Synthesis,characterisation and reactivity of oxodiperoxo-[2-(1-pyrazolyl)-6-menthylpyridine]molybdenum(VI): The first chiral 2-(1-pyrazole)pyridineoxodiperoxomolybdenum(VI) complex |
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| Affiliation: | 1. Department of Applied Chemistry, College of Life Science, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China;2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
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| Abstract: | We have obtained a novel chiral enantiomerically pure molybdenum complex of the type MoO(O2)2LL′ which has been fully characterised, including structural determination by X-ray crystallography and screened in a series of epoxidation reactions with simple olefins giving satisfactory conversions, but low enantioselectivities. It’s mode of epoxidation has been investigated. |
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