Wideband Graphene-Based Fractal Absorber and its Applications as Switch and Inverter

In this paper, the idea of square fractal geometry has been utilized to introduce a tunable wideband graphene-based perfect plasmonic absorber in the near-infrared region. It consists of a MgF₂ layer and an array of gold squares fractal loaded on a graphene layer. In the designed absorber a single layer of graphene has been used instead of multilayered graphene structures. The structure is polarization-insensitive under normal incidence due to the geometric symmetry. The absorption and bandwidth of the structure are almost insensitive to the incident angle up to 15° and 45° for TE and TM polarizations, respectively. Moreover, by choosing appropriate structural parameters, the resonance wavelength of the desired plasmonic absorber can be controlled. The absorption of the introduced structure can be tuned by changing the chemical potential of the graphene. Therefore, the proposed fractal absorber can act as switch and inverter at λ = 1995 nm. Furthermore, the equivalent circuit model of the absorber has been derived to confirm the validity of the simulation results. The superiorities of our fractal absorber are wide full-width at half-maximum of 406 nm, multi-applicant, perfect absorption, and fabrication feasibility due to the simple structure with the maximum absorption tolerance error of 5.12%.

     

Staked Graphene for Tunable Terahertz Absorber with Customized Bandwidth

Terahertz (THz) absorber with dynamically tunable bandwidth possesses huge application value in the fields of switches, sensors, and THz detection. However, the perfect absorbers based on photonic crystals and metamaterials are not intelligent enough to capture the electromagnetic wave in a tunable way. In this paper, we utilized only patterned graphene to tune the absorption positions and the bandwidth in the terahertz regime. More distinguished than some dynamic absorbers proposed before, the performances with peak frequency relative tuning range of 68 % and nearly unity absorbance are obtained by a single cross-shaped graphene layer. Additionally, the working bandwidth can be broadened with stacked structured graphene. The almost perfect absorption shifted from 2.36～3.2 to 3.26～3.99 THz continuously via changing the chemical potential of graphene.     

Theoretical <Emphasis Type="Italic">T</Emphasis> Circuit Modeling of Graphene-Based Metamaterial Broadband Absorber

We demonstrate a broadband light absorber with its absorption being able to reach as high as 90 % and above ranging from the ultraviolet to the visible regimes. A theoretical model is given for the purpose of analyzing the physical mechanism of the absorption. By applying the equivalent T circuit model of metamaterial layers to the analysis of our designed absorber, our calculated results are in good agreement to that of the theoretical model and satisfy the perfect-absorption condition very well.     

Multi-layered Graphene Silica-Based Tunable Absorber for Infrared Wavelength Based on Circuit Theory Approach

Graphene can be utilized as a tunable material for a wide range of infrared wavelength regions due to its tunable conductivity property. In this paper, we use Y-shaped silver material resonator placed over the top of multiple graphene silica-layered structures to realize the perfect absorption over the infrared wavelength region. We propose four different designs by placing the graphene sheet over silica. The absorption and reflectance performance of the structures have been explored for 1500- to 1600-nm wavelength range. The proposed design also explores the absorption tunability of the structure for the different values of graphene chemical potential. We have reported the negative impedance for the perfect absorption for proposed metamaterial absorber structures. All the metamaterial absorbers have reported 99% of its absorption peaks in the infrared wavelength region. These designs can be used as a tunable absorber for narrowband and wideband applications. The proposed designs will become the basic building block of large photonics design which will be applicable for polariser, sensor, and solar applications.

     

Multiband Terahertz Metamaterial Absorber Based on Multipolar Plasmonic Resonances

Terahertz metamaterial absorbers (MMA) have found wide scope of research prospective, remarkably in the development of multiband absorbers. Considerable applications are established using these multiband absorbers in THz imaging, wireless communication and bolometric detectors. The MMA was built on a GaAs substrate of 30 µm thickness and the hexagonal metallic pattern was etched out on a gold layer of 0.4 µm thickness on the top surface. The underlying ground layer is metallic backed. This design realizes the multiband (9-bands) of absorption in the spectral region from 0.56 to 0.92 THz. The multiband absorption mechanism of the absorber was examined by electric field dispersion analysis and impedance matching concept. From the established results, the absorber exhibits nine bands within a narrow frequency range and secures promising applications in hyperspectral imaging, clinical sensing and detection.

     

Single-Patterned Metamaterial Structure Enabling Multi-band Perfect Absorption

Multi-band or broadband perfect metamaterial absorbers, based on coplanar super-unit structure or multiple vertically stacked layers, have received intense attention because of their potential for practical applications. The resonance mechanism of them usually only utilizes the overlapping of the fundamental resonance of the different-sized patterns, and neglects the high-order resonance of the structure, and thus making the proposed structures quite troublesome to be fabricated and the mechanism of the current demonstrated absorbers lack of novelty. In this paper, a simple design of dual-band terahertz absorber consisted of only a traditional square metallic patch and a dielectric layer on top of a continuous ground plane is presented. Simulation results show that the single resonant structure has two resonance absorption peaks, which are both average over 99.5 %. The mechanism of the dual-band absorber is due to the overlapping of the fundamental mode and three-order response of the patterned structure, which is totally different from previous reports that only combining the fundamental resonances of the different-shaped complex structures to obtain the dual-band response. Furthermore, the proposed single-patterned structure can be used to extend the number of the absorption peaks (for example, triple-band absorber) by combining one more resonance (the five-order response). The proposed absorbers with the simple structure design have potential applications in many areas, such as detection, sensing, and selective thermal emitters.     

An Ultra-Wideband Terahertz Metamaterial Absorber Utilizing Sinusoidal-Patterned Dielectric Loaded Graphene

In this paper, a non-structured graphene sheet loaded with a sinusoidal-patterned dielectric is introduced as an ultra-wideband metamaterial absorber in terahertz regime. Regardless of conventional structures with multilayered-graphene, a single layer sheet of non-structured graphene is used whereas the proposed structure benefits from dielectric width modulation and cavity method in order to excite continuous graphene plasmon resonances. The structure comprises four layers that two Fabry-Perot cavity mirrors are constructed by upper sinusoidal-patterned dielectric and a gold film. Full wave simulation results demonstrate that a broadband over 90% absorption with absolute bandwidth of 6.58 THz and central frequency of 3.97 THz is achieved under normal TE/TM incident plane wave. The designed structure yields 166% relative bandwidth. According to the symmetric configuration, the absorption spectra of mentioned polarizations are thoroughly close to each other resulting to a polarization insensitive structure. The stability of bandwidth and absorbance of the structure versus angle of incidence, θ, up to 35°/65° for TM/TE polarizations, respectively, and azimuth angle, φ, shows an interesting capability for utilization as detectors and sensors. The simple geometry of utilized graphene layer results in easy fabrication. The designed structure has wideband absorption in THz regime. Moreover, it is more compact than conventional broadband THz absorbers.

     

Dark Mode Driven Extra-narrow and Multiband Absorber

Recently, metamaterial absorbers have received tremendous amount of interest because of their remarkable ability to manipulate the amplitude, phase, and polarization of light. However, most absorbers rely on the direct coupling of electric or magnetic field with external excitation, which lead to inevitable energy leakage to the surrounding environment and depress the quality factor of the structure. In this work, we investigate the multiband absorption property by exciting dark plasmonic modes in reflective symmetric and asymmetric metamaterials. Theoretically, the existence of dark plasmonic modes in asymmetric metamaterials is unambiguously illustrated by the improved eigen-mode theory. With the introduction of asymmetry, dark modes in metamaterials can be easily excited by normal incident plane wave. Moreover, we also directly excite the dark modes in symmetric absorber with oblique incidence. The dark modes splitting mechanism is also clarified with the excitation of designer surface plasmon. Dominated by magnetic dipole or higher-order multipole, these dark modes possess high quality factors (Q). Numerical results indicate that the metamaterial absorber maintains high absorbance within a wide-angle incidence (0~50°). The high Q asymmetric metamaterial absorber can be an excellent candidate for multiband plasmonic sensor.     

Cadmium Free Cu2ZnSnS4 Solar Cells with 9.7% Efficiency

Cu₂ZnSnS₄(CZTS) thin‐film solar cell absorbers with different bandgaps can be produced by parameter variation during thermal treatments. Here, the effects of varied annealing time in a sulfur atmosphere and an ordering treatment of the absorber are compared. Chemical changes in the surface due to ordering are examined, and a downshift of the valence band edge is observed. With the goal to obtain different band alignments, these CZTS absorbers are combined with Zn_1?xSn_xO_y (ZTO) or CdS buffer layers to produce complete devices. A high open circuit voltage of 809 mV is obtained for an ordered CZTS absorber with CdS buffer layer, while a 9.7% device is obtained utilizing a Cd free ZTO buffer layer. The best performing devices are produced with a very rapid 1 min sulfurization, resulting in very small grains.     

Equivalent Voltage and Current Waves for TM SPP in Graphene Sheets

We present a theoretical model to describe the propagation of a transverse magnetic surface plasmon polariton in graphene based on equivalent voltage and charge current waves, which includes the spatial dispersion effect. Electrons and holes in graphene are governed by the Boltzmann equation in the particle conserving relaxation time approximation. First, we deduce expressions for the non-equilibrium distributions when there are charge oscillations in graphene as a response to the electromagnetic field applied to it. These distribution functions are used in the Boltzmann equations to derive other equations for the following four local macroscopic averages: the oscillating electron and hole densities, and the electron and hole current densities. Then, for a specific structure, we solve the wave equations for the electric and vector magnetic potentials to obtain the relations between the charge oscillations and the potentials. So, we reach a homogeneous system of four coupled equations relating the amplitudes of the voltage and the current waves. The non-trivial solutions of the system allow us to compute the dispersion and loss curves for such waves. As it is already known, for a given frequency, we can see that the higher the Fermi level is, the lesser the spatial-dispersion effect is. Following the analysis, a distributed-element circuit for the equivalent transmission line in which would propagate the waves, is developed. Finally, we analyze the dependence of these circuit elements and the impedance on both the frequency and Fermi level.

     

Aspects of fast-ion dosimetry

A first step in the dosimetry of fast-ion beams is the determination of accurate Bragg (ionization) functions. Bragg functions for several substances have been measured and calculated for 3480 MeV carbon ions. In the measurements, the ions first traverse an absorber in which the energy is reduced to either 1900 or 1200 MeV, then a "range gauge" followed by a thin ionization chamber. Functions are calculated with an analytical method using convolutions of straggling functions. This approach gives results without the stochastic variations implicit in Monte Carlo methods. The comparison of measured and calculated functions shows how reliable the calculations are. An important part of the calculations is the determination of the total range of the ions. The range can be determined from the Bragg function. The measured range is given by the sum of the thickness of the absorber and the residual range measured with the range gauge. For water, the range is about 150 mm, and the precision of the measurements is +/-0.05 mm. Because the ion energy at the surface of the absorber fluctuates with time, measurements with water are used to define this energy. Thus the ranges (or average stopping powers) in absorbers are obtained relative to those in water. Measured ranges R(m) are compared with ranges R(0) calculated with a current version of the Bethe theory. For light absorbers (atomic number Z < 20), differences between R(m) and R(0) are less than +/-0.3 mm; for Z > 20 differences are between 0 and +/-0.6 mm. This agreement between calculated and measured ranges confirms the value I = 80 eV for water measured earlier for protons. The ionization by nuclear fragments is obtained from the difference between measured and calculated ionization functions, and has little influence on the ranges of the primary ions.     

A Newfangled Terahertz Absorber Tuned Temper by Temperature Field Doped by the Liquid Metal

In this article, a terahertz absorber tuned by temperature field with a newfangled structure is presented, which comprises the mercury resonators. In this scheme, temperature (T) build-up will lead the mercury stored in the bottom slot to expand through the columniform hole and be full of the upper central cross container, which can transform the absorption bands of such an absorber. The simulated results manifest that when T is increased from 0 to 25 °C, the dual-frequency absorption points (2.59 THz, 3.03 THz) and a narrow absorption region over 90% (6.54–7.10 THz), whose relative bandwidth (RB) is 7.9%, will be tailored to a single-frequency point absorption (3.12 THz) and a broadband absorption area (6.00–7.21 THz, and RB = 18.3%). For figuring out the property of the absorber mentioned above, the impacts of incident and polarization angles along with some relevant parameters of the structure on the absorption property are investigated. In addition, for plainly expounding the physical mechanism of absorption, the distributions of the surface current diagrams of the presented absorber are calculated, as well as the electric field diagrams, the magnetic field diagrams, the power loss density diagrams, and the power flow density diagrams. The proffered scheme in this article may offer a novel idea for realizing the reconfigurable absorbers.

     

Transparent Cuprous Oxide Photocathode Enabling a Stacked Tandem Cell for Unbiased Water Splitting

Photoelectrochemical water splitting represents an attractive method of capturing and storing the immense energy of sunlight in the form of hydrogen, a clean chemical fuel. Given the large energetic demand of water electrolysis, and the defined spectrum of photons available from incident sunlight, a two absorber tandem device is required to achieve high efficiencies. The two absorbers should be of different and complementary bandgaps, connected in series to achieve the necessary voltage, and arranged in an optical stack configuration to maximize the utilization of sunlight. This latter requirement demands a top device that is responsive to high‐energy photons but also transparent to lower‐energy photons, which pass through to illuminate the bottom absorber. Here, cuprous oxide (Cu₂O) is employed as a top absorber component, and the factors influencing the balance between transparency and efficiency toward operation in a tandem configuration are studied. Photocathodes based on Cu₂O electrodeposited onto conducting glass substrates treated with thin, discontinuous layers of gold achieve reasonable sub‐bandgap transmittance while retaining performances comparable to their opaque counterparts. This new high‐performance transparent photocathode is demonstrated in tandem with a hybrid perovskite photovoltaic cell, resulting in a full device capable of standalone sunlight‐driven water splitting.     

A Tunable Perfect THz Metamaterial Absorber with Three Absorption Peaks Based on Nonstructured Graphene

In this paper, a graphene-based tunable multi-band terahertz absorber is proposed and numerically investigated. The proposed absorber can achieve perfect absorption within both sharp and ultra-broadband absorption spectra. This wide range of absorption is gathered through a unique combination of periodically cross- and square-shaped dielectrics sandwiched between two graphene sheets; the latter enables it to offer more absorption in comparison with the traditional single-layer graphene structures. The aforementioned top layer is mounted on a gold plate separated by a Topas layer with zero volume loss. Furthermore, in our proposed approach, we investigated the possibility of changing the shapes and sizes of the dielectric layers instead of the geometry of the graphene layers to alleviate the edge effects and manufacturing complications. In numerical simulations, parameters, such as graphene Fermi energy and the dimensions of the proposed dielectric layout, have been optimally tuned to reach perfect absorption. We have verified that the performance of our dielectric layout called fishnet, with two widely investigated dielectric layouts in the literature (namely, cross-shaped and frame-and-square). Our results demonstrate two absorption bands with near-unity absorbance at frequencies of 1.6–2.3 and 4.2–4.9 THz, with absorption efficiency of 98% in 1.96 and 4.62 THz, respectively. Moreover, a broadband absorption in the 7.77–9.78 THz is observed with an absorption efficiency of 99.6% that was attained in 8.44–9.11 THz. Finally, the versatility provided by the tunability of three operation bands of the absorber makes it a great candidate for integration into terahertz optoelectronic devices.

     

Flexible and Salt Resistant Janus Absorbers by Electrospinning for Stable and Efficient Solar Desalination

With recent progress in interfacial solar steam generation, direct solar desalination is considered a promising technology for providing a clean water solution through a cost effective and environmental‐friendly pathway. As a high and stable water production rate is the key to enable widespread applications, salt deposition becomes a critical issue that needs to be addressed. Herein, the authors demonstrate that a flexible Janus absorber fabricated by sequential electrospinning can enable stable and efficient solar desalination. Taking advantage of the unique structure of Janus, two functions of steam generation, solar absorption and water pumping, are decoupled into different layers, with an upper hydrophobic carbon black nanoparticles (CB) coating polymethylmethacrylate (PMMA) layer for light absorption, and a lower hydrophilic polyacrylonitrile (PAN) layer for pumping water. Therefore, salt can only be deposited in the hydrophilic PAN layer and quickly be dissolved because of continuous water pumping. Janus absorber demonstrates high efficiency (72%) and stable water output (1.3 kg m^–2 h^–1, over 16 days) under 1‐sun, not achieved in most previous absorbers. With a unique structure design achieved by scalable process, this flexible Janus absorber provides an efficient, stable and portable solar steam generator for direct solar desalination.     

A Compact Design of Multiband Terahertz Metamaterial Absorber with Frequency and Polarization Tunability

A new and simple design of quad-band metamaterial absorber for terahertz frequency has been proposed. The unit cell of the absorber is composed of a top metallic patch having H-shaped slot and a ground metallic plane, both separated by a dielectric layer. The proposed design is capable of providing four distinct absorption peaks over at 0.81, 1.98, 3.25, and 3.50 THz. Our design is a step ahead of the previously proposed terahertz absorbers for its simplistic design approach which removes the fabrication difficulty. Interestingly, rather placing multiple resonators in a single unit cell, we able to accommodate multiple orders of resonances in the proposed design using only a single metallic structure to achieve multiband absorbance. The sensing performance of the absorber in terms of surrounding index is also analyzed. Moreover, we have shown how the proposed structure can be easily converted into a frequency tunable absorber using a simple stub without changing the overall geometry of the absorber. This fast and easy frequency tunability feature is an additional advantage over the simple design of the structure. Also, we lead our work to its upgradation into a polarization tunable absorber where the absorption frequencies are controllable by the polarization of the incident light. The vibrant design of the proposed absorber is expected to find application in detection, imaging, radar cross-section (RCS) reduction, and sensing-related activities.     

Photoexcited triplet states of new UV absorbers, cinnamic acid 2-methylphenyl esters

Phosphorescence spectra of nonphosphorescent or very weakly phosphorescent new UV absorbers, 2-methylphenyl cinnamate (MePC), 2-methylphenyl 4-methoxycinnamate (MePMC) and 2-methylphenyl 4-ethoxycinnamate (MePEC) have been observed by using external heavy atom effects of ethyl iodide in ethanol at 77 K. The lowest excited triplet (T(1)) energies of these new UV absorbers are lower than those of a widely used UV-A absorber, 4-tert-butyl-4'-methoxydibenzoylmethane (BM-DBM), in both keto and enol forms. The intermolecular triplet-triplet energy transfer from photolabile BM-DBM to MePMC was observed by measuring the time-resolved phosphorescence spectra. Electron paramagnetic resonance spectra have been observed for the T(1) states of these new UV absorbers in ethanol at 77 K by using benzophenone as a triplet sensitizer. The observed T(1) lifetimes, zero-field splitting (ZFS) parameters and molecular orbital calculations of the ZFS parameters suggest that T(1) states of these new UV absorbers posses mainly (3)ππ* character. The deactivation processes of the lowest excited singlet (S(1)) states are predominantly fluorescence and internal conversion to the ground (G) states in MePMC and MePEC, while the main deactivation process of the S(1) state of MePC is internal conversion to the G state. The molar absorption coefficients of MePMC and MePEC in the UV-A and UV-B regions are larger than that of most widely used UV-B absorber, octyl methoxycinnamate.     

First-principle study of the native defects in GaAs saturable absorbers

The change of atom configuration in GaAs, caused by intrinsic point defects (Ga and As vacancies, Ga and As antisites, Ga and As interstitials), is first calculated by a plane wave pseudo-potential method with the generalised gradient approximation in the frame of density functional theory, and the most stable structure is obtained. Then, the formation energy of each kind of the native defect is calculated, by which the possibilities of the six kinds of point defects to be formed during crystal growth are analysed. The defect energy levels corresponding to each kind of the native point defect and their electron occupancy are analysed from the aspect of density of states. Finally, the elastic constants of GaAs saturable absorbers with native point defects are calculated, and the impacts on the elastic properties brought by native point defects are studied. The values of defect energy levels obtained will be helpful in ascertaining the mechanism of the EL2 deep level in the GaAs saturable absorber, and the analysis of the elastic properties of a GaAs crystal with native point defects will be helpful in guiding the application of the GaAs crystal as a saturable absorber in passively Q-switched lasers.     

Quartet-mapping, a generalization of the likelihood-mapping procedure.

Likelihood-mapping (LM) was suggested as a method of displaying the phylogenetic content of an alignment. However, statistical properties of the method have not been studied. Here we analyze the special case of a four-species tree generated under a range of evolution models and compare the results with those of a natural extension of the likelihood-mapping approach, geometry-mapping (GM), which is based on the method of statistical geometry in sequence space. The methods are compared in their abilities to indicate the correct topology. The performance of both methods in detecting the star topology is especially explored. Our results show that LM tends to reject a star tree more often than GM. When assumptions about the evolutionary model of the maximum-likelihood reconstruction are not matched by the true process of evolution, then LM shows a tendency to favor one tree, whereas GM correctly detects the star tree except for very short outer branch lengths with a statistical significance of >0.95 for all models. LM, on the other hand, reconstructs the correct bifurcating tree with a probability of >0.95 for most branch length combinations even under models with varying substitution rates. The parameter domain for which GM recovers the true tree is much smaller. When the exterior branch lengths are larger than a (analytically derived) threshold value depending on the tree shape (rather than the evolutionary model), GM reconstructs a star tree rather than the true tree. We suggest a combined approach of LM and GM for the evaluation of starlike trees. This approach offers the possibility of testing for significant positive interior branch lengths without extensive statistical and computational efforts.     

Calculation of electric fields induced in the human knee by a coil applicator

Calculations are presented of the induced electric fields and current densities in the cartilage of the knee produced by a coil applicator developed for applying pulsed magnetic fields to osteoarthritic knees. This applicator produces a sawtooth-like magnetic field waveform composed of a series of 260-micros pulses with a peak to peak magnitude of approximately 0.12 mT in the cartilage region. The simulations were performed using a recently developed 3 dimensional finite difference frequency domain technique for solving Maxwell's equations with an equivalent circuit model. The tissue model was obtained from the anatomically segmented human body model of Gandhi. The temporal peak electric field magnitude was found to be -153 mV/m, averaged within the medial cartilage of the knee for the typical dB/dt excitation levels of this coil. The technique can be extended to analyze other excitation waveforms and applicator designs.