The cationic polymerization of 3-O-acetyl-β-arabinofuranose 1,2,5-orthobenzoate |
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| Authors: | Alexey F Bochkov Vladimir N Chernetsky Nikolay K Kochetkov |
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| Institution: | N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of U.S.S.R., Leninsky Prospect 47, Moscow 117334 U.S.S.R. |
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| Abstract: | Cationic polymerisation of 3-O-acetyl-β-L-arabinofuranose 1,2,5-orthobenzoate initiated by either triphenylcarbonium tetrafluoroborate or benzoylium perchlorate has been studied. The existence of living chains was demonstrated by termination of polymerisation with tritium-labelled 1-butanol. The number of growing chains reached a maximum after ≈10 min and then decreased. |
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