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大果大戟的化学成分
引用本文:王环,张晓峰,潘莉,杨淑敏,马云保,罗晓东.大果大戟的化学成分[J].天然产物研究与开发,2003,15(6):483-486.
作者姓名:王环  张晓峰  潘莉  杨淑敏  马云保  罗晓东
作者单位:1. 中国科学院西北高原生物研究所,青海,西宁,810001;中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室,云南,昆明,650204
2. 中国科学院西北高原生物研究所,青海,西宁,810001
3. 中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室,云南,昆明,650204
基金项目:ProjectsupportedbythefinancialsupportfromtheStateKeyLaboratoryofPhytochemistryandPlantResourcesinWestChi na ,KunmingInstituteofBotany ,ChineseAcademyofSciences,andsupportedbytheKnowledgeInnovationProjectfromtheNorthWestPlateatInstituteofBiology ,C
摘    要:从大果大戟的根部首次分离得到11个化合物。利用波谱方法鉴定为β-香树素(1),β-香树素乙酸酯(2),3β-乙酰化羽扇豆烯醇(3),baccatin(4),2个caffeic mters(5a,5b),棕榈酸-1-甘油酯(6),棕榈酸(7),东莨菪内酯(8),β-谷甾醇(9)和胡萝卜甙(10)。其中5a,5b是第一次在大戟属中得到;并对5a,5b的碳谱和氢谱数据进行了全归属。

关 键 词:大果大戟  大戟属  棕榈酸-1-甘油酯  化学成分

CHEMICAL CONSTITUENTS FROM EUPHORBIA WALLICHII
WANG Huan ,ZHANG Xiao-feng,PAN Li,YANG Shu-min,MA Yun-bao,LUO Xiao-dong.CHEMICAL CONSTITUENTS FROM EUPHORBIA WALLICHII[J].Natural Product Research and Development,2003,15(6):483-486.
Authors:WANG Huan    ZHANG Xiao-feng  PAN Li  YANG Shu-min  MA Yun-bao  LUO Xiao-dong
Institution:WANG Huan 1,2,ZHANG Xiao-feng1,PAN Li1,YANG Shu-min2,MA Yun-bao2,LUO Xiao-dong 2*
Abstract:Eleven known compounds were isolated from the roots of Euphorbia wallichii for the first time.They were elucidated to be three triterpenoids, β-amyrin ( 1 ), β-armyrin acetate (2) and 3β-acetoxy-lupenol (3), one nor-triterpene peroxide baccatin (4), two caffeic esters (5a, 5b), palmitic acid-2,3-dihydroxypropanenyl ester (6), palmitic acid (7), scopoletin(8), β-sitosterol (9) and daucosterol (10) on the basis of spectral methods. Among them, compound 5a,5b were reported firstly in the spurge family. And the NMR assigrnents of compounds 5a and 5b were given for the first time.
Keywords:Euphorbia wallichii  Euphorbia  baccatin  caffeic ester  palmitic acid-2  3-dihydroxy-propanenyl ester
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