Cost-effectiveness of bioethanol policies to reduce carbon dioxide emissions in Greece

Purpose

The aim of this study was to evaluate the cost-effectiveness of bioethanol as regards to its carbon dioxide emissions. The production of the raw material accounts for more than 50 % of the total cost as well as having a significant part of greenhouse gases emitted during the entire process. For this reason, special emphasis is given to a change in agricultural land usage influenced by the demand of biofuel. Therefore, we have estimated the extent of policy influence according to its bioethanol cost-effectiveness. A case study on bioethanol production in an ex-sugar factory in the region of Thessaly, Greece, illustrates the above ideas.

Methods

A partial equilibrium micro-economic model of regional supply in the arable farming system of Thessaly was coupled to industrial processing sub-models of bioethanol production from beets and grains. The maximisation of total welfare determines the most suitable crop mix for farmers as well as the lowest cost configurations for industry and, eventually, the minimal level of support by the government for biofuel activity to take off. The environmental performance is assessed under the life cycle assessment (LCA) framework following three interrelated phases: data inventory, data analysis and interpretation. The economic burden to society to support the activity divided by avoided CO₂ eq. emissions indicates the bioethanol cost-effectiveness, in other words, the cost of greenhouse gases emissions savings.

Results

The integrated agro-industry model has been parametrically run for a range of biofuel capacities. A change in direct land use results in lower emissions in the agricultural phase, since energy crops are a substitute for intensive cultivations, such as cotton and corn. A change in indirect land use moderates these estimations, as it takes in account imported food crops that are replaced by energy crops in the region. The savings in cost vary around 160 euros per ton of CO₂ eq. for the basic agricultural policy scenario. The current policy that supports cotton production by means of increased coupled area payment has increased up to 30 % the cost of greenhouse gas savings due to bioethanol production.

Conclusions

An integrated model, articulating the agricultural supply of biomass with ethanol processing, maximises the total surplus that is under constraints in order to determine the cost-effectiveness for different production levels. Results demonstrate that economic performances, as well as the environmental cost-effectiveness of bioethanol, are clearly affected by the parameters of agricultural policies. Therefore, bioenergy, environmental and economic performances, when based on LCA and the conceptual change in land usage, are context dependent. Agricultural policies for decoupling subsidies from production are in favour of cultivation in biomass for energy purposes.     

Life cycle assessment of commodity chemical production from forest residue via fast pyrolysis

Purpose

This life cycle assessment evaluates and quantifies the environmental impacts of renewable chemical production from forest residue via fast pyrolysis with hydrotreating/fluidized catalytic cracking (FCC) pathway.

Methods

The assessment input data are taken from Aspen Plus and greenhouse gases, regulated emissions, and energy use in transportation (GREET) model. The SimaPro 7.3 software is employed to evaluate the environmental impacts.

Results and discussion

The results indicate that the net fossil energy input is 34.8 MJ to produce 1 kg of chemicals, and the net global warming potential (GWP) is ?0.53 kg CO₂ eq. per kg chemicals produced under the proposed chemical production pathway. Sensitivity analysis indicates that bio-oil yields and chemical yields play the most important roles in the greenhouse gas footprints.

Conclusions

Fossil energy consumption and greenhouse gas (GHG) emissions can be reduced if commodity chemicals are produced via forest residue fast pyrolysis with hydrotreating/FCC pathway in place of conventional petroleum-based production pathways.     

Design of a sustainable packaging in the food sector by applying LCA

Purpose

The choice of a sustainable packaging alternative is a key issue for the improvement of the environmental performances of a product, both from a production perspective and end-of-life management. The present study is focused on the life cycle assessment (LCA) of two packaging alternatives of a poultry product, in particular a polystyrene-based tray and an aluminum bowl (70 wt% primary and 30 wt% secondary aluminum) were considered.

Methods

The LCA was performed according to ISO 14040-44 and following a “from-cradle-to-grave” perspective. The following stages were considered: production, use phase (i.e., cooking), and end-of-life. Different end-of-life scenarios were hypothesized. Greenhouse Gas Protocol, Cumulative Energy Demand, and ILCD midpoint method were used in the impact assessment (LCIA).

Results and discussion

The aluminum bowl was carefully designed in order to allow its use during the cooking stage of the poultry product in the oven and to reduce the cooking time (40 min instead of 50 min needed when using a conventional bowl) at 200 °C: cooking time reduction allows electric energy savings equal to 0.21 kWh (1.38 kWh instead of 1.59 kWh). Electric energy savings become of primary importance to reduce overall emissions, in particular CO₂ eq emissions, especially in those countries such as Italy and Germany where there is a predominance of fossil fuels in the electric energy country mix.

Conclusions

Over the entire life cycle of the two alternatives considered (taking into account production, transport, cooking, and end-of-life), cooking stage has the most impact; so, the specific design of the packaging bowl/tray can allow significant lowering of the overall CO₂ eq emissions. In addition, when designing an aluminum-based packaging, the content of the secondary material can be significantly increased in order to reach higher sustainability during the production stage.     

Life cycle assessment of bio-based ethanol produced from different agricultural feedstocks

Purpose

Bio-based products are often considered sustainable due to their renewable nature. However, the environmental performance of products needs to be assessed considering a life cycle perspective to get a complete picture of potential benefits and trade-offs. We present a life cycle assessment of the global commodity ethanol, produced from different feedstock and geographical origin. The aim is to understand the main drivers for environmental impacts in the production of bio-based ethanol as well as its relative performance compared to a fossil-based alternative.

Methods

Ethanol production is assessed from cradle to gate; furthermore, end-of-life emissions are also included in order to allow a full comparison of greenhouse gas (GHG) emissions, assuming degradation of ethanol once emitted to air from household and personal care products. The functional unit is 1 kg ethanol, produced from maize grain in USA, maize stover in USA, sugarcane in North-East of Brazil and Centre-South of Brazil, and sugar beet and wheat in France. As a reference, ethanol produced from fossil ethylene in Western Europe is used. Six impact categories from the ReCiPe assessment method are considered, along with seven novel impact categories on biodiversity and ecosystem services (BES).

Results and discussion

GHG emissions per kilogram bio-based ethanol range from 0.7 to 1.5 kg CO₂ eq per kg ethanol and from 1.3 to 2 kg per kg if emissions at end-of-life are included. Fossil-based ethanol involves GHG emissions of 1.3 kg CO₂ eq per kg from cradle-to-gate and 3.7 kg CO₂ eq per kg if end-of-life is included. Maize stover in USA and sugar beet in France have the lowest impact from a GHG perspective, although when other impact categories are considered trade-offs are encountered. BES impact indicators show a clear preference for fossil-based ethanol. The sensitivity analyses showed how certain methodological choices (allocation rules, land use change accounting, land use biomes), as well as some scenario choices (sugarcane harvest method, maize drying) affect the environmental performance of bio-based ethanol. Also, the uncertainty assessment showed that results for the bio-based alternatives often overlap, making it difficult to tell whether they are significantly different.

Conclusions

Bio-based ethanol appears as a preferable option from a GHG perspective, but when other impacts are considered, especially those related to land use, fossil-based ethanol is preferable. A key methodological aspect that remains to be harmonised is the quantification of land use change, which has an outstanding influence in the results, especially on GHG emissions.     

A life cycle carbon dioxide inventory of the Million Trees Los Angeles program

Purpose

This study seeks to answer the question, “Will the Million Trees LA (Million Trees Los Angeles, MTLA) program be a carbon dioxide (CO₂) sink or source?” Because there has never been a full accounting of CO₂ emissions, it is unclear if urban tree planting initiatives (TPIs) are likely to be effective means for reaching local reduction targets.

Methods

Using surveys, interviews, field sampling, and computer simulation of tree growth and survival over a 40-year time period, we developed the first process-based life cycle inventory of CO₂ for a large TPI. CO₂ emissions and reductions from storage and avoided emissions from energy savings were simulated for 91,786 trees planted from 2006 to 2010, of which only 30,813 (33.6 %) were estimated to survive.

Results and discussion

The MTLA program was estimated to release 17,048 and 66,360 t of fossil and biogenic CO₂ over the 40-year period, respectively. The total amount emitted (83,408 t) was slightly more than the ?77,942 t CO₂ that trees were projected to store in their biomass. The MTLA program will be a CO₂ sink if projected 40-year-avoided fossil fuel CO₂ emissions from energy savings (?101,679 t) and biopower (?1,939 t) are realized. The largest sources of CO₂ emissions were mulch decomposition (65.1 %), wood combustion (14.5 %), and irrigation water (9.7 %).

Conclusions

Although trees planted by the MTLA program are likely to be a net CO₂ sink, there is ample opportunity to reduce emissions. Examples of these opportunities include selecting drought-tolerant trees and utilizing wood residue to generate electricity rather than producing mulch.     

Assessing environmental consequences of using co-products in animal feed

Purpose

The livestock sector has a major impact on the environment. This environmental impact may be reduced by feeding agricultural co-products (e.g. beet tails) to livestock, as this transforms inedible products for humans into edible products, e.g. pork or beef. Nevertheless, co-products have different applications such as bioenergy production. Based on a framework we developed, we assessed environmental consequences of using co-products in diets of livestock, including the alternative application of that co-product.

Methods

We performed a consequential life cycle assessment, regarding greenhouse gas emissions (including emissions related to land use change) and land use, for two case studies. Case 1 includes increasing the use of wheat middlings in diets of dairy cattle at the expense of using it in diets of pigs. The decreased use of wheat middlings in diets of pigs was substituted with barley, the marginal product. Case 2 includes increasing the use of beet tails in diets of dairy cattle at the expense of using it to produce bioenergy. During the production of biogas, electricity, heat and digestate (that is used as organic fertilizer) were produced. The decrease of electricity and heat was substituted with fossil fuel, and digestate was substituted with artificial fertilizer.

Results and discussion

Using wheat middlings in diets of dairy cattle instead of using it in diets of pigs resulted in a reduction of 329 kg CO₂ eq per ton wheat middlings and a decrease of 169 m² land. Using beet tails in diets of dairy cattle instead of using it as a substrate for anaerobic digestion resulted in a decrease of 239 kg CO₂ eq per ton beet tails and a decrease of 154 m² land. Emissions regarding land use change contributed significantly in both cases but had a high uncertainty factor, ±170 ton CO₂ ha^?1. Excluding emissions from land use change resulted in a decrease of 9 kg CO₂ eq for case 1 ‘wheat middlings’ and an increase of 50 kg CO₂ eq for case 2 ‘beet tails’.

Conclusions

Assessing the use of co-products in the livestock sector is of importance because shifting its application can reduce the environmental impact of the livestock sector. A correct assessment of the environmental consequences of using co-products in animal feed should also include potential changes in impacts outside the livestock sector, such as the impact in the bioenergy sector.     

Quantifying the greenhouse benefits of the use of wood products in two popular house designs in Sydney, Australia

Purpose

As the average wood products usage per unit of floor area in Australia has decreased significantly over time, there is potential for increased greenhouse gas (GHG) mitigation benefits through an increased use of wood products in buildings. This study determined the GHG outcomes of the extraction, manufacture, transport, use in construction, maintenance and disposal of wood products and other building materials for two popular house designs in Sydney, Australia.

Methods

The life cycle assessment (LCA) was undertaken using the computer model SimaPro 7.1, with the functional unit being the supply of base building elements for domestic houses in Sydney and its subsequent use over a 50-year period. The key data libraries used were the Australian Life Cycle Inventory library, the ecoinvent library (with data adapted to Australian circumstances where appropriate) and data for timber production from an Australian study for a range of Australian forestry production systems and wood products. Two construction variations were assessed: the original intended construction, and a “timber-maximised” alternative. The indicator assessed was global warming, as the focus was on GHG emissions, and the effect of timber production, use and disposal on the fate of carbon.

Results and discussion

The timber maximised design resulted in approximately half the GHG emissions associated with the base designs. The sub-floor had the largest greenhouse impact due to the concrete components, followed by the walls due to the usage of bricks. The use of a “timber maximised” design offset between 23 and 25 % of the total operational energy of the houses. Inclusion of carbon storage in landfill made a very significant difference to GHG outcomes, equivalent to 40–60 % of total house GHG emissions. The most beneficial options for disposal from a GHG perspective were landfill and incineration with energy recovery.

Conclusions

The study showed that significant GHG emission savings were achieved by optimising the use of wood products for two common house designs in Sydney. The switch of the sub-floor and floor covering components to a “wood” option accounted for most of the GHG savings. Inclusion of end of life parameters significantly impacted on the outcomes of the study.     

Modelling the amount of materials to improve inventory datasets of greenhouse infrastructures

Purpose

Previous studies have shown the importance of including agricultural capital goods in environmental assessments. In particular for protected crops, greenhouse structural components may account for nearly 30 % of the total in environmental impact categories such as resource depletion and global warming. The lack of appropriate datasets can make it difficult to include these structural components. The present paper provides a modelling approach for the greenhouse inventory stage to provide better assessments of greenhouse production systems.

Methods

In this study, four main greenhouse structures were assessed: a glass greenhouse, a multi-tunnel greenhouse, a local Mediterranean type known as the parral greenhouse and a low-tunnel greenhouse. After selecting the main materials of the structure, we generated equations to calculate the amount of the main structural materials as a function of the main greenhouse dimensions. We performed a quality assessment of the data used for different greenhouse structures. We also calculated a simplified environmental assessment made by the different structures to the climate change category in order to test the effects of the different amounts of material in the four greenhouse types.

Results and discussion

Equations to calculate the amount of the main greenhouse materials as a function of greenhouse size are provided. For the four greenhouse types under consideration, statistical correlations showed a good fit between the amounts of greenhouse materials and the parameters related to the main greenhouse dimensions, such as greenhouse perimeter, surface and volume. The results from the complementary impact assessment study show that glass greenhouses contributed the most in the climate change category, with an average value of 2.9 kg CO₂ eq m^?2. After variability was taken into account, multi-tunnel and parral greenhouses showed similar values of between 0.5 and 1.3 kg CO₂ eq m^?2, while low-tunnel greenhouses had the lowest ranges, between 0.4 and 0.6 kg CO₂ eq m^?2. The environmental assessment was done using the square metre as a reference flow, so the actual impact depends on the functional unit selected, which is usually the yield.

Conclusions

Application of the equations developed in this study provides an easy way to calculate the quantity of materials used to make greenhouses of different dimensions, thus resulting in more accurate calculation of greenhouse production system impacts. This analysis also highlights the importance of the different amounts of materials used to build these structures and, therefore, the need to include ranges of uncertainty in environmental analyses.     

Responses of Senna reticulata,a legume tree from the Amazonian floodplains,to elevated atmospheric CO2 concentration and waterlogging

Key message

The Amazonian tree Senna reticulata showed an increase in photosynthesis and starch content under elevated [CO ₂ ] that led an increment in biomass after 90 days. Elevated [CO ₂ ] was also capable of reducing the negative effect of waterlogging.

Abstract

Tree species from the Amazonian floodplains have to cope with low oxygen availability due to annual pulses of inundation that can last up to 7 months. Species capable of adapting to flooding and/or waterlogged conditions usually partition their storage to favor starch and allocate it to roots, where carbohydrates are used to maintain respiration rates during waterlogging. In spite of climate change, virtually nothing is known about how elevated atmospheric CO₂ concentration ([CO₂]) will affect plants when combined with waterlogging. In this work, we used open top chambers to evaluate the effect of elevated [CO₂] during a period of terrestrial phase and in subsequent combination with waterlogged conditions to determine if the surplus carbon provided by elevated [CO₂] may improve the waterlogging tolerance of the fast-growing Amazonian legume tree Senna reticulata. During the terrestrial phase, photosynthesis was ca. 28 % higher after 30, 45 and 120 days of elevated [CO₂], and starch content in the leaves was, on average, 49 % higher than with ambient [CO₂]. Total biomass was inversely correlated to the starch content of leaves, indicating that starch might be the main carbohydrate source for biomass production during the terrestrial phase. This response was more pronounced under elevated [CO₂], resulting in 30 % more biomass in comparison to ambient [CO₂] plants. After 135 days at elevated [CO₂] an inversion has been observed in total biomass accumulation, in which ambient [CO₂] presented a greater increment in total biomass in comparison to elevated [CO₂], indicating negative effects on growth after long-term CO₂ exposure. However, plants with elevated [CO₂]/waterlogged displayed a greater increment in biomass in comparison with ambient [CO₂]/waterlogged that, unlike during the terrestrial phase, was unrelated to starch reserves. We conclude that S. reticulata displays mechanisms that make this species capable of responding positively to elevated [CO₂] during the first pulse of growth. This response capacity is also associated with a “buffering effect” that prevents the plants from decreasing their biomass under waterlogged conditions.     

Mitigation of greenhouse gas emissions from reed canary grass in paludiculture: effect of groundwater level

Background and aims

Combination of rewetting and wetland crop cultivation (paludiculture) is pursued as a wider carbon dioxide (CO₂) mitigation option in drained peatland. However, information on the overall greenhouse gas (GHG) balance for paludiculture is lacking. We investigated the GHG balance of peatlands grown with reed canary grass (RCG) and rewetted to various extents.

Methods

Gas fluxes of CO₂, methane (CH₄) and nitrous oxide (N₂O) were measured with a static chamber technique for 10 months from mesocosms sown with RCG and manipulated to ground water levels (GWL) of 0, ?10, ?20, ?30 and ?40 cm below the soil surface. Gross primary production (GPP) was estimated from the above ground biomass yield.

Results

The mean dry biomass yield across all water table treatments was 6 Mg ha^?1 with no significant differences between the treatments. Raising the GWL to the surface decreased both the net ecosystem exchange (NEE) of CO₂ and N₂O emissions whereas CH₄ emissions increased. Total cumulative GHG emissions (for 10 months) corresponded to 0.08, 0.13, 0.61, 0.68 and 0.98 kg CO₂ equivalents m^?2 from the GWL treatments at 0, ?10, ?20, ?30 and ?40 cm below the soil surface, respectively.

Conclusions

The results showed that a reduction in total GHG emission can be achieved without losing the productivity of newly established RCG when GWL is maintained close to the surface. Further studies should address the practical constrains and long-term productivity of RCG cultivation in rewetted peatlands.     

Absence of soil frost affects plant-soil interactions in temperate grasslands

Background and aims

Intermittently frozen ground in winter is expected to disappear over large areas in the temperate zone due to ongoing climate warming. The lack of soil frost influences plant soil interactions and needs to be studied in more detail.

Methods

Winter soil frost was avoided by belowground heating wires in a field experiment over two subsequent winters in a temperate grassland. Soil respiration, soil nitrogen availability and plant performance (aboveground biomass, root length at two depth levels, greenness, nutrient content) were compared between “no-frost” and reference plots which underwent repeated freeze-thaw cycles in both winters.

Results

Soil respiration increased in the “no-frost” treatment during the warming phase (+291 %). N-availability in the upper 10 cm of the soil profile was not affected, possibly due to increased plant N accumulation during winter (+163 %), increased plant N concentration (+18 %) and increased biomass production (+31.5 %) in the growing season. Translocation of roots into deeper soil layers without changes in total root length in response to the “no-frost” treatment, however, may be a sign of nutrient leaching.

Conclusions

The cumulative effect on carbon cycling due to warmer soils therefore depends on the balance between increased winter carbon loss due to higher soil biotic activity and enhanced plant productivity with higher nutrient accumulation in the growing season.     

Life cycle assessment of potential energy uses for short rotation willow biomass in Sweden

Purpose

Two different bioenergy systems using willow chips as raw material has been assessed in detail applying life cycle assessment (LCA) methodology to compare its environmental profile with conventional alternatives based on fossil fuels and demonstrate the potential of this biomass as a lignocellulosic energy source.

Methods

Short rotation forest willow plantations dedicated to biomass chips production for energy purposes and located in Southern Sweden were considered as the agricultural case study. The bioenergy systems under assessment were based on the production and use of willow-based ethanol in a flexi fuel vehicle blended with gasoline (85 % ethanol by volume) and the direct combustion of willow chips in an industrial furnace in order to produce heat for end users. The standard framework for LCA from the International Standards Organisation was followed in this study. The environmental profiles as well as the hot spots all through the life cycles were identified.

Results and discussion

According to the results, Swedish willow biomass production is energetically efficient, and the destination of this biomass for energy purposes (independently the sort of energy) presents environmental benefits, specifically in terms of avoided greenhouse gases emissions and fossil fuels depletion. Several processes from the agricultural activities were identified as hot spots, and special considerations should be paid on them due to their contribution to the environmental impact categories under analysis. This was the case for the production and use of the nitrogen-based fertilizer, as well as the diesel used in agricultural machineries.

Conclusions

Special attention should be paid on diffuse emissions from the ethanol production plant as well as on the control system of the combustion emissions from the boiler.     

Effects of nitrate concentration on the denitrification potential of a calcic cambisol and its fractions of N2, N2O and NO

Background and aims

The direct measurement of denitrification dynamics and its product fractions is important for parameterizing process-oriented model(s) for nitrogen cycling in various soils. The aims of this study are to a) directly measure the denitrification potential and the fractions of nitrogenous gases as products of the process in laboratory, b) investigate the effects of the nitrate (NO ₃ ^? ) concentration on emissions of denitrification gases, and c) test the hypothesis that denitrification can be a major pathway of nitrous oxide (N₂O) and nitric oxide (NO) production in calcic cambisols under conditions of simultaneously sufficient supplies of carbon and nitrogen substrates and anaerobiosis as to be found to occur commonly in agricultural lands.

Methods

Using the helium atmosphere (with or without oxygen) gas-flow-soil-core technique in laboratory, we directly measured the denitrification potential of a silt clay calcic cambisol and the production of nitrogen gas (N₂), N₂O and NO during denitrification under the conditions of seven levels of NO ₃ ^? concentrations (ranging from 10 to 250 mg N kg^?1 dry soil) and an almost constant initial dissolved organic carbon concentration (300 mg C kg^?1 dry soil).

Results

Almost all the soil NO ₃ ^? was consumed during anaerobic incubation, with 80–88 % of the consumed NO ₃ ^? recovered by measuring nitrogenous gases. The results showed that the increases in initial NO ₃ ^? concentrations significantly enhanced the denitrification potential and the emissions of N₂ and N₂O as products of this process. Despite the wide range of initial NO ₃ ^? concentrations, the ratios of N₂, N₂O and NO products to denitrification potential showed much narrower ranges of 51–78 % for N₂, 14–36 % for N₂O and 5–22 % for NO.

Conclusions

These results well support the above hypothesis and provide some parameters for simulating effects of variable soil NO ₃ ^? concentrations on denitrification process as needed for biogeochemical models.     

Life cycle greenhouse gas emissions of palm oil production by wet and dry extraction processes in Thailand

Purpose

The crude palm oil (CPO) extraction is normally done by a wet extraction process, and wastewater treatment of the wet process emits high levels of greenhouse gases (GHGs). A dry process extracts mixed palm oil (MPO) from palm fruit without using water and has no GHG emissions from wastewater treatment. This work is aimed at determining the GHG emissions of a dry process and at evaluating GHG savings on changing from wet to dry process, including land use change (LUC) effects.

Methods

Life cycle assessment from cradle to gate was used. The raw material is palm fruits. The dry process includes primary production, oil room, and utilities. MPO is the main product, while palm cake and fine palm residue are co-products sold for animal feed. Case studies were undertaken without and with carbon stocks of firewood and of nitrogen recycling at plantations from fronds. Allocations by mass, economic, and heating values were conducted. The trading of GHG emissions from co-products to GHG emissions from animal feed was assessed. The GHG emissions or savings from direct LUC (dLUC) and from indirect LUC (iLUC) effects and for the change from wet to dry process were determined.

Results and discussion

Palm fruit and firewood were the major GHG emission sources. Nitrogen recycling on plantations from fronds significantly affects the GHG emissions. With the carbon stocks, the GHG emissions allocated by energy value were 550 kg CO₂ eq/t MPO. The GHG emissions were affected by ?3 to 37% for the change from wet to dry process. When the plantation area was increased by 1 ha and the palm oil extraction was changed from wet to dry process, and the change included dLUC and iLUC, the GHG savings ranged from ?0.94 to 5.08 t CO₂ eq/ha year. The iLUC was the main GHG emission source. The GHG saving mostly originated from the change of extraction process and from the dLUC effect. Based on the potential use of biodiesel production from oil palm, during 2015–2036 in Thailand, when the extraction process was changed and dLUC and iLUC effects were included, the saving in GHG emissions was estimated to range from ?35,454 to 274,774 t CO₂ eq/year.

Conclusions

The change of palm oil extraction process and the LUC effects could minimize the GHG emissions from the palm oil industry. This advantage encourages developing policies that support the dry extraction process and contribute to sustainable developments in palm oil production.

     

A comparison of the GHG emissions caused by manufacturing tissue paper from virgin pulp or recycled waste paper

Purpose

The aim of this work is to compare greenhouse gas (GHG) emissions from producing tissue paper from virgin pulp (VP) or recycled waste paper (RWP). In doing so, the study aims to inform decision makers at both company and national levels which are the main causes of emissions and to suggest the actions required to reduce pollution.

Methods

An attributional life cycle assessment (LCA) was performed in order to estimate and compare the GHG emissions of the two processes. LCA allows us to assess how the choice of raw material for VP and RWP processes influences total GHG emissions of tissue paper production, what are the main drivers behind these emissions and how do the direct materials; energy requirements and transportation contribute to the generation of emissions. The cradle-to-gate approach is carried out.

Results and discussion

The results show that demands for both thermal energy and electricity are higher for the RWP than for the VP if only the manufacturing stages are considered. However, a different picture emerges when the analysis looks at the entire life cycle of the production. GHG from the VP are about 30 % higher than the RWP, over the life cycle emitting 568 kg CO₂ eq more per kilogram of tissue paper. GHG emissions from the wood pulping alone were 559 g CO₂ eq per kilogram of tissue paper, three times higher than waste paper collection and transportation.

Conclusions

In terms of GHG emissions from cradle to gate, the recycled process less intensive than the virgin one for two reasons. First, as shown in the results the total GHG emissions from RWP are lower than those from VP due to relatively lower energy and material requirements. Second is the non-recyclability nature of tissue paper. Because the tissue paper is the last use of fibre, using RWP as an input would be preferable over using VP. The environmental profile of the tissue products both from RWP and VP can be improved if the following conditions are considered by the company. First, the company should consider implementing a cogeneration unit to simultaneously generate both useful heat and electricity. Second, it may consider changing the VP mix, in order to avoid the emissions associated with long distance transpiration effort. Third, there is the option of using sludge as fuel, which would reduce the total fossil fuel requirement.     

Climate change impacts on life cycle greenhouse gas (GHG) emissions savings of biomethanol from corn and soybean

Purpose

The purpose of this study is to assess and calculate the potential impacts of climate change on the greenhouse gas (GHG) emissions reduction potentials of combined production of whole corn bioethanol and stover biomethanol, and whole soybean biodiesel and stalk biomethanol. Both fuels are used as substitutes to conventional fossil-based fuels. The product system includes energy crop (feedstock) production and transportation, biofuels processing, and biofuels distribution to service station.

Methods

The methodology is underpinned by life cycle thinking. Crop system model and life cycle assessment (LCA) model are linked in the analysis. The Decision Support System for Agrotechnology Transfer – crop system model (DSSAT-CSM) is used to simulate biomass and grain yield under different future climate scenarios generated using a combination of temperature, precipitation, and atmospheric CO₂. Historical weather data for Gainesville, Florida, are obtained for the baseline period (1981–1990). Daily minimum and maximum air temperatures are projected to increase by +2.0, +3.0, +4.0, and +5.0 °C, precipitation is projected to change by ±20, 10, and 5 %, and atmospheric CO₂ concentration is projected to increase by +70, +210, and +350 ppm. All projections are made throughout the growing season. GaBi 4.4 is used as primary LCA modelling software using crop yield data inputs from the DSSAT-CSM software. The models representation of the physical processes inventory (background unit processes) is constructed using the ecoinvent life cycle inventory database v2.0.

Results and discussion

Under current baseline climate condition, net greenhouse gas (GHG) emissions savings per hectare from corn-integrated biomethanol synthesis (CIBM) and soybean-integrated biomethanol synthesis (SIBM) were calculated as ?8,573.31 and ?3,441 kg CO₂-eq. ha^?1 yr^?1, respectively. However, models predictions suggest that these potential GHG emissions savings would be impacted by changing climate ranging from negative to positive depending on the crop and biofuel type, and climate scenario. Increased atmospheric level of CO₂ tends to minimise the negative impacts of increased temperature.

Conclusions

While policy measures are being put in place for the use of renewable biofuels driven by the desire to reduce GHG emissions from the use of conventional fossil fuels, climate change would also have impacts on the potential GHG emissions reductions resulting from the use of these renewable biofuels. However, the magnitude of the impact largely depends on the biofuel processing technology and the energy crop (feedstock) type.     

Carbon footprint of spring barley in relation to preceding oilseeds and N fertilization

Purpose

Carbon footprint of field crops can be lowered through improved cropping practices. The objective of this study was to determine the carbon footprint of spring barley (Hordeum vulgare L.) in relation to various preceding oilseed crops that were fertilized at various rates of inorganic N the previous years. System boundary was from cradle-to-farm gate.

Materials and methods

Canola-quality mustard (Brassica juncea L.), canola (Brassica napus L.), sunflower (Helianthus annuus L.), and flax (Linum usitatissimum L.) were grown under the N fertilizer rates of 10, 30, 70, 90, 110, 150, and 200?kg?N?ha^?1 the previous year, and spring barley was grown on the field of standing oilseed stubble the following year. The study was conducted at six environmental sites; they were at Indian Head in 2005, 2006 and 2007, and at Swift Current in 2004, 2005 and 2006, Saskatchewan, Canada.

Results and discussion

On average, barley grown at humid Indian Head emitted greenhouse gases (GHGs) of 1,003?kg?CO₂eq?ha^?1, or 53% greater than that at the drier Swift Current site. Production and delivery of fertilizer N to farm gate accounted for 26% of the total GHG emissions, followed by direct and indirect emissions of 28% due to the application of N fertilizers to barley crop. Emissions due to N fertilization were 26.6 times the emission from the use of phosphorous, 5.2 times the emission from pesticides, and 4.2 times the emission from various farming operations. Decomposition of crop residues contributed emissions of 173?kg?CO₂eq?ha^?1, or 19% of the total emission. Indian Head-produced barley had significantly greater grain yield, resulting in about 11% lower carbon footprint than Swift Current-produced barley (0.28 vs. 0.32?kg?CO₂eq?kg^?1 of grain). Emissions in the barley production was a linear function of the rate of fertilizer N applied to the previous oilseed crops due to increased emissions from crop residue decomposition coupled with higher residual soil mineral N.

Conclusions

The key to lower the carbon footprint of barley is to increase grain yield, make a wise choice of crop types, reduce N inputs to crops grown in the previous and current growing seasons, and improved N use efficiency.     

Methane and nitrous oxide emissions from direct-seeded and seedling-transplanted rice paddies in southeast China

Background and aims

The rice production is experiencing a shift from conventionally seedling-transplanted (TPR) to direct-seeded (DSR) cropping systems in Southeast Asia. Besides the difference in rice crop establishment, water regime is typically characterized as water-saving moist irrigation for DSR and flooding-midseason drainage-reflooding and moist irrigation for TPR fields, respectively. A field experiment was conducted to quantify methane (CH₄) and nitrous oxide (N₂O) emissions from the DSR and TPR rice paddies in southeast China.

Methods

Seasonal measurements of CH₄ and N₂O fluxes from the DSR and TPR plots were simultaneously taken by static chamber-GC technique.

Results

Seasonal fluxes of CH₄ averaged 1.58 mg m^?2 h^?1 and 1.02 mg m^?2 h^?1 across treatments in TPR and DSR rice paddies, respectively. Compared with TPR cropping systems, seasonal N₂O emissions from DSR cropping systems were increased by 49 % and 46 % for the plots with or without N application, respectively. The emission factors of N₂O were estimated to be 0.45 % and 0.69 % of N application, with a background emission of 0.65 and 0.95 kg N₂O-N ha^?1 under the TPR and DSR cropping regimes, respectively. Rice biomass and grain yield were significantly greater in the DSR than in the TPR cropping systems. The net global warming potential (GWP) of CH₄ and N₂O emissions were comparable between the two cropping systems, while the greenhouse gas intensity (GHGI) was significantly lower in the DSR than in the TPR cropping systems.

Conclusions

Higher grain yield, comparable GWP, and lower GHGI suggest that the DSR instead of conventional TPR rice cropping regime would weaken the radiative forcing of rice production in terms of per unit of rice grain yield in China, and DSR rice cropping regime could be a promising rice development alternative in mainland China.     

Modelling,assessing, and ranking public procurement options for a climate-friendly catering service

Purpose

Several scientific papers and technical reports have discussed the role of green public procurement in the food sector. Different strategies for the restoration sector have been identified. However, there is not yet a common understanding of which policies could be the most efficient in reducing the global warming potential of the public restoration service. This paper assesses a set of procurement policies, ranking them according to their potential to reduce the greenhouse gas emissions of public catering.

Methods

Eleven relevant green public procurement policies were identified from the literature. These are discussed in the context of a case study of the school catering service in the city of Turin (Italy). Initially, a life cycle approach is applied to a baseline scenario of the collective restoration system of the city, to quantify the quantity of greenhouse gases produced by the entire catering service (including all stages from the production of food to the management of waste from kitchens and canteens). Afterwards, the 11 policies were applied to the baseline scenario so that the potential improvement achieved by each policy could be quantified.

Results and discussion

The baseline scenario resulted in 1.67 kgCO₂eq per average meal. The production of food dominates the global warming potential of the full service, being responsible for about 78% of the greenhouse gas emissions. Among the selected policies, a change in diet was the most effective (leading to a 32% reduction of the CO₂eq emissions), followed by the adoption of improved food production practices (11% reduction) and the purchasing of certified green electricity (6% reduction).

Conclusions

The proposed method allows the assessment of procurement policies in the catering service by applying a simplified life cycle approach that considers all the stages of the process. Public authorities and other stakeholders could benefit from basing their decisions upon scientific evidence and avoiding the prioritisation of policies based on personal opinions or weak evidence. Uncertainties and areas for improvement in the method have been also identified for future investigation.

     

Life cycle assessment of sugarcane ethanol production in India in comparison to Brazil

Purpose

India’s biofuel programme relies on ethanol production from sugarcane molasses. However, there is limited insight on environmental impacts across the Indian ethanol production chain. This study closes this gap by assessing the environmental impacts of ethanol production from sugarcane molasses in Uttar Pradesh, India. A comparative analysis with south-central Brazilian sugarcane ethanol is also presented to compare the performance of sugarcane molasses-based ethanol with sugarcane juice-based ethanol.

Methods

The production process is assessed by a cradle-to-gate life cycle assessment. The multifunctionality problem is solved by applying two variants of system expansion and economic allocation. Environmental impacts are assessed with Impact 2002+ and results are presented at the midpoint level for greenhouse gas emissions, non-renewable energy use, freshwater eutrophication and water use. Furthermore, results include impacts on human health and ecosystem quality at the damage level. Sensitivity analysis is also performed on key contributing parameters such as pesticides, stillage treatment and irrigation water use.

Results and discussion

It is found that, compared to Brazilian ethanol, Indian ethanol causes lower or comparable greenhouse gas emissions (0.09–0.64 kgCO_2eq/kg_ethanolIN, 0.46–0.63 kgCO_2eq/kg_ethanolBR), non-renewable energy use (?0.3–6.3 MJ/kg_ethanolIN, 1–4 MJ/kg_ethanolBR), human health impacts (3.6?·?10^?6 DALY/kg_ethanolIN, 4?·?10^?6 DALY/kg_ethanolBR) and ecosystem impairment (2.5 PDF?·?m²?·?year/kg_ethanolIN, 3.3 PDF?·?m²?·?year/kg_ethanolBR). One reason is that Indian ethanol is exclusively produced from molasses, a co-product of sugar production, resulting in allocation of the environmental burden. Additionally, Indian sugar mills and distilleries produce surplus electricity for which they receive credits for displacing grid electricity of relatively high CO₂ emission intensity. When economic allocation is applied, the greenhouse gas emissions for Indian and Brazilian ethanol are comparable. Non-renewable energy use is higher for Indian ethanol, primarily due to energy requirements for irrigation. For water use and related impacts, Indian ethanol scores worse due groundwater irrigation, despite the dampening effect of allocation. The variation on greenhouse gas emissions and non-renewable energy use of Indian mills is much larger for high and low performance than the respective systems in Brazil.

Conclusions

Important measures can be taken across the production chain to improve the environmental performance of Indian ethanol production (e.g. avoiding the use of specific pesticides, avoiding the disposal of untreated stillage, transition to water efficient crops). However, to meet the targets of the Indian ethanol blending programme, displacement effects are likely to occur in countries which export ethanol. To assess such effects, a consequential study needs to be prepared.