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Nanomaterials are expected to play an important role in the development of sustainable products. The use of nanomaterials in solar cells has the potential to increase their conversion efficiency. In this study, we performed a life cycle assessment (LCA) for an emerging nanowire‐based solar technology. Two lab‐scale manufacturing routes for the production of nanowire‐based solar cells have been compared—the direct growth of GaInP nanowires on silicon substrate and the growth of InP nanowires on native substrate, peel off, and transfer to silicon substrate. The analysis revealed critical raw materials and processes of the current lab‐scale manufacturing routes such as the use of trifluoromethane (CHF3), gold, and an InP wafer and a stamp, which are used and discarded. The environmental performance of the two production routes under different scenarios has been assessed. The scenarios include the use of an alternative process to reduce the gold requirements—electroplating instead of metallization, recovery of gold, and reuse of the InP wafer and the stamp. A number of suggestions, based on the LCA results—including minimization of the use of gold and further exploration for upscaling of the electroplating process, the increase in the lifetimes of the wafer and the stamp, and the use of fluorine‐free etching materials—have been communicated to the researchers in order to improve the environmental performance of the technology. Finally, the usefulness and limitations of lab‐scale LCA as a tool to guide the sustainable development of emerging technologies are discussed.  相似文献   

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When software is used to facilitate life cycle assessments (LCAs), the implicit assumption is that the results obtained are not a function of the choice of software used. LCAs were done in both SimaPro and GaBi for simplified systems of creation and disposal of 1 kilogram each of four basic materials (aluminum, corrugated board, glass, and polyethylene terephthalate) to determine whether there were significant differences in the results. Data files and impact assessment methodologies (Impact 2002, ReCiPe, and TRACI 2) were ostensibly identical (although there were minor variations in the available ReCiPe version between the programs that were investigated). Differences in reported impacts of greater than 20% for at least one of the four materials were found for 9 of the 15 categories in Impact 2002+, 7 of the 18 categories in ReCiPe, and four of the nine categories in TRACI. In some cases, these differences resulted in changes in the relative rankings of the four materials. The causes of the differences for 14 combinations of materials and impact categories were examined by tracing the results back to the life cycle inventory data and the characterization factors in the life cycle impact assessment (LCIA) methods. In all cases examined, a difference in the characterization factors used by the two programs was the cause of the differing results. As a result, when these software programs are used to inform choices, the result can be different conclusions about relative environmental preference that are functions purely of the software implementation of LCIA methods, rather than of the underlying data.  相似文献   

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Life cycle inventory data have multiple sources of uncertainty. These data uncertainties are often modeled using probability density functions, and in the ecoinvent database the lognormal distribution is used by default to model exchange uncertainty values. The aim of this article is to systematically measure the effect of this default distribution by changing from the lognormal to several other distribution functions and examining how this change affects the uncertainty of life cycle assessment results. Using the ecoinvent 2.2 inventory database, data uncertainty distributions are switched from the lognormal distribution to the normal, triangular, and gamma distributions. The effect of the distribution switching is assessed for both impact assessment results of individual products system, as well as comparisons between product systems. Impact assessment results are generated using 5,000 Monte Carlo iterations for each product system, using the Intergovernmental Panel on Climate Change (IPCC) 2001 (100‐year time frame) method. When comparing the lognormal distribution to the alternative default distributions, the difference in the resulting median and standard deviation values range from slight to significant, depending on the distributions used by default. However, the switch shows practically no effect on product system comparisons. Yet, impact assessment results are sensitive to how the data uncertainties are defined. In this article, we followed what we believe to be ecoinvent standard practice and preserved the “most representative” value. Practitioners should recognize that the most representative value can depart from the average of a probability distribution. Consistent default distribution choices are necessary when performing product system comparisons.  相似文献   

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A dissolved air flotation (DAF) system upgrade was proposed for an urban paper mill to recycle effluent. To understand the influence of operating variables on the environmental impacts of greenhouse gas (GHG) emissions and water consumption, a dynamic supply chain model was linked with life cycle assessment (LCA) to produce an environmental inventory. Water is a critical natural resource, and understanding the environmental impacts of recycling water is paramount in continued development of sustainable supply chains involving water. The methodology used in this study bridged the gap between detailed process models and static LCA modeling so that operating variables beyond discrete scenario analysis could be investigated without creating unnecessarily complex models. The model performed well in evaluating environmental impacts. It was found that there was no single optimum operating regime for all environmental impacts. For a mill discharging 80 cubic meters of effluent per hour (m3/hour), GHGs could be minimized with a DAF capacity of 17.5 m3/hour, while water consumption could be minimized with a DAF capacity of 25 m3/hour, which allowed insight into where environmental trade‐offs would occur. The study shows that more complexity can be achieved in supply chain modeling without requiring a full technical model. It also illustrates the need to consider multiple environmental impacts and highlights the trade‐off of GHG emissions with water consumption in water recycling. The supply chain model used in this water treatment case study was able to identify the environmental trade‐offs from the operating variables selected.  相似文献   

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This work contributes to the development of a dynamic life cycle assessment (DLCA) methodology by providing a methodological framework to link a dynamic system modeling method with a time‐dependent impact assessment method. This three‐step methodology starts by modeling systems where flows are described by temporal distributions. Then, a temporally differentiated life cycle inventory (TDLCI) is calculated to present the environmental exchanges through time. Finally, time‐dependent characterization factors are applied to the TDLCI to evaluate climate‐change impacts through time. The implementation of this new framework is illustrated by comparing systems producing domestic hot water (DHW) over an 80‐year period. Electricity is used to heat water in the first system, whereas the second system uses a combination of solar energy and gas to heat an equivalent amount of DHW at the same temperature. This comparison shows that using a different temporal precision (i.e., monthly vs. annual) to describe process flows can reverse conclusions regarding which case has the best environmental performance. Results also show that considering the timing of greenhouse gas (GHG) emissions reduces the absolute values of carbon footprint in the short‐term when compared with results from the static life cycle assessment. This pragmatic framework for the implementation of time in DLCA studies is proposed to help in the development of the methodology. It is not yet a fully operational scheme, and efforts are still required before DLCA can become state of practice.  相似文献   

7.
This article presents an approach to estimate missing elements in hybrid life cycle inventories. Its development is motivated by a desire to rationalize inventory compilation while maintaining the quality of the data. The approach builds on a hybrid framework, that is, a combination of process‐ and input–output‐based life cycle assessment (LCA) methodology. The application of Leontief's price model is central in the proposed procedure. Through the application of this approach, an inventory with no cutoff with respect to costs can be obtained. The formal framework is presented and discussed. A numerical example is provided in Supplementary Appendix S1 on the Web.  相似文献   

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The human health impact of fiber reinforced polymer (FRP) composite materials manufactured by the pultrusion industry is not fully understood. In particular, it is unclear whether the human health impact of toxic chemicals present in low concentrations in fire retardant pultruded FRP materials is disproportionately high. This impact may be an important criterion when making boundary selection decisions in the life cycle assessment (LCA) of these materials. The North American pultrusion industry was surveyed to determine resin mix concentration levels and workplace inhalation toxicity exposure levels. LCAs were then conducted on three building panel resin mixes to determine whether the human health impact of toxic chemicals used in the mixes was low enough to exclude the chemicals from the life cycle inventory (LCI) boundary. The first resin mix represented a typical pultruded product, the second mix removed toxic chemicals present in small concentrations, and the third mix replaced toxic chemicals present in small concentrations with a nontoxic chemical. Results showed that toxicity levels fell below exposure limits and no significant difference in human health impact existed among the LCAs. The research concludes that human health impact is a useful criterion when defining an LCI boundary. Toxic chemicals present in small concentrations in pultruded FRP materials may be excluded from the LCI boundary, as their human health impacts are low. Because these levels are marginal in North American pultrusion factories, no changes in resin mixes are recommended for the pultrusion industry.  相似文献   

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Electric vehicles (EVs) coupled with low‐carbon electricity sources offer the potential for reducing greenhouse gas emissions and exposure to tailpipe emissions from personal transportation. In considering these benefits, it is important to address concerns of problem‐shifting. In addition, while many studies have focused on the use phase in comparing transportation options, vehicle production is also significant when comparing conventional and EVs. We develop and provide a transparent life cycle inventory of conventional and electric vehicles and apply our inventory to assess conventional and EVs over a range of impact categories. We find that EVs powered by the present European electricity mix offer a 10% to 24% decrease in global warming potential (GWP) relative to conventional diesel or gasoline vehicles assuming lifetimes of 150,000 km. However, EVs exhibit the potential for significant increases in human toxicity, freshwater eco‐toxicity, freshwater eutrophication, and metal depletion impacts, largely emanating from the vehicle supply chain. Results are sensitive to assumptions regarding electricity source, use phase energy consumption, vehicle lifetime, and battery replacement schedules. Because production impacts are more significant for EVs than conventional vehicles, assuming a vehicle lifetime of 200,000 km exaggerates the GWP benefits of EVs to 27% to 29% relative to gasoline vehicles or 17% to 20% relative to diesel. An assumption of 100,000 km decreases the benefit of EVs to 9% to 14% with respect to gasoline vehicles and results in impacts indistinguishable from those of a diesel vehicle. Improving the environmental profile of EVs requires engagement around reducing vehicle production supply chain impacts and promoting clean electricity sources in decision making regarding electricity infrastructure.  相似文献   

10.
This article examines methods for analyzing allocation in life cycle assessment (LCA); it focuses on comparisons of economic allocation with other feasible alternatives. The International Organization for Standardization's (ISO) guideline 14044 indicates that economic allocation should only be used as a last resort, when other methods are not suitable. However, the LCA literature reports several examples of the use of economic allocation. This is due partly to its simplicity and partly to its ability to illustrate the properties of complex systems. Sometimes a price summarizes complex attributes of product or service quality that cannot be easily measured by physical criteria. On the other hand, economic allocation does have limitations arising, for example, from the variability of prices and the low correlation between prices and physical flows. This article presents the state of the debate on the topic and some hypothetical examples for illustration. A general conclusion is that it is not possible to determine one “best” allocation method. The allocation procedure has to be selected on a case‐by‐case basis and no single approach is suitable for every situation. Despite its limitations, economic allocation has certain qualities that make it flexible and potentially suitable for different contexts. In some situations, economic allocation should not be the last methodological resort. The option of economic allocation should be considered, for example, whenever the prices of coproducts and coservices differ widely.  相似文献   

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A model is presented for calculating the environmental burdens of the part manufacturing and vehicle assembly (VMA) stage of the vehicle life cycle. The model is based on a process‐level approach, accounting for all significant materials by their transformation processes (aluminum castings, polyethylene blow molding; etc.) and plant operation activities (painting; heating, ventilation, and air conditioning [HVAC], etc.) germane to VMA. Using quantitative results for these material/transformation process pairings, a percent‐by‐weight material/transformation distribution (MTD) function was developed that permits the model to be applied to a range of vehicles, both conventional and advanced (e.g., hybrid electric, light weight, aluminum intensive). Upon consolidation of all inputs, the model reduces to two terms: one proportional to vehicle mass and a plant overhead per vehicle term. When the model is applied to a materially well‐characterized conventional vehicle, reliable estimates of cumulative energy consumption (34 gigajoules/vehicle) and carbon dioxide (CO2) emissions (2 tonnes/vehicle) with coefficients of variation are computed for the VMA life cycle stage. Due to the more comprehensive coverage of manufacturing operations, our energy estimates are on the higher end of previously published values. Nonetheless, they are still somewhat underestimated due to a lack of data on overhead operations in part manufacturing facilities and transportation of parts and materials between suppliers and vehicle manufacturing operations. For advanced vehicles, the material/transformation process distribution developed above needs some adjusting for different materials and components. Overall, energy use and CO2 emissions from the VMA stage are about 3.5% to 4.5% of total life cycle values for vehicles.  相似文献   

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We develop a hybrid‐unit energy input‐output (I/O) model with a disaggregated electricity sector for China. The model replaces primary energy rows in monetary value, namely, coal, gas, crude oil, and renewable energy, with physical flow units in order to overcome errors associated with the proportionality assumption in environmental I/O analysis models. Model development and data use are explained and compared with other approaches in the field of environmental life cycle assessment. The model is applied to evaluate the primary energy embodied in economic output to meet Chinese final consumption for the year 2007. Direct and indirect carbon dioxide emissions intensities are determined. We find that different final demand categories pose distinctive requirements on the primary energy mix. Also, a considerable amount of energy is embodied in the supply chain of secondary industries. Embodied energy and emissions are crucial to consider for policy development in China based on consumption, rather than production. Consumption‐based policies will likely play a more important role in China when per capita income levels have reached those of western countries.  相似文献   

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A shortcoming in current data quality assessment schemes is that the data quality information is not used systematically to identify the critical data in a life cycle inventory (LCI) model. In addition, existing criteria employed to evaluate representativeness lack relevance to the specific context of a study. A novel framework is proposed herein for the evaluation of the representativeness of LCI data, including an analysis of the importance of the data and a modification of quality criteria based on unit process characteristics. Temporal characteristics are analyzed by identifying the technology shift, because data generated before this time are considered outdated. Geographical and technological characteristics are analyzed by defining a “related area” and a “related technology,” which is done by identifying a number of relevant geographical and technical factors, and then comparing the collected data with these factors. The framework was illustrated in a case study on household waste incineration in Denmark. The results demonstrated the applicability of the method in practice, and they provided data quality criteria unique to waste incineration unit processes, for example, different time intervals to evaluate temporal representativeness. However, the proposed method is time demanding, and thus sector‐level characteristic analyses are feasible instead of the user having to do the analyses.  相似文献   

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Life cycle assessment (LCA) and environmentally extended input–output analyses (EEIOA) are two techniques commonly used to assess environmental impacts of an activity/product. Their strengths and weaknesses are complementary, and they are thus regularly combined to obtain hybrid LCAs. A number of approaches in hybrid LCA exist, which leads to different results. One of the differences is the method used to ensure that mixed LCA and EEIOA data do not overlap, which is referred to as correction for double counting. This aspect of hybrid LCA is often ignored in reports of hybrid assessments and no comprehensive study has been carried out on it. This article strives to list, compare, and analyze the different existing methods for the correction of double counting. We first harmonize the definitions of the existing correction methods and express them in a common notation, before introducing a streamlined variant. We then compare their respective assumptions and limitations. We discuss the loss of specific information regarding the studied activity/product and the loss of coherent financial representation caused by some of the correction methods. This analysis clarifies which techniques are most applicable to different tasks, from hybridizing individual LCA processes to integrating complete databases. We finally conclude by giving recommendations for future hybrid analyses.  相似文献   

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This study proposes methods to improve data mining workflows for modeling chemical manufacturing life cycle inventory. Secondary data sources can provide valuable information about environmental releases during chemical manufacturing. However, the often facility‐level nature of the data challenges their utility for modeling specific processes and can impact the quality of the resulting inventory. First, a thorough data source analysis is performed to establish data quality scoring and create filtering rules to resolve data selection issues when source and species overlaps arise. A method is then introduced to develop context‐based filter rules that leverage process metadata within data sources to improve how facility air releases are attributed to specific processes and increase the technological correlation and completeness of the inventory. Finally, a sanitization method is demonstrated to improve data quality by minimizing the exclusion of confidential business information (CBI). The viability of the methods is explored using case studies of cumene and sodium hydroxide production in the United States. The attribution of air releases using process context enables more sophisticated filtering to remove unnecessary flows from the inventory. The ability to sanitize and incorporate CBI is promising because it increases the sample size, and therefore representativeness, when constructing geographically averaged inventories. Future work will focus on expanding the application of context‐based data filtering to other types and sources of environmental data.  相似文献   

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Life cycle assessment (LCA) is highly needed and widely used to assess the environmental performance of circular economy (CE) measures such as reusing and sharing. However, the results of such LCAs are hampered by limited knowledge about the use phase of consumer products and oversimplification of important use phase aspects such as product functionality, user behavior, displacement, and rebound effects. This paper aims to validate the usefulness of a framework designed to assist practitioners in the generation and utilization of such knowledge in LCAs of circular measures. To validate the framework, a case study is used: reuse of shell jackets enabled by “premium secondhand” stores for outdoor equipment and clothing. The paper demonstrates that conclusions about the environmental performance of reuse can easily be altered depending on the functional unit definition, whether real user behavior data are used, and whether imperfect displacement and rebound effects are considered. For instance, shell jacket life cycles that include reuse and thus may be labeled “circular” have significantly higher environmental impact per use occasion than “linear” ones (used by one principal user the entire lifespan), since “circular” shell jackets are used less frequently, in particular during their first use span. Through facilitating the generation and utilization of environmentally relevant use phase data, which are otherwise often overlooked, the framework seems capable of supporting a better understanding of the environmental performance of CE measures.  相似文献   

17.
Urban ecosystems and the North American carbon cycle   总被引：12，自引：0，他引：12  
Approximately 75–80% of the population of North America currently lives in urban areas as defined by national census bureaus, and urbanization is continuing to increase. Future trajectories of fossil fuel emissions are associated with a high degree of uncertainty; however, if the activities of urban residents and the rate of urban land conversion can be captured in urban systems models, plausible emissions scenarios from major cities may be generated. Integrated land use and transportation models that simulate energy use and traffic‐related emissions are already in place in many North American cities. To these can be added a growing dataset of carbon gains and losses in vegetation and soils following urbanization, and a number of methods of validating urban carbon balance modeling, including top down atmospheric monitoring and urban ‘metabolic’ studies of whole ecosystem mass and energy flow. Here, we review the state of our understanding of urban areas as whole ecosystems with regard to carbon balance, including both drivers of fossil fuel emissions and carbon cycling in urban plants and soils. Interdisciplinary, whole‐ecosystem studies of the socioeconomic and biophysical factors that influence urban carbon cycles in a range of cities may greatly contribute to improving scenarios of future carbon balance at both continental and global scales.  相似文献   

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Studies investigated the patient‐care (in‐hospital) and outside‐the‐hospital energy consumptions for delivering the hemodialysis (HD) service. A life cycle inventory methodology was used for this patient‐based analysis for two hospitals located in Wichita, Kansas. It was found that, for both hospitals, the actual HD machines consumed approximately 3.5 kilowatt‐hours (kWh) of electrical energy per HD, only 8% to 16% of the total energy used for delivering the HD service (in hospital). This increases to 9.6 to 28.9 kWh of hospital billable energy for the whole system of HD machine, auxiliaries, and dialysis water treatment. Converting these hospital direct electrical energy values to natural resource energy (nre) then adding the cradle‐to‐gate natural resource energy for the manufacturing and supply chain of all the HD consumables, the total is 78 to 149 kWh nre/HD. The nre measures all the direct fuel burned to generate energy and is thus directly related to emissions to the air, water, and land and is a direct secondary impact on public health from HD. The ratio of outside‐the‐hospital energy to direct hospital HD electrical energy consumption is 4:1 to 7:1, so a broader base exists for improvement than just the hospital.  相似文献   

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Social impacts of novel technology can, parallel to environmental and economic consequences, influence its sustainability. By analyzing the case of hydrogen production by advanced alkaline water electrolysis (AEL) from a life cycle perspective, this paper illustrates the social implications of the manufacturing of the electrolyzer and hydrogen production when installed in Germany, Austria, and Spain. This paper complements previous environmental and economic assessments, which selected this set of countries based on their different structures in electricity production. The paper uses a mixed method design to analyze the social impact for the workers along the process chain. Appropriate indicators related to working conditions are selected on the basis of the UN Agenda 2030 Sustainable Development Goals. The focus on workers is chosen as a first example to test the relatively new Product Social Impact Life Cycle Assessment (PSILCA) database version 2.0. The results of the quantitative assessment are then complemented and compared through an investigation of the underlying raw data and a qualitative literature analysis. Overall, advanced AEL is found to have least social impact along the German process chain, followed by the Spanish and the Austrian. All three process chains show impacts on global upstream processes. In order to reduce social impact and ultimately contribute to Sustainable Development, policymakers and industry need to work together to further improve certain aspects of working conditions in different locations, particularly within global upstream processes.  相似文献   

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The relationship between environmental life cycle costing (ELCC) and sustainability was explored using two detailed wastewater case studies. The case studies were selected to increase the tension between existing market values and values for sustainability; the first case study considered incremental change to an existing plant and the second considered a paradigm shift in wastewater treatment. Pollution control provided the greatest cost savings for the first case study and provided a “win‐win” result—meeting existing standards and saving money. However, benefits for pollution control beyond current standards were not captured, which emphasized the role of standards to internalize as well as limit the values considered in ELCC. In the second case study, the value of water had the potential to change the focus of wastewater design from pollution abatement to resource recovery. However, social acceptance of recovered water and market access for resources created large risk for investment. The ELCC was also sensitive to the discount rate which limited longer‐term considerations. Other sustainability values such as scarcity and ecological thresholds were not captured. The ELCC code of practice suggests including such costs if likely in the foreseeable future; defining these values may also clarify the role of ELCC to evaluate sustainability over the life cycle.  相似文献   

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