A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride |
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| Authors: | Yamada Hidetoshi Hayashi Tomomi |
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| Affiliation: | School of Science, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan. hidetosh@kwansei.ac.jp |
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| Abstract: | A glycosylation reaction induced by copper(II) trifluoromethanesulfonate is described. Using benzotrifluoride as the reaction solvent, five kinds of glycosyl donors, a glucosyl chloride, a fluoride, a trichloroacetimidate, a 1-O-acetyl compound, and a lactol were activated to give the corresponding glucosides. |
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| Keywords: | Glycosylation Copper(II) trifluoromethanesulfonate |
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