Purpose
The protocols of carbon footprints generally define three scopes for different greenhouse gas (GHG) emissions levels. The most important carbon footprint emissions source comes from upstream indirect emissions of scope 3 for products that do not consume energy during their use phase. Upstream scope 3 GHG inventory can usually be analyzed through input–output or hybrid LCA analysis. The economic input–output life cycle analysis (EIO-LCA) and the hybrid LCA model have been widely used for this purpose. However, a cutoff error exists in the hybrid model, and the lack of a truncation criterion between process and IO inventory may lead to a high level of uncertainty in the hybrid model. This study attempts to improve the problem of cutoff uncertainty in hybrid LCA and proposes a method to minimize the cutoff uncertainty.Methods
The way to improve the cutoff uncertainty could follow two steps. First, through the IO inventory analysis of EIO-LCA, we can define the emissions by various tiers of product components. The IO inventory indicator can provide a definitive criterion for the process inventory of the hybrid model. Second, we connect the process- and IO-LCI according to the IO inventory result. The advantage of the process inventory is that it provides detailed manufacturing information on the target while the IO encompasses a complete system boundary. For improvements, the process inventory can catch the most important process of the GHG emissions, and the IO inventory could compensate for the remainder of the incomplete system inventory.Results and discussion
In this case study, the printed circuit board production process is used to evaluate the efficiency of the improved method. The threshold M was set to 70 in this case study, and the IO inventory provides the remaining 30 %. For the integrated hybrid model, the tier 3 process inventory takes only 64 % while the incorporation of the proposed method can include 92 % of the total emissions, which shows the cutoff uncertainty can be reduced through the improvement.Conclusions
This study provides a clear guideline for process and IO cutoff criteria, which can help the truncation uncertainty. When higher precision is required, process LCI will need to play an important role, and thus, a higher M value should be set. In this situation, the emissions from IO-LCI would be smaller than the emissions from the process LCI. The appropriate solution would attain a comfortable balance between data accuracy and time and labor consumption. 相似文献Purpose
Life cycle assessment (LCA) of chemicals is usually developed using a process-based approach. In this paper, we develop a tiered hybrid LCA of water treatment chemicals combining the specificity of process data with the holistic nature of input–output analysis (IOA). We compare these results with process and input–output models for the most commonly used chemicals in the Australian water industry to identify the direct and indirect environmental impacts associated with the manufacturing of these materials.Methods
We have improved a previous Australian hybrid LCA model by updating the environmental indicators and expanding the number of included industry sectors of the economy. We also present an alternative way to estimate the expenditure vectors to the service sectors of the economy when financial data are not available. Process-based, input–output and hybrid results were calculated for caustic soda, sodium hypochlorite, ferric chloride, aluminium sulphate, fluorosilicic acid, calcium oxide and chlorine gas. The functional unit is the same for each chemical: the production of 1 tonne in the year 2008.Results and discussion
We have provided results for seven impact categories: global warming potential; primary energy; water use; marine, freshwater and terrestrial ecotoxicity potentials and human toxicity potential. Results are compared with previous IOA and hybrid studies. A sensitivity analysis of the results to assumed wholesale prices is included. We also present insights regarding how hybrid modelling helps to overcome the limitations of using IO- or process-based modelling individually.Conclusions and recommendations
The advantages of using hybrid modelling have been demonstrated for water treatment chemicals by expanding the boundaries of process-based modelling and also by reducing the sensitivity of IOA to fluctuations in prices of raw materials used for the production of these industrial commodities. The development of robust hybrid life cycle inventory databases is paramount if hybrid modelling is to become a standard practice in attributional LCA. 相似文献Uncertainty analyses in life cycle assessment (LCA) literature have focused primarily on the life cycle inventory (LCI) phase, but LCA experts generally agree that the life cycle impact assessment (LCIA) phase is likely to contribute even more to the overall uncertainty of an LCA result. The magnitude of perceived uncertainties in characterization relative to that in LCI, however, has not been examined in the literature. Here, we use the pedigree approach to gauge the perceived uncertainty in the characterization phase relative to the LCI phase. In addition, we evaluate the level of approval on the pedigree approach as a means to characterize uncertainty in LCA.
MethodsApplying the Numeral Unit Spread Assessment Pedigree (NUSAP) approach to environmental risk assessment literature, we extracted the criteria for evaluating the uncertainty in the characterization phase. We used expert elicitation to identify a pool of experts and conducted a survey, to which 47 LCA practitioners from 12 countries responded. In order to reduce personal biases in perceived geometric standard deviation (GSD) values, we used two reference questions on weight and life expectancy at birth for calibration.
ResultsNearly half (49%) of respondents expressed their approval to the pedigree matrix approach as a means of characterizing uncertainties in LCA, and responses were highly sensitive to the respondent’s familiarity with the pedigree matrix. For instance, respondents who are highly familiar with the pedigree matrix were more polarized, with 15% and 19% of them expressing either strong approval or strong disapproval, respectively. Respondents less familiar with the pedigree approach were generally more favorable to its use. Compared with LCI, variability in characterization factors was influenced more strongly by geographical correlation and reliability of the underlying model, which showed 11 to 16% larger average GSDs when compared with the comparable criteria for LCI. Conversely, temporal correlation criterion was a less significant factor in characterization than in LCI.
Conclusions and discussionOverall, survey respondents viewed LCIA characterization as only marginally more uncertain than LCI, but with a wider variability in responses on characterization than LCI. This finding indicates the need for additional research to develop more thorough methods for characterizing uncertainties in life cycle impact assessment that are compatible with the uncertainty measures in LCI.
相似文献It is frequently mentioned in literature that LCA is linear, without a proof, or even without a clear definition of the criterion for linearity. Here we study the meaning of the term linear, and in relation to that, the question if LCA is indeed linear.
MethodsWe explore the different meanings of the term linearity in the context of mathematical models. This leads to a distinction between linear functions, homogeneous functions, homogenous linear functions, bilinear functions, and multilinear functions. Each of them is defined in accessible terms and illustrated with examples.
ResultsWe analyze traditional, matrix-based, LCA, and conclude that LCA is not linear in any of the senses defined.
Discussion and conclusionsDespite the negative answer to the research question, there are many respects in which LCA can be regarded to be, at least to some extent, linear. We discuss a few of such cases. We also discuss a few practical implications for practitioners of LCA and for developers of new methods for LCI and LCIA.
相似文献Awareness regarding carbon and water footprint has gained visibility, encouraging actions towards compliance with the main available standards by fruit producers. This study presents the carbon and water footprint of packed mango produced in Vale do São Francisco, the main irrigated valley in Brazil. It provides an approach to identify the critical processes and opportunities for improvements in the conventional crop system that may support producers in the task of developing future site-specific assessments.
MethodsThis assessment followed ISO 14046 and ISO 14067 for water and carbon footprints, respectively, as well as specific requirements of product category rule (PCR) 013 for fruits and nuts and Publicly Available Specification (PAS) 2051-1 for horticulture products. Primary data was collected for nursery (seedling), land use change, crop production, and packaging, considering five exported mango varieties: Palmer, Keitt, Kent, Haden, and Tommy Atkins. The carbon footprint assessment was based on the impact category climate change, while water footprint encompassed the following categories: water scarcity, marine and freshwater eutrophication, human toxicity (carcinogenic and non-carcinogenic), and freshwater ecotoxicity. The footprint analysis was performed for 1 kg of packed mango.
Results and discussionThe three main processes responsible for both footprints were related to crop production: fertilizer and electricity production as well as mango cropping. Moving from Caatinga vegetation to mango orchards increased carbon storage but was not enough to offset the impact on climate change. For water footprint, it was observed that the total volume of applied irrigation water was already below technical requirements and cannot be reduced, the same occurring for nitrogen fertilization. Scenario analysis showed that the use of alternative electricity sources and the reuse of wastewater brought no major improvement in results. Furthermore, the choice of local or country level characterization factors for water scarcity changed results significantly. Discussions are made regarding (i) the relevance of mango footprints when compared to other irrigated fruits, (ii) possibilities for improving mango footprint performance, (iii) the need for updating product category rules for fruits, and (iv) the quality of provided inventories and results.
ConclusionsThe comparison of mango footprints with previous studies of irrigated fruits showed that mango performance is similar or better than many irrigated fruits, cultivated all over the world. Moreover, footprints may be further reduced if mango orchards are established in previously deforested land or areas occupied with annual crops and if improvements are made in the irrigation and fertilization practices at each mango production stage.
相似文献One aim of LCA-based rating tools developed by the apparel industry is to promote a change in demand for textiles by influencing consumer preferences based on the environmental footprint of textiles. Despite a growing consensus that footprints developed using attributional LCA (aLCA) are not suitable to inform decisions that will impact supply and demand, these tools continue to use aLCA. This paper analyses the application of the LCA methods to wool production, specifically the application of aLCA methods that provide a retrospective assessment of impacts and consequential (cLCA) methods that estimate the impacts of a change.
MethodsAttributional and consequential life cycle inventories (LCIs) were developed and analysed to examine how the different methodological approaches affect the estimated environmental impacts of wool.
Results and discussionLife cycle impact assessment (LCIA) of aLCI and cLCI for wool indicates that estimated global warming and water stress impacts may be considerably lower for additional production of wool, as estimated by cLCIA, than for current production as estimated by aLCIA. However, fossil resource impacts for additional production may be greater than for current production when increased wool production was assumed to displace dedicated sheep meat production.
ConclusionsThis work supports the notion that the use of a retrospective assessment method (i.e. aLCA) to produce information that will guide consumer preferences may not adequately represent the impacts of a consumer’s choice because the difference between aLCIA and cLCIA results may be relatively large. As such, rating tools based on attributional LCA are unlikely to be an adequate indicator of the sustainability of textiles used in the apparel industry.
相似文献Despite the wide use of LCA for environmental profiling, the approach for determining the system boundary within LCA models continues to be subjective and lacking in mathematical rigor. As a result, life cycle models are often developed in an ad hoc manner, and are difficult to compare. Significant environmental impacts may be inadvertently left out. Overcoming this shortcoming can help elicit greater confidence in life cycle models and their use for decision making.
MethodsThis paper describes a framework for hybrid life cycle model generation by selecting activities based on their importance, parametric uncertainty, and contribution to network complexity. The importance of activities is determined by structural path analysis—which then guides the construction of life cycle models based on uncertainty and complexity indicators. Information about uncertainty is from the available life cycle inventory; complexity is quantified by cost or granularity. The life cycle model is developed in a hierarchical manner by adding the most important activities until error requirements are satisfied or network complexity exceeds user-specified constraints.
Results and DiscussionThe framework is applied to an illustrative example for building a hybrid LCA model. Since this is a constructed example, the results can be compared with the actual impact, to validate the approach. This application demonstrates how the algorithm sequentially develops a life cycle model of acceptable uncertainty and network complexity. Challenges in applying this framework to practical problems are discussed.
ConclusionThe presented algorithm designs system boundaries between scales of hybrid LCA models, includes or omits activities from the system based on path analysis of environmental impact contribution at upstream network nodes, and provides model quality indicators that permit comparison between different LCA models.
相似文献Purpose
Topsoil erosion due to land use has been characterised as one of the most damaging problems from the perspective of soil-resource depletion, changes in soil fertility and net soil productivity and damage to aquatic ecosystems. On-site environmental damage to topsoil by water erosion has begun to be considered in Life Cycle Assessment (LCA) within the context of ecosystem services. However, a framework for modelling soil erosion by water, addressing off-site deposition in surface water systems, to support life cycle inventory (LCI) modelling is still lacking. The objectives of this paper are to conduct an overview of existing methods addressing topsoil erosion issues in LCA and to develop a framework to support LCI modelling of topsoil erosion, transport and deposition in surface water systems, to establish a procedure for assessing the environmental damage from topsoil erosion on water ecosystems.Methods
The main features of existing methods addressing topsoil erosion issues in LCA are analysed, particularly with respect to LCI and Life Cycle Impact Assessment methodologies. An overview of nine topsoil erosion models is performed to estimate topsoil erosion by water, soil particle transport through the landscape and its in-stream deposition. The type of erosion evaluated by each of the models, as well as their applicable spatial scale, level of input data requirements and operational complexity issues are considered. The WATEM-SEDEM model is proposed as the most adequate to perform LCI erosion analysis.Results and discussion
The definition of land use type, the area of assessment, spatial location and system boundaries are the main elements discussed. Depending on the defined system boundaries and the inherent routing network of the detached soil particles to the water systems, the solving of the multifunctionality of the system assumes particular relevance. Simplifications related to the spatial variability of the input data parameters are recommended. Finally, a sensitivity analysis is recommended to evaluate the effects of the transport capacity coefficient in the LCI results.Conclusions
The published LCA methods focus only on the changes of soil properties due to topsoil erosion by water. This study provides a simplified framework to perform an LCI of topsoil erosion by considering off-site deposition of eroded particles in surface water systems. The widespread use of the proposed framework would require the development of LCI erosion databases. The issues of topsoil erosion impact on aquatic biodiversity, including the development of characterisation factors, are now the subject of on-going research. 相似文献Objective uncertainty quantification (UQ) of a product life-cycle assessment (LCA) is a critical step for decision-making. Environmental impacts can be measured directly or by using models. Underlying mathematical functions describe a model that approximate the environmental impacts during various LCA stages. In this study, three possible uncertainty sources of a mathematical model, i.e., input variability, model parameter (differentiate from input in this study), and model-form uncertainties, were investigated. A simple and easy to implement method is proposed to quantify each source.
MethodsVarious data analytics methods were used to conduct a thorough model uncertainty analysis; (1) Interval analysis was used for input uncertainty quantification. A direct sampling using Monte Carlo (MC) simulation was used for interval analysis, and results were compared to that of indirect nonlinear optimization as an alternative approach. A machine learning surrogate model was developed to perform direct MC sampling as well as indirect nonlinear optimization. (2) A Bayesian inference was adopted to quantify parameter uncertainty. (3) A recently introduced model correction method based on orthogonal polynomial basis functions was used to evaluate the model-form uncertainty. The methods are applied to a pavement LCA to propagate uncertainties throughout an energy and global warming potential (GWP) estimation model; a case of a pavement section in Chicago metropolitan area was used.
Results and discussionResults indicate that each uncertainty source contributes to the overall energy and GWP output of the LCA. Input uncertainty was shown to have significant impact on overall GWP output; for the example case study, GWP interval was around 50%. Parameter uncertainty results showed that an assumption of ±?10% uniform variation in the model parameter priors resulted in 28% variation in the GWP output. Model-form uncertainty had the lowest impact (less than 10% variation in the GWP). This is because the original energy model is relatively accurate in estimating the energy. However, sensitivity of the model-form uncertainty showed that even up to 180% variation in the results can be achieved due to lower original model accuracies.
ConclusionsInvestigating each uncertainty source of the model indicated the importance of the accurate characterization, propagation, and quantification of uncertainty. The outcome of this study proposed independent and relatively easy to implement methods that provide robust grounds for objective model uncertainty analysis for LCA applications. Assumptions on inputs, parameter distributions, and model form need to be justified. Input uncertainty plays a key role in overall pavement LCA output. The proposed model correction method as well as interval analysis were relatively easy to implement. Research is still needed to develop a more generic and simplified MCMC simulation procedure that is fast to implement.
相似文献A scalable life cycle inventory (LCI) model, which provides mass composition and gate-to-gate manufacturing data for a power electronic inverter unit intended for controlling electric vehicle propulsion motors, was developed. The purpose is to fill existing data gaps for life cycle assessment (LCA) of electric vehicles. The model comprises new and easy-to-use data with sufficient level of detail to enable proper component scaling and in-depth analysis of inverter units. The aim of this article (part II) is to describe the modeling of all production steps and present new datasets. Another objective is to explain the strategies for data collection, system boundaries, and how unit process datasets were made to interact properly with the scalable design model (part I).
MethodsData for the manufacturing of the inverter unit was collected from a variety of literature, technical specifications, factory data, site visits, and expert interviews. The model represents current levels of technology and modern industrial scale production. Industry data dates back to 2012. Some older literature is referred to, but only if it was found to remain relevant. Upstream, new data has been gathered to the point where the Ecoinvent database can be used to model a full cradle-to-gate inventory. To make the LCI model easy to use, each flow crossing the system boundary is reported with a recommended linked flow to this database.
Results and discussionThe screening and modeling of manufacturing inverter units resulted in a substantial compilation of new inventory data. In close integration with the design model, which is scalable in size over a range of 20–200 kW in nominal power and 250–700 V in DC system voltage (part I), it forms a comprehensive scalable LCI model of a typical automotive power electronic inverter unit intended for traction motor control. New production data covers electroplating of gold, electro-galvanization, machining and anodizing of aluminum, ceramic substrate fabrication, direct copper bonding, photoimaging and regenerative etching, power module assembly with a two-step soldering process, and the assembly of automotive printed circuit boards.
ConclusionsInterviews with experts were found to be vital for effective data collection and the reporting of details a key to maintaining data usability over time, for reuse, rework, and criticism by other LCA practitioners.
相似文献A review of LCA process datasets is an important element of quality assurance for databases and for other systems to provide LCA datasets. Somewhat surprisingly, a broadly accepted and applicable set of criteria for a review of LCA process datasets was lacking so far. Different LCA databases and frameworks are proposing and using different criteria for reviewing datasets. To close this gap, a set of criteria for reviewing LCA dataset has been developed within the Life Cycle Initiative.
MethodsPrevious contributions to LCA dataset review have been analysed for a start, from ISO and various LCA databases. To avoid somewhat arbitrary review criteria, four basic rules are proposed which are to be fulfilled by any dataset. Further, concepts for assessing representativeness and relevance are introduced into the criteria set from established practices in statistics and materiality. To better structure the criteria and to ease their application, they are grouped into clusters. A first version of the developed review criteria was presented in two workshops with database providers and users on different levels of experience, and draft versions of the criteria were shared within the initiative. The current version of the criteria reflects feedback received from various stakeholders and has been applied and tested in a review for newly developed datasets in Brazil, Malaysia and Thailand.
Results and discussionOverall, 14 criteria are proposed, which are organised in clusters. The clusters are goal, model, value, relevance and procedure. For several criteria, a more science-based definition and evaluation is proposed in comparison to ‘traditional’ LCA. While most of the criteria depend on the goal and scope of dataset development, a core set of criteria are seen as essential and independent from specific LCA modelling. For all the criteria, value scales are developed, typically using an ordinal scale, following the pedigree approach.
ConclusionsReview criteria for LCI datasets are now defined based on a stringent approach. They aim to be globally acceptable, considering also database interoperability and database management aspects, as well as feedback received from various stakeholders, and thus close an important gap in LCA dataset quality assurance. The criteria take many elements of already existing criteria but are the first to fully reflect the implications of the ISO data quality definition, and add new concepts for representativeness and relevance with the idea to better reflect scientific practice outside of the LCA domain. A first application in a review showed to be feasible, with a level of effort similar to applying other review criteria. Aspects not addressed yet are the review procedure and the mutual recognition of dataset reviews, and their application for a very high number of datasets.
相似文献