黔西北两铜矿4种藓类植物重金属元素分析

坝口铜矿和长箐沟铜矿是峨眉山玄武岩型铜矿。利用3种光谱仪对卷叶丛本藓（Anoectangium thomso-niiMitt.）、酸土藓Oxystegus cylindricus（Brid.）Hilp.]、硬叶扭口藓Barbula rigidula（Hedw.）Mild.]和齿边异齿藓Regmatodon serrulatus（Dozy et Molk.）Bosch et Lac.]及其基质中的Cu、Zn、Ca、Mg、Cd、Pb、Hg和As8种元素进行测定及分析,并计算出富集系数。结果表明,两铜矿Cu、Zn、Cd和Hg的背景值均超标,特别是Hg和Cu的平均含量分别是其标准值的10.28倍和2.33倍。长箐沟铜矿受Hg污染较重,坝口铜矿比长箐沟铜矿含Cu高。Cu-Cd、Zn-Ca、Ca-Pb和Hg-As均在0.05水平显著相关,Zn-Pb在0.01水平显著相关。Cu-Cd、Zn-Pb和Hg-As均产生协同效应。Zn-Ca和Ca-Pb均产生拮抗效应。富集系数有显著意义。4种藓类植物对Cu、Cd和Pb的吸收能力均是同一水平,可以作为指示植物,构成藓类植物组合来鉴别富集Cu、Cd和Pb的矿区。可利用卷叶丛本藓作为特征植物降低矿区As的污染。

Heavy Metal Contents in Four Mosses at Two Copper Mines in Northwest Guizhou,China

The Bakou and Changqinggou copper mines are both Emeishan basalt-type copper deposits.The copper is located mainly in the top and the upper part of the Permian Emeishan basalt.By using a Analyst 800 atomic absorption spectrophotometer,AF-640 atomic fluorescence spectrophotometer,and Optima 5300 V inductively coupled plasma optical emission spectrophotometer,we analyzed the contents of eight elements (Cu,Zn,Ca,Mg,Cd,Pb,Hg,and As) in Anoectangium thomsonii Mitt.,Oxystegus cylindricus (Brid.) Hilp.,Barbula rig...