Unambiguous structure of atractyloside and carboxyatractyloside |
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| Authors: | Sanchez Jean-Frédéric Kauffmann Brice Grélard Axelle Sanchez Corinne Trézéguet Véronique Huc Ivan Lauquin Guy J-M |
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| Institution: | Université de Bordeaux, IBGC, UMR5095, Laboratoire de Physiologie Moléculaire et Cellulaire, Bordeaux, France. |
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| Abstract: | Atractyloside (ATR) was characterized in 1868 and until now structural studies on diterpenic moiety had been done through the characterization of ATR derivatives; while the glycosidic moiety seemed to be a β-D-glucopyranose a recent crystal structure of the mitochondrial ATP/ADP carrier in complex with CATR showed an α-D-glucopyranose. We decided to re-examine the ATR and CATR structures by crystallographic study of ATR. |
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