A novel type of copper(I)/(II) mixed-valence compound: [Cu(dmp)2][Cu(hfac)3] with dmp=2,9-dimethyl-1,10-phenanthroline and hfac=hexafluoroacetylacetonate |
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| Authors: | Valeri Pawlowski |
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| Institution: | Institut für Anorganische Chemie, Universität Regensburg, Universitaetsstrasse 31, D-93040 Regensburg, Germany |
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| Abstract: | The mixed-valence compound CuI(dmp)2]CuII(hfac)3] with dmp=2,9-dimethyl-1,10-phenanthroline and hfac−=hexafluoroacetylacetonate has been synthesized and structurally characterized by X-ray crystallography. The MV interaction has been examined by emission spectroscopy. The phosphorescence of CuI(dmp)2]+ is completely quenched. It is suggested that this quenching takes place by excited state electron transfer from Cu(I) to Cu(II). |
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| Keywords: | Electronic spectra Luminescence Copper complexes Mixed-valence compounds |
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