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Photochemical Synthesis and Multiphoton Luminescence of Monodisperse Silver Nanocrystals
Authors:Thomas Kempa  Richard A. Farrer  Michael Giersig  John T. Fourkas
Affiliation:(1) Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA;(2) Department of Nanoparticle Technology, Center of Advanced European Studies and Research, Ludwig-Erhard Allee 2, 53175 Bonn, Germany;(3) Department of Chemistry and Biochemistry, University of Maryland, College Park, MD, USA
Abstract:
A rapid, photochemical solution-phase synthesis has been developed for the production of monodisperse, nanometer-sized silver particles. The stabilizer used in the synthesis can be used to control the average diameter of the particles over a range from 1 to 7 nm. The same reaction mixture can also be employed to deposit patterns of nanoparticles with a laser via multiphoton absorption. The particles exhibit strong multiphoton absorption-induced luminescence when irradiated with 800-nm light, allowing emission from single nanoparticles to be observed readily.
Keywords:Silver nanoparticle  Photochemical synthesis  Multiphoton absorption  Luminescence
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