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硝酸铵水凝胶分子印迹聚合物的制备
引用本文:赵晨,胡莉莉,郑三婷.硝酸铵水凝胶分子印迹聚合物的制备[J].生物磁学,2011(5):864-866.
作者姓名:赵晨  胡莉莉  郑三婷
作者单位:西安工业大学电子信息工程学院,陕西西安710032
基金项目:西安工业大学校长科研基金资助(XAGDXJJ0713)
摘    要:目的:目前安全问题成为世界各国的首要问题,尤其是对炸药分子的检测。硝酸铵是硝铵炸药的主要成分。研究水凝胶分子印迹法对硝铵炸药分子的检测。方法:水凝胶分子印迹方法制备硝酸铵水凝胶分子印迹聚合物,运用静态结合实验对其结合率进行了测定。结果:聚合物对硝酸铵具有良好的识别和吸附性能。印迹聚合物的解离常数为4.08g/L,最大吸附量为3.51mg/g。结论:水凝胶分子印迹法可合成水溶性炸药分子印迹聚合物,并且识别及吸附性能良好。

关 键 词:分子印迹聚合物  水凝胶分子印迹法  硝酸铵

Synthesis of Ammonium Nitrate Molecularly Imprinted Polymer within Hydrogels
ZHAO Chen,HU Li-li,ZHENG San-ting.Synthesis of Ammonium Nitrate Molecularly Imprinted Polymer within Hydrogels[J].Biomagnetism,2011(5):864-866.
Authors:ZHAO Chen  HU Li-li  ZHENG San-ting
Institution:(College of electronic information,Xi'an technological university,Xi'an,Shanxi,10032,China)
Abstract:Objective:Currently,security issues had become the world's most important issue,especially for molecular detection of explosives.Ammonium nitrate were the main component of ammonia dynamite which can be detected using molecular imprinting method.Methods:Molecularly imprinted hydrogels were prepared,and their binding rate were measured by static binding assay.Results:Research showed that the polymer had a good properties of recognition and adsorption.Dissociation constants was 4.08g/L,maximum adsorption was 3.51mg/g.Conclusion:water-soluble explosives molecularly imprinted polymer could be by molecularly imprinted hydrogels technology,and had favorable recognition and adsorption.
Keywords:Moleculary imprinted polymer  Molecularly imprinting within hydrogels  Ammonium nitrate
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