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New Triterpene Glycosides from an Ulosa sp. Sponge
Authors:Antonov  A S  Kalinovskii  A I  Dmitrenok  P S  Stonik  V A
Institution:(1) Far East Division, Russian Academy of Sciences, Pacific Institute of Bioorganic Chemistry, pr. Stoletiya Vladivostoka 159, Vladivostok, 660022, Russia
Abstract:New triterpene glycosides, ulososides C, (20S,22S,23R,24S)-3beta,22,23-trihydroxy-3-O-(beta-D-glucopyranosyl)-32-nor-24-methyllanost-8(9)-ene-30-oic acid, D, (20S,22S,23R,24S)-3beta,22,23-trihydroxy-3-O-(beta-D-N-acetylglucosaminopyranosyl)-32-nor-24-methyllanost-8(9)-ene-30-oic acid, and E, (20S,22S,23R,24S)-3beta,22,23-trihydroxy-3-O-(beta-D-glucuronopyranosyl-(1 rarr 2)-agr-D-arabinopyranosyl-32-nor-24-methyllanost-8(9)-ene-30-oic acid, were isolated from an Ulosa sp. sponge. Their structures were determined by spectral methods and chemical transformations. Specific features of their structures are discussed.
Keywords:sponge Ulosa sp    triterpene glycosides  isolation  spectral characteristics  structure
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