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Sensitive and selective system of benzene detection based on a cataluminescence sensor
Authors:Bo Li  Yuejin Zhang  Juefu Liu  Xin Xie  Dan Zou  Minqiang Li  Jinhuai Liu
Institution:1. Research Center for Biomimetic Functional Materials and Sensing Devices, Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei, PR China;2. School of Information Engineering, East China Jiaotong University, Nanchang, PR China
Abstract:Au/La2O3 nanomaterials were prepared through calcining Au‐modified La(OH)3 precursors. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X‐ray diffractometry (XRD) were employed to characterize the as‐prepared samples. Benzene, a common volatile organic compound, was selected as a model to investigate the cataluminescence (CTL)‐sensing properties of the Au/La2O3 nanomaterials. Results indicated that the as‐prepared Au/La2O3 exhibited outstanding CTL properties such as stable intensity, high signal‐to‐noise values, and short response and recovery times. Under optimized conditions, the benzene assay exhibited a broad linear range of 1–4000 ppm, with a limit of detection of 0.7 ppm, which was below the standard permitted concentrations. Furthermore, the gas sensor system showed outstanding selectivity for benzene compared with seven other types of common volatile organic compounds (VOCs). The proposed gas sensor showed good characteristics with high selectivity, fast response time and long lifetime, which suggested the promising application of the Au/La2O3 nanomaterials as a novel highly efficient CTL‐sensing material. Copyright © 2013 John Wiley & Sons, Ltd.
Keywords:cataluminescence  benzene  gas sensor  Au/La2O3
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