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Exploring the molecular mechanism of karrikins and strigolactones
Authors:Scaffidi Adrian  Waters Mark T  Bond Charles S  Dixon Kingsley W  Smith Steven M  Ghisalberti Emilio L  Flematti Gavin R
Institution:School of Chemistry and Biochemistry, The University of Western Australia, Crawley, WA 6009, Australia. adrian.scaffidi@uwa.edu.au
Abstract:Karrikins and strigolactones are novel plant growth regulators that contain similar molecular features, but very little is known about how they elicit responses in plants. A tentative molecular mechanism has previously been proposed involving a Michael-type addition for both compounds. Through structure-activity studies with karrikins, we now propose an alternative mechanism for karrikin and strigolactone mode of action that involves hydrolysis of the butenolide ring.
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