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A mixed-valence Cu(I)-Cu(II) and metal-metal bond containing coordination polymer obtained from an in situ oxidation reaction route |
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| Authors: | Jack Y Lu Amy B Schauss |
| Institution: | a Department of Chemistry, University of Houston-Clear Lake, 2700 Bay Area Blvd., Box 214, Houston, TX 77058, USA b Departament de Quimica Inorganica, Instituto de Ciencia Molecular, Facultat de quimica de la Universitat de la, Universitat de Valencia, Dr. Moliner 50, 46100, Burjassot, Valencia, Spain |
| Abstract: | A new mixed-valence copper coordination polymer with copper-copper metal bonds in a two-dimensional network was generated from an in situ oxidation reaction route under hydrothermal conditions. The synthesis of this coordination polymer demonstrated that the novel compounds that may not be accessible using the known methods could be synthesized via an oxidation reaction route. The reaction conditions are mild enough to keep the building blocks intact during the oxidation and self-assembly process under hydrothermal conditions. |
| Keywords: | Coordination polymers Mixed valence Copper Metal-metal bond Oxidation reactions Hydrothermal reactions |
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