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Volatile Compounds from Melicope obscura
Authors:Jacqueline Smadja  Dominique Strasberg  Géraldine Legoff  Anne Gauvin‐Bialecki
Institution:1. Laboratoire de Chimie des Substances Naturelles et des Sciences des Aliments, Faculté des Sciences et Technologies, Université de la Réunion, 15 Avenue René Cassin, BP 7151, F‐97715 St Denis Messag Cedex 9, La Réunion, (phone: +262‐262‐938197;2. fax: +262‐262‐938183);3. UMR PVBMT, C53 Peuplements Végétaux et Bio‐agresseurs en Milieu Tropical, Faculté des Sciences et Technologies, Université de La Réunion, 15 Avenue René Cassin, BP 7151, F‐97715 St Denis Messag Cedex 9, La Réunion
Abstract:To evaluate the interpopulation variability of volatile compounds in Melicope obscura, four samples representing four populations were collected all over the distribution area of the species in Reunion Island (Indian Ocean). The samples were extracted by hydrodistillation, and analyzed using GC/FID and GC/MS techniques. The study revealed that, in the four essential oils obtained, oxygenated sesquiterpenes were one of the major chemical classes (9.2–35.2%), mainly consisting of a new compound, (+)‐6‐ethenyl‐2‐hydroxy‐6,10‐dimethylundeca‐2,9‐dien‐4‐one ( 1 ), called melicopenol (8.6–30.1%). The compound was isolated by column chromatography and identified by spectral analyses including 1D‐ and 2D‐NMR.
Keywords:Melicope obscura  Sesquiterpenes  Melicopenol  Reunion Island  Essential oils  Biodiversity
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