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A benzil and isoflavone from Iris tenuifolia
Authors:Choudhary Muhammad Iqbal  Hareem Sumaira  Siddiqui Hina  Anjum Shazia  Ali Shamsher  Atta-Ur-Rahman  Zaidi Mudassir Israr
Institution:H.E.J. Research Institute of Chemistry, International Center for Chemical and Biological Sciences, University of Karachi, Karachi 75270, Pakistan. hej@cyber.net.pk
Abstract:Two compounds, tenuifodione (1) and tenuifone (2), and 12 known compounds, izalpinin (3), alpinone (4), arborinone (5), irilin B (6), irisone A (7), irisone B (8), betavulgarin (9), beta-sitosterol (10), 5,7-dihydroxy-2',6-dimethoxyisoflavone (11), 2',5-dihdroxy-6,7-methylenedioxy flavanone (12), irisoid A (13) and ethyl-beta-d-glucopyranoside (14) were isolated from the whole plant of Iris tenuifolia Pall. All compounds, except 12, were isolated for the first time from this plant. Compounds 2, 3 and 11 have shown a considerable DPPH radical scavenging activity. Structures of these compounds were identified on the basis of spectroscopic techniques, including 2D NMR. Compounds 3, 5 and 7 were also subjected to single-crystal X-ray diffraction analysis and their structures were unambiguously deduced.
Keywords:Iris tenuifolia  Iridaceae  Phytochemical investigation  Benzil  Isoflavone  DPPH radical scavenging activity  X-ray diffraction studies
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