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Mid-infrared spectroscopic analysis of saccharides in aqueous solutions with sodium chloride
Authors:Mikihito Kanou  Takaharu Kameoka  Ken-ichiro Suehara  Atsushi Hashimoto
Institution:1. Intellectual Property Office, Community-University Research Cooperation Center, Mie University, Tsu, Japankanou@crc.mie-u.ac.jp;3. Division of Sustainable Resource Sciences, Graduate School of Bioresources, Mie University, Tsu, Japan
Abstract:The infrared spectral characteristics of three different types of disaccharides (trehalose, maltose, and sucrose) and four different types of monosaccharides (glucose, mannose, galactose, and fructose) in aqueous solutions with sodium chloride (NaCl) were determined. The infrared spectra were obtained using the FT-IR/ATR method and the absorption intensities respected the interaction between the saccharide and water with NaCl were determined. This study also focused on not only the glycosidic linkage position and the constituent monosaccharides, but also the concentration of the saccharides and NaCl and found that they have a significant influence on the infrared spectroscopic characterization of the disaccharides in an aqueous solution with NaCl. The absorption intensities representing the interaction between a saccharide and water with NaCl were spectroscopically determined. Additionally, the applications of MIR spectroscopy to obtain information about saccharide–NaCl interactions in foods and biosystems were suggested.
Keywords:monosaccharide  disaccharide  sodium chloride  mid-infrared spectroscopy
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