Preparation of an enantiomerically pure, highly porous metalloorganic crystal |
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| Authors: | Renata Kobetic Piotr Piotrowiak |
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| Institution: | a Department of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA
b Department of Chemistry, University of New Orleans, New Orleans, LA 70148, USA |
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| Abstract: | We report the synthesis and the structure determination of tris-(4,5-diazo-spiro-bifluorene)ruthenium(II) chloride, a chiral building block whose racemic mixture solution spontaneously resolves and forms two crystalline, enantiomerically pure, porous networks composed exclusively of the Λ or Δ atropisomers. The extended chiral channels are occupied by water molecules (approximately 20% by weight) and the chloride counter-ions. |
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| Keywords: | Chiral crystal Spirane ligands |
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