New aspects of NMR spectroscopy of polyoxometallates |
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| Authors: | Oliver W Howarth |
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| Institution: | (1) Department of Chemistry, University of Warwick, CV4 7AL Coventry, UK |
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| Abstract: | A range of 1D and 2D NMR methods has been developed for the investigation of polyoxometallate solutions, to complement and extend the insights obtained from crystallography and potentiometry. Static, dynamic and structural information can be obtained from1H,17O,51V and183W NMR. Applications are given in the elucidation of the structures and chemical interrelationships of isopolytungstates and vanadates, molybdotungstates, tungstovanadates and molybdovanadates. |
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| Keywords: | NMR isopolytungstates vanadates molybdotungstates molybdovanadates |
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