Experiments on the Capture of Li,H, and D by Lithium Collectors at Different Surface Temperatures at the T-11M Tokamak

Prototypes of lithium emitters and collectors designed on the basis of capillary-porous systems (CPS) are being tried-out at the T-11M tokamak within the concept of continuous lithium circulation, previously proposed for stationary fusion neutron sources (FNSs). One of the goals of the T-11M tokamak research program are to implement the closure of the lithium circulation circuit and to develop the technology of recuperation (extraction and removal from the tokamak chamber) of hydrogen isotopes by using special lithium CPS-based collectors in order to prevent hydrogen isotope accumulation on the inner surface of the discharge chamber. In order to determine the optimal temperature regime for the future FNS operation, the effect of the temperature of the collector surface on its ability to capture lithium and hydrogen isotopes was studied. It is ascertained that the efficiency of capturing lithium and hydrogen isotopes by metal (12Cr18Ni10Ti) collectors in the operating regimes of the T-11M tokamak depends on the temperature of their collecting surfaces; namely, it remains almost constant in the temperature range from–196 to 50°С and then gradually decreases as the temperature rises to 300–400°С. In this case, the amount of the collected lithium is reduced by no more than sixfold, whereas the amount of collected hydrogen isotopes decreases by more than two orders of magnitude. Thus, the wall of a tokamak reactor chamber, which will be heated to 400°С but still coated with residual lithium (or its chemical compounds), will serve as a “mirror” for the incident hydrogen isotopes. It is found that the liquid lithium surface of the CPS-based collector can efficiently capture hydrogen isotopes falling onto it. As the lithium CPS-based collector is heated from 100 to 240°С, the amount of captured deuterium is reduced only twofold. This means that, in a steady-state mode, if, e.g., an MHD pump is used to transport liquid lithium from the collector back to the emitter, then, together with lithium, the captured hydrogen isotopes can also be transported into the recuperation zone.     

Investigation of the plasma radiation power in the Globus-M tokamak by means of SPD silicon photodiodes

Radiation losses from the plasma of the Globus-M tokamak are studied by means of SPD silicon photodiodes developed at the Ioffe Institute, Russian Academy of Sciences. The results from measurements of radiation losses in regimes with ohmic and neutral beam injection heating of plasmas with different isotope compositions are presented. The dependence of the radiation loss power on the plasma current and plasma–wall distance is investigated. The radiation power in different spectral ranges is analyzed by means of an SPD spectrometric module. Results of measurements of radiation losses before and after tokamak vessel boronization are presented. The time evolution of the sensitivity of the SPD photodiode during its two-year exploitation in Globus-M is analyzed.     

Background and radiation resistance tests of neutral particle analyzer detectors for ITER by using a fast neutron beam

The radiation resistance and background sensitivity of scintillation (Hamamatsu H8500D photo-multiplier) and semiconductor (ORTEC BF-018-100-60 and BU-012-050-100) detectors to neutron and gamma radiation were investigated. Conclusions are drawn concerning the possibility of using such detectors in neutral particle analyzers that are being developed for ITER at the Ioffe Institute.     

Experimental study and numerical simulation of ion cyclotron heating of a hydrogen plasma in the T-11M tokamak

Results are presented from investigations of the possibility of heating a hydrogen plasma at the fundamental harmonic of the ion cyclotron frequency in the T-11M tokamak. The fluxes of charge-exchange atoms that escape from the plasma in the radial direction and across the toroidal magnetic field (transverse neutrals) were recorded by a Lakmus neutral particle analyzer. Measurements by the analyzer show that, during an RF pulse, the ion temperature increases by approximately 50–100 eV. Such plasma parameters as the ion temperature, rotation velocity, and isotopic composition were measured by a high-resolution spectrometer. According to the data from high-resolution spectroscopy, the ion temperature increases by approximately 150 eV. Results from numerical simulations of the ion cyclotron resonance heating of a hydrogen plasma in the T-11M tokamak are also given.     

Simulations of tokamak discharges with fast L-H transitions

Results are presented from the simulations of discharges with fast L-H transitions in the JET tokamak. During a transition, electron temperature perturbations propagate into the plasma core over a time much shorter than the transport time characteristic of this device. It is shown that the experimentally observed variations in the electron temperature may be caused by the change in the particle source intensity in the plasma when the atomic flux decreases, which is detected from the drop in the intensity of the D_α hydrogen spectral line. Hence, the experiments under consideration can be explained without the assumption about the nonlocal character of transport processes in tokamaks, which was made in some papers devoted to JET experiments. The plasma component responsible for the apparent nonlocal character of transport processes is the neutral component, whose propagation time across the plasma column is sufficiently short (t<100 μs). __________ Translated from Fizika Plazmy, Vol. 28, No. 1, 2002, pp. 3–8. Original Russian Text Copyright ? 2002 by Leonov.     

Thermal instability caused by plasma-wall interaction

A one-dimensional model describing recycling of hydrogen isotopes in fusion reactors is proposed. The dispersion relation for thermal instability caused by plasma-wall interaction is derived, and conditions under which it develops are determined. It is shown analytically and numerically that this instability can develop under typical tokamak conditions.     

Monitoring of the plasma isotope composition by charge-exchange neutral fluxes in a rippled toroidal magnetic field

To determine the hydrogen isotope ratio in plasma from charge-exchange neutral fluxes, certain assumptions are traditionally adopted, the most restrictive of which concerns the form of the ion distribution function, which is usually assumed to be Maxwellian. For large tokamaks, however, additional analysis is required in order to determine the energy range in which distortions of the distribution function will not lead to errors in isotope ratio measurements. The possible influence of drift motion on the ion distribution function is considered. Experimental results obtained in the ASDEX-Upgrade tokamak are presented. The role this mechanism plays during the transition to the H-mode in the auxiliary heating regime is compared to that in the ohmic heating regime.     

Effect of helical magnetic fields on plasma stability in tokamaks

Physical mechanisms for destabilization of MHD perturbations by external quasistatic magnetic fields and rotating helical magnetic fields in a tokamak plasma are identified using a numerical model of tearing modes in a viscous high-temperature plasma. The critical conditions for the onset of MHD perturbations and their dynamic model are compared with the experimental results from the JET tokamak. The model is used to predict how the stray magnetic fields will influence plasma stability in a tokamak reactor (ITER). __________ Translated from Fizika Plazmy, Vol. 26, No. 8, 2000, pp. 675–682. Original Russian Text Copyright ￠ 2000 by Savrukhin.     

Do spherical tokamaks have a thermonuclear future?

This work has been initiated by the publication of a review by B.V.Kuteev et al., ??Intense Fusion Neutron Sources?? [Plasma Physics Reports 36, 281 (2010)]. It is stated that the key thesis of the above review that a spherical tokamak can be recommended for research neutron sources and for demonstration hybrid systems as an alternative to expensive ??classical?? tokamaks of the JET and ITER type is inconsistent. The analysis of the experimental material obtained during the last 10 years in the course of studies on the existing spherical tokamaks shows that the TIN-ST fusion neutron source spherical tokamak proposed by the authors of the review and intended, according to the authors?? opinion, to replace ??monsters?? in view of its table-top dimensions (2 m³) and laboratory-level energetics cannot be transformed into any noticeable stationary megawatt-power neutron source competing with the existing classical tokamaks (in particular, with JET with its quasi-steady DT fusion power at a level of 5 MW). Namely, the maximum plasma current in the proposed tokamak will be not 3 MA, as the authors suppose erroneously, but, according to the present-day practice of spherical tokamaks, within 0.6?C0.7 MA, which will lead to a reduction on the neutron flux by two to three orders of magnitude from the expected 5 MW. The possibility of the maintenance of the stationary process itself even in such a ??weakened?? spherical tokamak is very doubtful. The experience of the largest existing devices of this type (such as NSTX and MAST) has shown that they are incapable of operating even in a quasi-steady operating mode, because the discharge in them is spontaneously interrupted about 1 s after the beginning of the current pulse, although its expected duration is of up to 5 s. The nature of this phenomenon is the subject of further study of the physics of spherical tokamaks. This work deals with a critical analysis of the available experimental data concerning such tokamaks and a discussion of the potential possibility of their use in thermonuclear research.     

Reduced kinetic models of neutral transport in the tokamak plasma

A method for constructing reduced models of neutrals transport for problems with a reduced dimension has been proposed on the basis of the kinetic equation. The case of a cylindrically symmetric plasma column, which is a good approximation for the tokamak geometry, has been thoroughly analyzed. For this geometry, the kinetic model of neutrals in the isotropic approximation is implemented using an algorithm based on energy grouping of neutrals; this algorithm for atomic hydrogen isotopes is integrated in the ASTRA code.     

Islands and ergodicity of the plasma current in toroidal magnetic confinement systems

Magnetic and current structures arising due to resonant perturbations of an equilibrium current-carrying magnetic configuration are analyzed using the Hamiltonian formalism. Special attention is paid to axisymmetric tokamak and pinch configurations. It is shown that, due to the very different dependences of the magnetic and current rotational transforms on the plasma pressure, the resonances (islands) of the magnetic field may not coincide with those of the current. The perturbed force-free equilibrium of a cylindrical pinch in which the field and current islands overlap is analyzed. The long-lived ribbon structures observed in the JET tokamak are explained as a manifestation of a force-free magneto-current island.     

Behavior of the fast neutrals generated during a disruption in the T-11M tokamak

Results are presented from experimental studies of the generation of high-energy neutrals during a major disruption in the T-11M tokamak. Fast-neutral fluxes from the plasma, magnetic perturbations, and the neutral-hydrogen and impurity radiation from the plasma core are measured simultaneously in the course of disruption. A high (～1 μs) temporal resolution of the recording system (the characteristic disruption time being about 100 μs) makes it possible to thoroughly investigate the time behavior of the processes that occur during a disruption.     

Stable isotope compounds - production,detection, and application

Stable isotopes are used in wide fields of application from natural tracers in biology, geology and archeology through studies of metabolic fluxes to their application as tracers in quantitative proteomics and structural biology. We review the use of stable isotopes of biogenic elements (H, C, N, O, S, Mg, Se) with the emphasis on hydrogen and its heavy isotope deuterium. We will discuss the limitations of enriching various compounds in stable isotopes when produced in living organisms. Finally, we overview methods for measuring stable isotopes, focusing on methods for detection in single cells in situ and their exploitation in modern biotechnologies.     

Study of plasma heating in discharges with neutral beam injection in the Globus-M spherical tokamak

Results from experimental studies on the injection of high-energy neutral hydrogen beams into the plasma of the Globus-M spherical tokamak are reviewed. In the Introduction, the importance of these studies for implementing the controlled fusion research program and constructing the ITER tokamak is proved. Some problems related to the use of neutral beam injection in small and low-aspect-ratio tokamaks is analyzed. Results are presented from numerical simulations of the experiment by using the ASTRA transport code. It is shown that the use of neutral beam injection in the Globus-M tokamak ensures efficient ion heating and increases the plasma stored energy. The greater part of the review is devoted to the survey of experiments on the injection of 22-to 30-keV hydrogen and deuterium beams with a power of 0.4–0.8 MW into the plasma of the Globus-M spherical tokamak in a wide range of plasma currents and densities. The experimental results are analyzed and compared with the results of numerical simulations. The achievement of top plasma parameters is highlighted.     

Linking protein structure and dynamics to catalysis: the role of hydrogen tunnelling

Early studies of enzyme-catalysed hydride transfer reactions indicated kinetic anomalies that were initially interpreted in the context of a 'tunnelling correction'. An alternate model for tunnelling emerged following studies of the hydrogen atom transfer catalysed by the enzyme soybean lipoxygenase. This invokes full tunnelling of all isotopes of hydrogen, with reaction barriers reflecting the heavy atom, environmental reorganization terms. Using the latter approach, we offer an integration of the aggregate data implicating hydrogen tunnelling in enzymes (i.e. deviations from Swain-Schaad relationships and the semi-classical temperature dependence of the hydrogen isotope effect). The impact of site-specific mutations of enzymes plays a critical role in our understanding of the factors that control tunnelling in enzyme reactions.     

Peripheral fluctuations and particle transport during an L-H transition in the FT-2 tokamak

Experimental data on the processes in edge plasma that accompany the transition to an improved confinement regime during lower hybrid heating in the FT-2 tokamak are presented. The poloidal and radial distributions of the plasma parameters and drift particle fluxes were measured with the use of mobile mulitielectrode Langmuir probes and were found to be substantially nonuniform in the poloidal direction. The evolution of the plasma parameters in the course of heating and during an L-H transition is investigated. It is shown that, in FT-2 experiments, the drift of plasma particles in a slowly varying (quasi-steady) electric field and the fluctuation-induced particle fluxes make comparable contributions to the radial particle transport, whereas the contribution of fluctuations to poloidal plasma fluxes is negligibly small. The effective coefficient of radial diffusion is determined. The measurement results show that the L-H transition is accompanied by a substantial decrease in this coefficient.     

Measurement of 2H distribution in natural products by quantitative 2H NMR: An approach to understanding metabolism and enzyme mechanism?

During the biosynthesis of natural products, the intra-molecular distribution of isotopes is introduced as a result of different isotope effects associated with the reactions involved. Due to the sensitivity of certain enzymes to the presence of a heavy isotope, the isotope selection effects related to some transformations can be high, especially for hydrogen. The effect of a series of isotope effects specific to each enzyme-catalysed step are additive during a biosynthetic pathway, leading to fractionation of the isotopes between the starting substrate and the final product. As the individual reactions are acting on different positions in the substrate, the net effect is a non-statistical distribution of isotope within the final product. Quantitative ²H NMR spectroscopy can be used to measure the distribution of ²H at natural abundance in natural products. In the first example, the fermentation of glucose is examined. Glucose can act as a primary carbon source for a wide range of fermentation products, produced by a variety of pathways. In many cases, competing pathways are active simultaneously. The relative fluxes are influenced by both environmental and genetic parameters. Quantitative ²H NMR spectroscopy is being used to obtain mechanistic and regulatory information about isotopic fractionation from glucose during such fermentations. Quantitative ²H NMR spectroscopy can also be used to examine the fractionation in ²H that occurs in long-chain fatty acids during chain elongation and oxygenation. It has been found that the (²H/¹H) ratio shows an alternating pattern along the length of the chain and that the residual hydrogen atoms at the sites of desaturation are asymmetrically impoverished. The extent to which the non-statistical distribution of isotopes can be related to the mechanism of enzymes involved in the biosynthetic pathway via kinetic isotopic effects will be discussed.     

Proton polarizability of poly(L-tyrosine)–hydrogen phosphate hydrogen bonds as a function of alkali cations

We studied films of poly(L -tyrosine) with hydrogen phosphate (residue/phosphate, 1:1) by ir spectroscopy. The influences of the alkali cations (Li⁺, Na⁺, K⁺) and of the degree of hydration were clarified. If Li⁺ ions are present, the OH ?^?OP hydrogen bonds formed in the dried films between the tyrosine OH groups and hydrogen phosphate are asymmetrical. The formation of hydrogen phosphate–hydrogen phosphate hydrogen bonds is prevented by the presence of the Li⁺ ions. With an increase in the degree of hydration, the tyrosine–phosphate bonds are not broken but become slightly stronger. Completely different behaviour is found if K⁺ ions are present. In dry films, the OH ?^?OP ? O^? ?HOP hydrogen bonds formed between tyrosine and hydrogen phosphate show large proton polarizability. The tyrosine proton has a noticeable residence time at the acceptor O atom of the phosphate. The difference in the behaviour of the system with K⁺ ions when compared to the system with Li⁺ ions can be explained, since the hydrogen acceptor O atom of phosphate ions is more negatively charged due to the weaker influence of the K⁺ ions. Furthermore, POH ?^?OP hydrogen bonds between hydrogen phosphate molecules are formed. With an increase in the degree of hydration, the tyrosine–hydrogen phosphate hydrogen bonds are broken, all tyrosine protons are found at the tyrosine residues, and the -PO₃^? groupings are in a symmetrical environment, indicating that the K⁺ ions are removed from these groupings. If the degree of hydration increases further, hydrogen-bonded systems such as hydrogen phosphate–water–hydrogen phosphate are formed that show large proton polarizability due to collective proton motion. When Na⁺ ions are present, the OH ?^?OP ? O^? ?HOP hydrogen bonds formed in dry films still show proton polarizability, but the residence time of the tyrosine proton at the phosphate is very short.     

Numerical bias estimation for mass spectrometric mass isotopomer analysis

Mass spectrometric (MS) isotopomer analysis has become a standard tool for investigating biological systems using stable isotopes. In particular, metabolic flux analysis uses mass isotopomers of metabolic products typically formed from ¹³C-labeled substrates to quantitate intracellular pathway fluxes. In the current work, we describe a model-driven method of numerical bias estimation regarding MS isotopomer analysis. Correct bias estimation is crucial for measuring statistical qualities of measurements and obtaining reliable fluxes. The model we developed for bias estimation corrects a priori unknown systematic errors unique for each individual mass isotopomer peak. For validation, we carried out both computational simulations and experimental measurements. From stochastic simulations, it was observed that carbon mass isotopomer distributions and measurement noise can be determined much more precisely only if signals are corrected for possible systematic errors. By removing the estimated background signals, the residuals resulting from experimental measurement and model expectation became consistent with normality, experimental variability was reduced, and data consistency was improved. The method is useful for obtaining systematic error-free data from ¹³C tracer experiments and can also be extended to other stable isotopes. As a result, the reliability of metabolic fluxes that are typically computed from mass isotopomer measurements is increased.     

Time-dependent density functional theory study on the electronic excited-state hydrogen bonding of the chromophore coumarin 153 in a room-temperature ionic liquid

In the present work, in order to investigate the electronic excited-state intermolecular hydrogen bonding between the chromophore coumarin 153 (C153) and the room-temperature ionic liquid N,N-dimethylethanolammonium formate (DAF), both the geometric structures and the infrared spectra of the hydrogen-bonded complex C153–DAF⁺ in the excited state were studied by a time-dependent density functional theory (TDDFT) method. We theoretically demonstrated that the intermolecular hydrogen bond C₁?=?O₁···H₁–O₃ in the hydrogen-bonded C153–DAF⁺ complex is significantly strengthened in the S₁ state by monitoring the spectral shifts of the C=O group and O–H group involved in the hydrogen bond C₁?=?O₁···H₁–O₃. Moreover, the length of the hydrogen bond C₁?=?O₁···H₁–O₃ between the oxygen atom and hydrogen atom decreased from 1.693 Å to 1.633 Å upon photoexcitation. This was also confirmed by the increase in the hydrogen-bond binding energy from 69.92 kJ mol^?1 in the ground state to 90.17 kJ mol^?1 in the excited state. Thus, the excited-state hydrogen-bond strengthening of the coumarin chromophore in an ionic liquid has been demonstrated theoretically for the first time.