Synthesis of 2,3,4,5-tetra-O-methyl-D-glucono-1,6-lactone as a monomer for the preparation of copolyesters |
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| Authors: | Pinilla Inmaculada Molina Martínez Manuel Bueno Galbis Juan A |
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| Institution: | Departamento de Qui;mica Orgánica y Farmacéutica, Facultad de Farmacia Qui;mica Orgánica y Farmacéutica, Universidad de Sevilla, 41071, Sevilla, Spain. |
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| Abstract: | 2,3,4,5-tetra-O-methyl-D-glucono-1,6-lactone has been prepared as a crystalline compound in acceptable yield by two different routes. An initial assay of copolymerization with L-lactide by ring-opening polymerization was carried out. The incorporation of the carbohydrate monomer into the polymer chain was about 2%. |
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| Keywords: | d-Gluconic acid" target="_blank">d-Gluconic acid protected d-Glucono-1" target="_blank">d-Glucono-1 6-lactone protected l-Lactide" target="_blank">l-Lactide Ring-opening polymerization Copolyesters |
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