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A new approach to divalent thio-azo ligands; Ni(dpesdt)2 |
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| Authors: | S. Rabaç a,M.C. Duarte,M. Fourmigué ,M. Almeida |
| Affiliation: | a Departamento de Química, Instituto Tecnológico e Nuclear/CFMCUL, P-2686-953 Sacavém, Portugal b Laboratoire CIMMA, UMR CNRS 6501, Université d’Angers, Bd. Lavoisier, F-49045 Angers, France c Sciences Chimiques de Rennes, UMR 6226 CNRS-Uiversité, Rennes I, Campus de Beaulieu, F-35042 Rennes, France |
| Abstract: | The preparation of a new bis(2-pyridylethylsulfanyl)-1,3-dithiole-2-one (1) and the first example of a tetra-azo substituted bisdithiolene transition metal complex, Ni(dpesdt)2 (2) are reported. This complex crystallizes in two polymorphs, one is triclinic, and the other is monoclinic, P21/n space group. |
| Keywords: | Thioazo ligands Bisdithiolene Nickel complexes |
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