Dynamics of the ion energy spectrum in EUV-induced hydrogen plasma

The dynamics of the ion energy spectrum in low-pressure (10–100 Pa) hydrogen plasma induced by extreme ultraviolet (EUV) pulses in the wavelength range of 10–20 nm was studied experimentally. The plasma was generated under cathode irradiation due to both direct gas ionization by EUV photons and impact ionization by high-energy secondary electrons. The dynamics of the spectra of ions incident on the cathode was measured using a time-resolved retarding field energy analyzer. It is shown that the ion spectrum dynamics is completely determined by the time evolution of the cathode sheath. At low gas pressures (<20 Pa), the ion spectrum at early moments after the EUV pulse has a peaked shape, typical of a collisionless plasma sheath, and is mainly determined by the cathode voltage. As the pressure increases, the peak broadens and low energy ions appear in the spectrum due to ion collisions in the cathode sheath. An increase in the role of collisions with decreasing plasma density is also observed in the time evolution of ion spectra.     

Some aspects of ion sheath dynamics under the action of pulsed voltage

The time evolution of an unsteady cathode ion sheath in plasma has been studied numerically. The calculations demonstrate the presence of spikes in the ion current density and electric field strength at the cathode. The amplitudes of these spikes significantly exceeds the steady-state level, which agrees with data from other studies. Approximate formulas are derived that describe the spike amplitudes as functions of the rise time and amplitude of the applied voltage pulse, the mass and charge of ions, and the density and temperature of plasma electrons.     

Enantiomeric separation of baclofen by capillary electrophoresis tandem mass spectrometry with sulfobutylether-beta-cyclodextrin as chiral selector in partial filling mode

Capillary electrophoresis (CE) coupled to tandem mass spectrometry was applied to the chiral separation of baclofen using sulfobutylether-beta-cyclodextrin chiral selector in partial filling counter current mode. On-line UV detection was simultaneously used. Method optimization was performed by studying the effect of cyclodextrin and BGE concentration as well as sheath liquid composition on analyte migration time and enantiomeric resolution. The cyclodextrin showed stereoselective complexation towards baclofen enantiomers, allowing chiral resolution at low concentration. The CE capillary protrusion from the ESI needle relevantly affected the chiral resolution and the analyte migration time. Complete enantiomeric separation was obtained by using 0.25 M formic acid BGE containing 1.75 mM of chiral selector and water/methanol (30:70, v/v) 3% formic acid as sheath liquid. The method exhibited a LOD of 0.1 microg/mL (racemic concentration) in MS3 product ion scan mode of detection and was applied to the analysis of racemic baclofen in pharmaceutical formulations.     

Self-sustained low pressure glow discharge with a hollow cathode at currents of tens of amperes

Self-sustained glow discharge with a hollow cathode was studied at high discharge currents (up to 30 A). Using a grid analyzer placed on the side flange of the hollow cathode, the ion and electron currents flowing in the cathode sheath were measured. At a discharge current of 30 A, pressure of 0.2?C2 Pa, and plasma density of 10¹¹ cm^?3, the coefficient of secondary ion-electron emission ?? calculated from the experimental data is found to be 0.1?C0.15. The dependences of the plasma parameters on the area of the small anode placed inside the larger hollow cathode are determined.     

Pulsed mode of a negative corona in nitrogen: II. Numerical calculations

A simplified model of a cathode sheath sustained by electron avalanches is presented. The model is used to calculate the pulsed mode of a negative corona in nitrogen in order to establish the physical picture of the processes occurring in a pulsed corona. The most important point is that, in the pulsed mode, both the averaged and dynamic current-voltage characteristics of a glow cathode sheath are found to have a negative slope. Lowering the degree to which the glow cathode sheath is subnormal (by sharply reducing the sheath area) or switching on additional ionization mechanisms (e.g., stepwise ionization) that force the cathode sheath to evolve into a prearc spot causes the negative slopes of the averaged and dynamic current-voltage characteristics of the sheath to become more gradual and even positive, thereby stabilizing the discharge current.     

Numerical simulations of Trichel pulses in a negative corona in air

Numerical simulations of a negative corona in air demonstrate that the experimentally observed regime of self-oscillations, known as Trichel pulses, is well described by a three-dimensional axisymmetric model that is based on the standard transport equations and in which only the ion-induced secondary electron emission at the cathode is taken into account. The quantitative difference between the measured and calculated values of the mean current and the pulse repetition rate most likely stems from the insufficiently large dimensions of the computation region and from the fact that the point shape adopted in simulations somewhat inexactly conforms to that used in experiments. It was found that the transverse discharge structure near the cathode radically changes during the pulse. Specifically, as the current grows, a cathode sheath forms at the discharge axis and expands over the cathode surface. When the current falls off, the cathode sheath is rapidly destroyed; as a result, the characteristic field structure is well defined only near the discharge axis and becomes virtually indistinguishable as the current decreases by an order of magnitude.     

Longitudinal ion source with the current self-compensation of the focused ion beam

Utilization of ballistic focusing in the longitudinal Hall-type ion source is described. It allows transformation of the ion beam shape from an “ellipsoidal” one to a linear one, as well as increasing the ion beam current density per the operating surface. Both the influence of transverse magnetic field and edge effects on the beam shape are investigated. The ion beam is charge compensated by a plasma neutralizer designed on the basis of a supplementary semi-self-maintained magnetron-type discharge and hollow cathode effect.     

High-voltage stage of a vacuum arc

An elementary theory of the cathode region at the high-voltage stage of an arc discharge is proposed. The theory is based on the balance equations for the particles in an active plasma layer, the power balance at the cathode, and the equation for the Richardson-Dushman electron emission with allowance for the Schottky effect. The most characteristic features of this type of discharge are considered. A non-Langmuir cathode sheath model is proposed for a low-voltage arc on a tungsten electrode.     

Low-current moderate-pressure RF discharge with secondary electron photoemission

A model is proposed for a low-current RF discharge with secondary electron photoemission from the electrode surface caused by photons originating in the electrode sheath. The low-current state of RF discharges at moderate pressures is peculiar in that the electrons and ions produced during the preceding periods of the RF field promote the development of the discharge during subsequent periods. Since the ion space charge is induced during many periods of the RF field, even comparatively moderate fields in the electrode sheath are sufficient to ensure the conditions under which the current is self-sustaining, in which case the electron photoemission dominates over the remaining secondary processes at the electrode surface. In a low-current RF discharge, the ion-electron emission has essentially no impact on the formation of the electrode sheath because the half-period of the RF field is much shorter than the ion transit time through the sheath. The sheath results from the overlap of the secondary electron avalanches triggered by electron photoemission from the electrode surface. The sheath parameters are determined by the conditions under which the current in the sheath is selfsustaining due to the secondary electron photoemission from the electrode surface. The capacitive susceptance of the electrode sheath is substantially higher than its electrical conductance. Low-current RF discharges can only exist when the time required for the ions to drift through the sheath and reach the electrode is much longer than the half-period of the RF field.     

Drift model of the cathode region of a glow discharge

A one-dimensional drift model of the cathode region of a glow discharge with allowance for both electron-impact ionization and charged particle loss is proposed. An exact solution to the model equations is obtained for the case of similar power-law dependences of the ion and electron drift velocities on the electric field strength. It is shown that, even in the drift approximation, a relatively wide transition layer in which the ion-to-electron current ratio approaches a constant value typical of the positive column of a glow discharge should occur between the thin space-charge sheath and the quasineutral plasma, the voltage drop across the space-charge sheath being comparable to that across the transition layer. The calculated parameters of the normal and anomalous glow discharges are in good agreement with available experimental data.     

Simulations of a surface glow discharge in a supersonic gas flow in the presence of external ionization

Results of two-dimensional hydrodynamic simulations of a surface glow discharge operating at pressures of 0.2–0.5 Torr in a nitrogen flow propagating with a velocity of 1000 m/s in the presence of external ionization are presented. The effect of the external ionization rate on discharge operation is analyzed. The current-voltage characteristics of the discharge are calculated for different intensities of external ionization in both the presence and absence of secondary electron emission from the cathode. The discharge structure and plasma parameters in the vicinity of the loaded electrode are considered. It is shown that, when the discharge operates at the expense of secondary emission from the cathode, the discharge current and cathode sheath configuration are insensitive to external ionization. It is also demonstrated that, even at a high rate of external ionization, the discharge operates due to secondary emission from the cathode.     

On the upper bound in the Bohm sheath criterion

The question is discussed about the existence of an upper bound in the Bohm sheath criterion, according to which the Debye sheath at the interface between plasma and a negatively charged electrode is stable only if the ion flow velocity in plasma exceeds the ion sound velocity. It is stated that, with an exception of some artificial ionization models, the Bohm sheath criterion is satisfied as an equality at the lower bound and the ion flow velocity is equal to the speed of sound. In the one-dimensional theory, a supersonic flow appears in an unrealistic model of a localized ion source the size of which is less than the Debye length; however, supersonic flows seem to be possible in the two- and three-dimensional cases. In the available numerical codes used to simulate charged particle sources with a plasma emitter, the presence of the upper bound in the Bohm sheath criterion is not supposed; however, the correspondence with experimental data is usually achieved if the ion flow velocity in plasma is close to the ion sound velocity.     

Means for efficient electron beam generation in wide-aperture open-discharge light sources

The interaction of a plasma in the accelerating gap of an open discharge with a strong external electric field and with the cathode surface has been investigated theoretically and experimentally. In a pulsed nanosecond discharge, the ion inertia and plasma screening of the electric field cause a fast growth of the electric field E in the cathode region and a decrease in the length of the latter. Along with a reduction of the electron multiplication factor at high electric fields, this leads to a substantial decrease in the ion flux toward the cathode, which allows one to develop highly efficient open-discharge light sources with a long lifetime and low cathode sputtering. In this respect, continuous and quasi-continuous discharges are less advantageous because of the smaller increase in the electric field in the cathode region. The Townsend coefficients of charge multiplication and electron emission at high electric fields typical of open discharges have been measured for the first time. Fast ions and atoms extracted from the plasma of the accelerating gap significantly affect the cathode emission properties. In particular, photoemission is enhanced by more than one order of magnitude and becomes the main mechanism for electron generation. This also increases the efficiency and lifetime of open-discharge light sources.     

Aqueous Electrochemical Energy Storage with a Mediator‐Ion Solid Electrolyte

This study presents a battery concept with a “mediator‐ion” solid electrolyte for the development of next‐generation electrochemical energy storage technologies. The active anode and cathode materials in a single cell can be in the solid, liquid, or gaseous form, which are separated by a sodium‐ion solid‐electrolyte separator. The uniqueness of this mediator‐ion strategy is that the redox reactions at the anode and the cathode are sustained by a shuttling of a mediator sodium ion between the anolyte and the catholyte through the solid‐state electrolyte. Use of the solid‐electrolyte separator circumvents the chemical‐crossover problem between the anode and the cathode, overcomes the dendrite‐problem when employing metal‐anodes, and offers the possibility of using different liquid electrolytes at the anode and the cathode in a single cell. The battery concept is demonstrated with two low‐cost metal anodes (zinc and iron), two liquid cathodes (bromine and potassium ferricyanide), and one gaseous cathode (air/O₂) with a sodium‐ion solid electrolyte. This novel battery strategy with a mediator‐ion solid electrolyte is applicable to a wide range of electrochemical energy storage systems with a variety of cathodes, anodes, and mediator‐ion solid electrolytes.     

A phenomenological model of the current filamentation instability driven by cathode processes in the Livermore spheromak

The current density on the open field lines of the Livermore spheromak (SSPX) typically exceeds the saturation current density of the bulk plasma. We assume that the mechanism that provides conditions for that is associated with the formation of a thin layer near the cathode surface, where both the plasma and the neutral density are higher than in the bulk plasma and where intense ionization occurs. The ions formed in this layer fall back onto the cathode, whereas electrons contribute to the high current density in the bulk plasma. The particle balance in the ionizing layer is determined by the recycling coefficient, which, in turn, depends on the cathode temperature and the sheath voltage. As it turns out, these dependences give rise to an instability that leads to the current filamentation and the formation of hot spots on the cathode surface. The instability can be characterized in a phenomenological manner without going into the details of the structure of the ionizing layer, whose effect on the instability shows up in the form of a couple of numerical coefficients of the order of one. We predict the characteristic size and the shape of the filaments (and the hot spots), which are in a general agreement with discoloration patterns on the surface of the cathode in the SSPX. If the magnetic field is tilted to the surface, the footpoints of the filaments move with a significant velocity, whose direction depends on the ratio of the ion gyroradius and the thickness of the ionizing layer. This instability, although primarily considered in conjunction with the SSPX experiment, may play a role in spherical tokamaks and other systems with coaxial helicity injection.     

Investigation of the chaotic dynamics of an electron beam with a virtual cathode in an external magnetic field

The effect of the strength of the focusing magnetic field on chaotic dynamic processes occurring in an electron beam with a virtual cathode, as well as on the processes whereby the structures form in the beam and interact with each other, is studied by means of two-dimensional numerical simulations based on solving a self-consistent set of Vlasov-Maxwell equations. It is shown that, as the focusing magnetic field is decreased, the dynamics of an electron beam with a virtual cathode becomes more complicated due to the formation and interaction of spatiotemporal longitudinal and transverse structures in the interaction region of a vircator. The optimum efficiency of the interaction of an electron beam with the electromagnetic field of the vircator is achieved at a comparatively weak external magnetic field and is determined by the fundamentally two-dimensional nature of the motion of the beam electrons near the virtual cathode.     

Effect of Separation Conditions on Automated Isoelectric Focusing of Carbohydrate-Deficient Transferrin and Other Human Isotransferrins Using the PhastSystem

To investigate the effect of automated isoelectric focusing conditions in the PhastSystem, e.g., the point of sample application, prerun and separation times, and minimized gels on isotransferrin band pattern, human sera were analyzed with native transferrin iron load, after iron saturation or iron depletion in vitro. Varying the focusing conditions we found (i) Point of sample application (anode, middle of the gel, cathode) strongly affected transferrin iron loss. It was greatest at the anode and least at the cathode. (ii) Without prerun, distinct transferrin iron loss also occurred. A short prerun time prevented iron loss, but increasing it did not improve transferrin iron load stability as stated by others. (iii) An inappropriately long separation time inevitably yielded iron loss. In conclusion, inappropriate isoelectric focusing conditions strongly affect iron load stability of isotransferrins (obviously via low pH within the gel), resulting in transferrin iron release and cofocusing of isotransferrins with different sialic acid or iron contents. For determination of carbohydrate-deficient transferrin, such conditions resulted in overestimation of the marker of chronic alcohol abuse. Our findings may be of guiding importance for isoelectric focusing of protein-ligand complexes. We recommend the procedure described for development of isoelectric focusing of protein-ligand complexes.     

Formation of electrode sheaths during the acceleration of a magnetized plasma

A study is made of the motion of a plasma with a frozen-in magnetic field along the electrode surfaces in the direction transverse to the magnetic field. A one-dimensional problem of an electrode sheath is formulated in which all of the quantities depend only on the coordinate orthogonal to the electrode surface. Viscous plasma heating, plasma cooling via heat conduction, and other kinetic effects are taken into consideration. Account is also taken of the effect of plasma acceleration and of the related current that is transverse to the electrode surfaces and, due to the Hall effect, carries the magnetic flux away from the cathode and toward the anode. Solving the one-dimensional problem with a constant electric current and constant magnetic field shows that, in a sheath that forms near the cathode, the solution becomes self-similar, the plasma mass grows linearly, and the electron magnetization parameter remains unchanged. It is found that the anode sheath cannot be described in the magnetohydrodynamic approximation, according to which the plasma density in the sheath rapidly vanishes, while the current through the sheath remains constant. This difficulty can be overcome by incorporating some of the nonhydrodynamic effects (primarily, electron dispersion), thereby making the problem physically correct. Solving the problem numerically shows that a decrease in the plasma density in the anode sheath due to the Hall effect gives rise to additional significant plasma acceleration.     

Plasma diagnostics from the dynamic current-voltage haracteristic of an electric probe

A method for measuring the plasma electron density from the dynamic current-voltage probe characteristic is considered. For this purpose, an additional rectangular negative voltage pulse or a high-frequency sinusoidal voltage is applied to a negatively biased probe. Analytic expressions are derived for two cases: when the space charge sheath obeys the 3/2 law and when the voltage varies over a time shorter than the ion transit time through the sheath so that the sheath does not obey the 3/2 law. Dynamic and statistic probe methods for determining the electron density are compared experimentally.     

Higher,Stronger, Better…︁ A Review of 5 Volt Cathode Materials for Advanced Lithium‐Ion Batteries

The ever‐increasing demand for high‐performing, economical, and safe power storage for portable electronics and electric vehicles stimulates R&D in the field of chemical power sources. In the past two decades, lithium‐ion technology has proven itself a most robust technology, which delivers high energy and power capabilities. At the same time, current technology requires that the energy and power capabilities of Li‐ion batteries be ‘beefed up’ beyond the existing state of the art. Increasing the battery voltage is one of the ways to improve battery energy density; in Li‐ion cells, the objective of current research is to develop a 5‐volt cell, and at the same time to maintain high specific charge capacity, excellent cycling, and safety. Since current anode materials possess working potentials fairly close to the potential of a lithium metal, the focus is on the development of cathode materials. This work reviews and analyzes the current state of the art, achievements, and challenges in the field of high‐voltage cathode materials for Li‐ion cells. Some suggestions regarding possible approaches for future development in the field are also presented.