共查询到20条相似文献,搜索用时 15 毫秒
1.
Filippo Imperato 《Phytochemistry》1985,24(9):2136-2137
From aerial parts of the fern Asplenium bulbiferum, besides kaempferol 3,7-diglucoside and kaempferol 3-O-rhamnoside- 7-O-glucoside, the new glycoside kaempferol 3-O-β-glucoside-7-O-β-galactoside has been characterized. 相似文献
2.
Jeffrey B. Harborne Christine A. Williams Jenny Greenham Patrick Moyna 《Phytochemistry》1974,13(8):1557-1559
Identification of the phenolic constituents in flowers of nine palm species has revealed that charged C-glycosylflavones and caffeylshikimic acid are characteristically present. Flavonol glycosides are also common; the 3-glucosides, 3-rutinosides and 3,4′-diglucosides of quercetin and isorhamnetin and the 7-glucoside and 3,7-diglucoside of quercetin are all variously present. Tricin 7-glucoside, luteolin 7-rutinoside and several unchanged C-glycosylflavones were also detected. Male flowers of Phoenix canariensis differ from female flowers in having flavonol glycosides. As expected, in most species studied, flavonoid patterns in the flowers vary considerably from those found in the leaves. 相似文献
3.
Two new flavanone glycosides, liquiritigenin 4′-apiosyl(1 → 2)-glucoside and liquiritigenin 7,4′-diglucoside together with a known flavone, apigenin 6,8-di-C-glucoside, have been isolated from licorice. 相似文献
4.
《Phytochemistry》1987,26(9):2557-2558
The 7-, 3′- and 4′-glucosides of luteolin, the 7-glucoside and 6,8-di-C-glucoside of apigenin were isolated from Trichosanthes kirilowii var. japonica. Kaempferol 3,7-di-rhamnoside and 3-glucoside-7-rhamnoside were identified from T. cucumeroides, kaempferol 3-galactoside and 3-sophoroside were also identified from T. anguina. Quercetin-3-rutinoside was detected from T. multiloba and T. rostrata. T. bracteata afforded luteolin 3′-glucoside and kaempferol 3-rutinoside, and T. kirilowii afforded luteolin 7-, 3′- and 4′-glucosides and apigenin 7-glucoside. 相似文献
5.
Kenneth R. Markham 《Phytochemistry》1977,16(5):617-619
Flavonoid glycosides have been isolated from a species of the (primitive) order of liverworts, Calobryales, for the first time. The endemic New Zealand species, Haplomitrium gibbsiae, was found to contain acylated derivatives of apigenin-7-glucoside, apigenin 7,4′-diglucoside and isoscutellarein-7-glucoside, all of which are unique to the Bryophytes. The possible taxonomic and phylogenetic relevance of these findings is discussed. 相似文献
6.
Nariyuki Ishikura Shunzô Hayashida 《Bioscience, biotechnology, and biochemistry》2013,77(9):1923-1926
Blue seed-coats of Ophiopogon jaburan have been found to contain kaempferol, kaempferol 3-glucoside (astragalin), two new glucosides of kaempferol, and a trace amount of an unknown flavonol-like compound. One of the new glucosides was determined to be kaempferol 4′-glucoside and the other to be kaempferol 3, 4′-diglucoside by means of paper-chro-matographic and spectral analyses. 相似文献
7.
Christine A. Williams 《Phytochemistry》1979,18(5):803-813
In a leaf survey of 142 species from 75 genera of the Orchidaceae, flavone C-glycosides (in 53%) and flavonols (in 37 %) were found to be the most common constituents. However, since these compounds are not found uniformly and their distribution shows a strong correlation with plant geography, it is not possible to represent the Orchidaceae by a single flavonoid profile. Thus, flavone C-glycosides are most common in tropical and subtropical species of the Epidendroid and Vandoid tribes (in 63%) and flavonol glycosides are more characteristic of temperate species of the Neottioid tribes (in 78%). By contrast 6-hydroxyflavones (in 6 species), luteolin (in 2 species) and tricin as the 5-glucoside (in 1 species) are all rare. Three new glycosides were characterised: scutellarein 6-methyl ether 7-rutinoside from Oncidium excavatum and O. sphacelatum, pectolinarigenin 7-glucoside from 0. excavatutn and Eria javanica, and luteolin 3′,4′-diglucoside from Listera ovata. The xanthones, mangiferin and isomangiferin were found in Mormolyca ringens, Maxillaria aff. luteo-alba and 5 Polystachya species and a mangiferin sulphate tentatively identified in P. nyanzensis. Other unusual phenolic constituents include 6,7-methylenedioxy- and 6,7-dimethoxycoumarins from Dendrobium densiflorum and D. farmeri, formed by the rearrangement during the extraction process from the corresponding O-glucosyloxycinnamic acids. The origin and relationship of the Orchidaceae to other monocot groups are discussed in the light of the flavonoid evidence. 相似文献
8.
The flavonoids of an additional eight species of Clibadium have been determined. The compounds are derivatives of kaempferol, quercetin and quercetagetin. O-Methylated quercetagetin derivatives were found in several taxa with the possibility that 6-methoxykaempferol may also exist in one collection. Kaempferol and quercetin exist as 3-O-glucosides, galactosides, rhamnosides, rutinosides and diglucosides although not all glycosides occur in each taxon. Quercetagetin derivatives occur as 7-O-glucosides. Observations on these newly investigated species confirm previous work in the genus that three types of flavonoid profiles exist: (1) kaempferol and quercetin 3-glycosides; (2) kaempferol and quercetin 3-glycosides plus quercetagetin 7-glucoside; and (3) kaempferol and quercetin 3-glycosides plus quercetagetin 7-glucoside and O-methylated derivatives of quercetagetin. 相似文献
9.
Eight flavonol glycosides were detected in the three species of theFagonia sinaica complex. They were fully characterized as the 3-glucosides of kaempferol, quercetin and isorhamnetin, 3-rutinoside of quercetin and 3,7-diglucoside of quercetin and isorhamnetin. Two additional glycosides were partially characterized as a kaempferol 3,7-diglycoside and quercetin 3-diglycoside. 相似文献
10.
The present paper deals mainly with the chemical contents of the family Equisetaceae in China. The taxonomic value of the flavonol in this family is discussed.
The results of chemical investigation show that kaempferol-3,7-diglucoside and kaempferol are the characteristic components of the family; kaempferol-3-diglucoside is characteristic of
the genus Hippochaete and quercetin is characteristic of the genus Equisetum.
Described in this paper are isolation of 11 compounds and identification of 7 compounds
in this experiment, among which kaempferol-3-diglucoside and succinic acid are isolated from
Hippochaete hiemale for the first time. 相似文献
11.
From the aerial parts of Helichrysum chasmolycicum P.H Davis, which is an endemic species in Turkey, the flavonoids apigenin, luteolin, kaempferol, 3,5-dihydroxy-6,7,8-trimethoxyflavone, 3,5-dihydroxy-6,7,8,4′-tetramethoxyflavone, apigenin 7-O-glucoside, apigenin 4′-O-glucoside, luteolin 4′-O-glucoside, luteolin 4′,7-O-diglucoside, kaempferol 3-O-glucoside, kaempferol 7-O-glucoside and quercetin 3-O-glucoside were isolated. The methanol extract of the aerial parts of H. chasmolycicum showed antioxidant activity by DPPH method (IC50 0.92 mg/mL). Antimicrobial activity test was performed on the B, D, E extracts and also 3,5-dihydroxy-6,7,8-trimethoxyflavone and kaempferol 3-O-glucoside which were the major flavonoid compounds obtained from aerial parts of H. chasmolycicum by microbroth dilutions technique. The E (ethanol-ethyl acetate) extract showed moderate antimicrobial activity against Pseudomonas aeruginosa, B (petroleum ether-60% ethanol-chloroform) extract and 3,5-dihydroxy-6,7,8-trimethoxyflavone showed moderate antifungal activity against Candida albicans. 相似文献
12.
Nabiel A.M. Saleh Loutfy Boulos Sabry I. El-Negoumy Mohamed F. Abdalla 《Biochemical Systematics and Ecology》1982,10(1):33-36
The flavonoid glycosides of Medicago radiata as well as M. arabica, M. polymorpha, M. sativa, Trigonella coerulescens, T. foenum-graecum and T. spicata were studied in detail. Major glycosides identified were the 7-glucuronides of apigenin, luteolin, chrysoeriol and tricin, as well as lesser amounts of di- and triglucuronides of chrysoeriol and tricin. Also identified were the 3-robinobioside and 3,7-diglucoside of kaempferol, along with lesser amounts of quercetin-3,7-diglucoside, 4′,7-dihydroxyflavone, 3′,4′,7-trihydroxyflavone, formononetin and daidzein. Twelve other Medicago and Trigonella species were also studied for their flavonoid aglycones. The systematic position of M. radiata is discussed. 相似文献
13.
《Phytochemistry》1986,25(10):2423-2424
The flavonoids of Fagonia taeckholmiana and four varieties of F. arabica were investigated. Six flavonoids were identified: isorhamnetin 3-glucoside and 3-rutinoside, herbacetin 8-rutinoside, herbacetin 8-methyl ether-3-rutinoside, 3,7-diglucoside and 3-rutinoside-7-glucoside. 相似文献
14.
A novel trisubstituted kaempferol glycoside has been isolated from leaves and flowers of Coronilla emerus and identified as the 3-glucoside-7,4′-dirhamnoside. It co-occurs in the flowers with the 3-glucosides and 3-glucoside-7-rhamnosides of kaempferol and quercetin. A second kaempferol triglycoside based on glucose and xylose is also present. All six glycosides contribute to the UV patterning present in the wings of the flowers. This is the first report of kaempferol triglycosides with monosaccharide units substituting hydroxyl groups at the 3-, 7- and 4′-positions. 相似文献
15.
A. Ulubelen S. Öksüz B. Halfon Y. Aynehchi T.J. Mabry S.A. Matlin 《Phytochemistry》1984,23(12):2941-2943
Haplophyllum pedicellatum, H. robustum and H. glabrinum all yielded the known compound gossypetin 8,3′-dimethyl ether 3-rutinoside. In addition the first two species afforded isorhamnetin and its 3-rutinoside. A new glycoside, gossypetin 8,3′-dimethyl ether 3-glucoside was obtained from H. pedicellatum together with the 3-malonylrutinoside, 3-malonylglucoside and 3-galactoside of isorhamnetin plus kaempferol 3-malonylglucoside. H. robustum yielded isorhamnetin 7-glucoside and 3-glucoside and quercetin 3-galactoside, while H. glabrinum was found to contain gossypetin 8-methyl ether 3-malonylrutinoside in addition to kaempferol and isorhamnetin 3-glucoside. 相似文献
16.
Six new and nine known flavonoids were obtained from Neurolaena oaxacana. The known flavonoids are 6-hydroxykaempferol 3,7-dimethyl ether, quercetagetin 3,7-dimethyl ether, quercetin 3-methyl ether, axillarin, nodifloretin, 6-hydroxyluteolin 7-glucoside, kaempferol 3-glucoside, quercetagetin 7-glucoside and patulitrin. The new compounds are 6-hydroxykaempferol 3-methyl ether, quercetagetin 3,7-dimethyl ether 6-galactoside, quercetagetin 3-methyl ether 7-glucoside, the 6- and 7-glucosides of 6-hydroxykaempferol 3-methyl ether and quercetagetin 3-methyl ether 7-sulfate. 相似文献
17.
Angela Wilson 《Phytochemistry》1985,24(8):1685-1691
Flavonoid pigments (18) were identified in the wings and body of Melanargia galathea: tricin, tricin 7-glucoside, tricin 7-diglucoside, tricin 4′-glucoside, luteolin, luteolin 7-glucoside, luteolin 7-diglucoside, luteolin 7-triglucoside, apigenin, apigenin 7-glucoside, orientin, orientin 7-glucoside, iso-orientin, iso-orientin 7-glucoside, vitexin 7-glucoside, vitexin 7-glucoside, isovitexin, isovitexin 7-glucoside and a novel but incompletely identified tricin 4′-conjugate. Examination of the wings and bodies of individual M. galathea, M. galathea var. procida, M. lachesis, M. russiae, M. larissa, M. occitanica and M. ines butterflies from a number of different populations in Europe by 2D PC revealed that variation in their flavonoid patterns was so minor that the flavonoid pattern of these Melanargia spp. may be considered constant. The concentration of flavonoids in the wings of each butterfly was greater than that in the body, as is the covering of scales. Not all flavonoids are located in the scales; some are also located in the reproductive tissues of the female. With the exception of the tricin 4′-conjugate which was absent from the egg and first instar larvae before feeding commences, these flavonoids were present in all the life stages of M. galathea. The presence of tricin 4′-conjugate in Melanargia but its absence from the larval food plants suggests that this compound is synthesized by the insect and that flavonoids are not merely sequestered from the diet but are also partly metabolized. 相似文献
18.
《Biochemical Systematics and Ecology》2005,33(6):571-584
Seventy-five taxa belonging to the genus Asarum sensu lato were studied for their composition of flavonoids. Three chalcones and an aurone were found as major components. The chalcones were identified as chalcononaringenin 2′,4′-di-O-glucoside, 4,2′,4′-tri-O-glucoside, 4-O-glucoside, and the aurone as aureisidin 4,6-di-O-glucoside. The glycoside, 2′,4′-di-O-glucoside was detected in all taxa examined, and is a chemotaxonomical feature of Asarum sensu lato. 4,2′,4′-Tri-O-glucoside was found from the taxa classified into the genera Asiasarum, Geotaenium and Heterotropa by Maekawa's system. On the other hand, the glycoside was not detected from three Asarum sensu stricto species, A. caudigerum, A. caulescens and A. leptophyllum. In contrast, aurone, aureusidin 4,6-di-O-glucoside occurred in two Asarum s.s., A. caulescens and A. leptophyllum. Thus, the Asarum s.s. and other Maekawa's genera, Asiasarum, Geotaenium and Heterotropa could distinguish by the presence or absence of some anthochlor pigments. Other flavonoids were isolated from the selected 18 Asarum species. They were characterized as some flavonol 3- or 3,7-O-glycosides based on kaempferol, quercetin and isorhamnetin, flavone, apigenin 6,8-di-C-glycoside, flavanone, naringenin 5,7-di-O-glucoside, and xanthone, mangiferin. 相似文献
19.
A new lignan characterised as (-)-4-hydroxy-2,6-di-(4′-hydroxy-3′-methoxy)phenyl-3,7-dioxabicyclo-(3.3.0)octane along with n-10-nonacosanol, scopoletin, syringic acid, β-sitosterol and its glucoside, has been isolated from the aerial parts of Lonicera hypoleuca. The stereochemistry of the lignan has been established by its spectroscopic analysis and those of its derivatives, and by its conversion to (+)-pinoresinol. β-Sitosterol-β-D-glucoside displayed good spasmolytic activity. 相似文献
20.
A survey of 125 species of the Palmae revealed a complex pattern of flavonoids in the leaf. C-Glycosylflavones, leucoanthocyanins and tricin, luteolin and quercetin glycosides were common, being present in 84, 66, 51, 30 and 24% of the species respectively. Apigenin and kaempferol were recorded in only a few species and isorhamnetin only once. Eighteen flavonoids were identified: the 7-glucoside, 7-diglucoside and 7-rutinoside of both luteolin and tricin, tricin 5-glucoside, apigenin 7-rutinoside, quercetin 3-rutinoside-7-galactoside, isorhamnetin 7-rutinoside, orientin, iso-orientin, vitexin, isovitexin and vitexin 7-O-glucoside. Many of the C- and O-flavonoid glycosides were present as the potassium bisulphate salts and negatively charged compounds were detected in 50% of the species. The distribution patterns are correlated with the taxonomy of the family in several ways. Thus, the Phoenicoideae and Caryotoideae have distinctive flavonoid patterns, there is evidence to support the separation of the subfamilies Phytelephantoideae and Nypoideae, and tricin is a useful marker at tribal level. At the generic level, Cocos is clearly separated from Butia, and other Cocoseae and Mascarena and Chamaedorea form well defined groups within the Arecoideae. A numerical analysis of these biochemical data, together with morphological characters, produces a new classification which suggests that the flavonoid data may have more systematic value than is indicated when they are applied to the traditional classification. 相似文献