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Isolation of dihydroxylupene and dihydroxylupane from the bark of Lawsonia inermis
Authors:Tarakeswar Chakrabartty  Gurudas Poddar  Jan st. Pyrek
Affiliation:1. Department of Internal Medicine, University of Texas Medical School, P.O. Box 20708, Houston, TX 77025, U.S.A.
Abstract:Two pentacyclic triterpenes isolated from the bark of henna were identified as 3β, 30-dihydroxylup- 20(29)-ene (hennadiol), and (20S)-3β, 30-dihydroxylupane. The assignment of the C-20 configuration in the latter compound was supported by the analysis of Eu(fod)3-induced 1H NMR chemical shifts in the two C-20 epimers synthesized from lupeol.
Keywords:Lythraceae  henna  triterpenoids  30-hydroxylupeol  30-hydroxylupanol.
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