanding of these fascinating microorganisms. These include surface science, biochemistry of iron and sulfur metabolism, anaerobic metabolism, and biofilm formation. The study of microbial interactions among multispecies leaching consortia, including cell-to-cell communication mechanisms, must be considered in order to reveal more insights into the biology of bioleaching microorganisms and their potential biotechnological use.     

Mineralization of copper, manganese and zinc from rock mineral flour and city waste compost for efficient use in organic farming

Restricted supply of micronutrients is a common constraint for plant growth worldwide, especially in organic farming systems where nutrients supply to crops mostly depends on the mineralization of native soil organic matter, decomposition of applied manures and crop residues. A laboratory incubation study was therefore conducted to investigate the potential release of copper (Cu), manganese (Mn) and zinc (Zn) from the rock mineral flour (RMF) and city waste compost (CWC) as compared to inorganic micronutrient fertilizers for 140 days. Release of the micronutrients from RMF and CWC showed different trends. The results showed that about 4.6% of Cu added as RMF was released irrespective of the quantity of the RMF applied. However, Cu release from CWC increased from 0.7 to 3.5% as the amount of compost added was increased. Copper recovery from copper sulphate was 98%. Manganese release from RMF decreased from 114 to 103% as the RMF level was increased, while the corresponding decrease in Mn release from CWC was from 14 to ?3%. Manganese recovery from manganese sulphate was 100%. Zinc release from RMF increased from 5.8?15.5%, with an increase in the amount of RMF applied, while no Zn was released from CWC. Recovery of Zn from zinc sulphate was 98%. These results show that RMF and CWC could be used to meet Cu, Mn and Zn requirements of organically grown cereals. The results of the investigation have general applicability in organic farming.     

Biosorption of precious metals

Biosorption has emerged as a low-cost and often low-tech option for removal or recovery of base metals from aqueous wastes. The conditions under which precious metals such as gold, platinum and palladium are sorbed by biomass are often very different to those under which base metals are sorbed. This, coupled with the increasingly high demand for precious metals, drives the increase in research into efficient recovery of precious metal ions from all waste material, especially refining wastewaters. Common biosorbents for precious metal ions include various derivatives of chitosan, as well as other compounds with relatively high surface amine functional group content. This is generally due to the ability of the positively charged amine groups to attract anionic precious metal ions at low pH. Recent research regarding the biosorption of some precious metals is reviewed here, with emphasis on the effects of the biosorption environment and the biosorption mechanisms identified.