Exceptionally High Performance Anode Material Based on Lattice Structure Decorated Double Perovskite Sr2FeMo2/3Mg1/3O6−δ for Solid Oxide Fuel Cells |
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| Authors: | Zhihong Du Hailei Zhao Shanming Li Yang Zhang Xiwang Chang Qing Xia Ning Chen Lin Gu Konrad Świerczek Yan Li Tianrang Yang Ke An |
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| Affiliation: | 1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, China;2. Beijing Municipal Key Lab for Advanced Energy Materials and Technologies, Beijing, China;3. Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, China;4. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, China;5. Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, Krakow, Poland;6. AGH Centre of Energy, AGH University of Science and Technology, Krakow, Poland;7. Department of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing, China;8. Department of Mechanical Engineering, University of South Carolina, Columbia, SC, USA;9. Chemical and Engineering Materials Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN, USA |
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| Abstract: | A novel double perovskite Sr2FeMo2/3Mg1/3O6?δ is prepared and characterized as an anode material for solid oxide fuel cells (SOFCs). X‐ray diffraction refinement reveals that Mg and Mo cations locate separately in two different B sites (B and B′ in A2BB′O6) while Fe occupies both B and B′ sites, forming the lattice structure with the form of Sr2(Mg1/3Fe2/3)(Mo2/3Fe1/3)O6?δ. The inactive element Mg doping not only endows the material with excellent redox structural stability but also triggers the creation of antisite defects in the crystal lattice, which provide the material with excellent electrochemical activity. The anode performance of Sr2FeMo2/3Mg1/3O6?δ is characterized in an La0.8Sr0.2Ga0.8Mg0.2O3?δ electrolyte supported cell with La0.58Sr0.4Fe0.8Co0.2O3?δ cathode. A peak power density of 531, 803, 1038, and 1316 mW cm?2 at 750, 800, 850, and 900 °C, respectively, is achieved in humidified H2. The Sr2FeMo2/3Mg1/3O6?δ shows suitable thermal expansion coefficient (16.9(2) × 10?6 K?1), high electrical conductivity, and good tolerance to carbon deposition and sulfur poisoning. First‐principle computations demonstrate that the presence of FeB? O? FeB′ bonds can promote the easy formation and fast migration of oxygen vacancies in the lattice, which are the key to affecting the anode reaction kinetics. The excellent overall performance of Sr2FeMo2/3Mg1/3O6?δ compound makes it a promising anode material for SOFCs. |
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| Keywords: | antisite defects double perovskite oxygen surface exchange redox stability solid oxide fuel cells |
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