A growing family: New structures of coordination polymers containing adamantane-shaped phosphorus-nitrogen cage ligands |
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| Authors: | Alex B Spore Bruce C Noll Roger D Sommer |
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| Institution: | a Department of Chemistry, DePaul University, 1110 W. Belden Ave., Chicago, IL 60614, USA
b Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA |
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| Abstract: | Two new structurally characterized coordination polymers containing the P4(NR)6 ligand system are described. A convenient one-pot synthesis of P4(NR)6 (R = benzyl) via reaction of lithiated primary amine with phosphorus trichloride demonstrates an expanded scope for the preparation of this adamantane-type structure. Reactions of P4(NR)6 (R = Et, Bn) with cuprous iodide yield different products due to the differences in steric demands of the ligands. |
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| Keywords: | Coordination polymers Phosphorus-nitrogen Copper |
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