Chemical Synthesis of 3D Graphene‐Like Cages for Sodium‐Ion Batteries Applications |
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| Authors: | Xinxin Cao Anqiang Pan Sainan Liu Jiang Zhou Site Li Guozhong Cao Jun Liu Shuquan Liang |
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| Institution: | 1. School of Material Science and Engineering, Central South University, Changsha, P. R. China;2. Department of Materials Science & Engineering, University of Washington, Seattle, WA, USA;3. Pacific Northwest National Laboratory, Richland, WA, USA |
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| Abstract: | Sodium (Na) super ion conductor structured Na3V2(PO4)3 (NVP) is extensively explored as cathode material for sodium‐ion batteries (SIBs) due to its large interstitial channels for Na+ migration. The synthesis of 3D graphene‐like structure coated on NVP nanoflakes arrays via a one‐pot, solid‐state reaction in molten hydrocarbon is reported. The NVP nanoflakes are uniformly coated by the in situ generated 3D graphene‐like layers with the thickness of 3 nm. As a cathode material, graphene covered NVP nanoflakes exhibit excellent electrochemical performances, including close to theoretical reversible capacity (115.2 mA h g?1 at 1 C), superior rate capability (75.9 mA h g?1 at 200 C), and excellent cyclic stability (62.5% of capacity retention over 30000 cycles at 50 C). Furthermore, the 3D graphene‐like cages after removing NVP also serve as a good anode material and deliver a specific capacity of 242.5 mA h g?1 at 0.1 A g?1. The full SIB using these two cathode and anode materials delivers a high specific capacity (109.2 mA h g?1 at 0.1 A g?1) and good cycling stability (77.1% capacity retention over 200 cycles at 0.1 A g?1). |
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| Keywords: | graphene‐like cages nanoflake arrays Na3V2(PO4) sodium‐ion batteries surfactant |
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