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Lipase-mediated homotopic and heterotopic double resolutions of a planar chiral organometallic alcohol |
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| Authors: | Yoshimitsu Yamazaki Nobuo Morohashi Kuniaki Hosono |
| Institution: | (1) Fermentation Research Institute, AIST, 1-1-3 Higashi, 305 Tsukuba, Ibaraki, Japan;(2) Tsukuba Research Laboratories, Toyo Ink MFG. Co., Ltd., 27-Wadai, 300-42 Tsukuba, Ibaraki, Japan |
| Abstract: | Summary (±)-Tricarbonyl  6-3-methylbenzyl alcohol)chromium was resolved to of  100%e.e. and of 92%e.e. by lipase-catalyzed transesterifications arranged in homotopic and heterotopic double resolutions. |
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