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Buffering an Acidic Stream in New Hampshire with a Silicate Mineral
Authors:Gene E Likens  Donald C Buso  Brian K Dresser  Emily S Bernhardt  Robert O Hall Jr    Kate H Macneale  Scott W Bailey
Institution: Address correspondence to G. E. Likens, email  Institute of Ecosystem Studies, Millbrook, NY, U.S.A.;  Present address: NOAA Fisheries, Gloucester, MA, U.S.A.;  Cornell University, Ithaca, NY, U.S.A.;  Present address: Duke University, Durham, NC, U.S.A.;  University of Wyoming, Laramie, WY, U.S.A.;  Present address: Northwest Fisheries Science Center, Seattle, WA, U.S.A.;  USDA Forest Service, Campton, NH, U.S.A.
Abstract:Ground and pelletized Wollastonite (Wo; CaSiO3) was added to a 50‐m reach of an anthropogenically acidified stream within the Hubbard Brook Experimental Forest, New Hampshire, to evaluate its buffering and restoration potential. The Wo was highly effective in raising the pH, acid‐neutralizing capacity (ANC), dissolved inorganic carbon (DIC), and Ca2+ concentrations of the stream water, but during the short duration of the experiment had no discernable effect on the stream biota. After initial, spike‐like fluctuations in pH and concentrations of ANC, DIC, and Ca2+, the relatively slow dissolution rates of the Wo dampened extreme concentrations and contributed to relatively long‐lasting (4 months) amelioration of streamwater acidity. Changes in concentrations of Ca2+, dissolved Si, ANC, and DIC were inversely related to streamflow. After several high, stream‐discharge events, concentrations quickly and consistently returned to pre‐event conditions.
Keywords:acid rain                        Hubbard Brook                        stream chemistry                        stream ecosystems                        stream restoration                        Wollastonite
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