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无柄新乌檀中的配糖体
引用本文:康文艺,李昕,杨小生,郝小江. 无柄新乌檀中的配糖体[J]. 天然产物研究与开发, 2004, 16(2): 107-110
作者姓名:康文艺  李昕  杨小生  郝小江
作者单位:1. 中国科学院昆明植物研究所植物化学与西部资源持续利用国家重点实验室,昆明,650204
2. 贵阳医学院,贵阳,550004
3. 贵州省中科,院天然产物化学重点实验室,贵阳,550002
摘    要:
从无柄新乌檀乙醇浸膏的正丁醇部位分离得到7个已知配糖体化合物,经波谱分析为:喹诺酸-3-O-β-D-葡萄吡喃糖基(28→1)-β-D-葡萄吡喃糖酯(1),齐墩果酸-(28→1)-β-D-葡萄吡喃糖酯(2),熊果酸-(28→1)-β-D-葡萄吡喃糖酯(3),喹诺酸-3-O-β-D-葡萄吡喃糖基-(1→3)-6-去氧-β-葡萄吡喃糖苷(4),齐墩果酸-3-O-β-D-吡喃木糖基-(1→2)-β-D-葡萄吡喃糖基-28-O-β-D-葡萄吡喃糖酯(5),番木鳖甙(6),7-甲氧基-龙胆苦甙(7)。这些化合物均为首次从该属中分离得到。

关 键 词:配糖体 波谱分析 无柄新乌檀 中药 乙醇浸膏

GLYCOSIDES FROM NEONAUCLEA SESSILIFOLIA
Abstract. GLYCOSIDES FROM NEONAUCLEA SESSILIFOLIA[J]. Natural Product Research and Development, 2004, 16(2): 107-110
Authors:Abstract
Abstract:
Seven known conpoundls were isolated from the n-BuOH fraction of the stems of Neonauclea sessilifolia(Roxb.) Merr, and their structures were elucidated by means of spectroscopic method as quinovic acid-3-O-β-D-glucopyranosyl- (28--→1)-β-D-glucopyranosyl ester( 1 ), oleanolic acid- ( 28 → 1 )-β-D-glucopyranosyl ester(2), ursolicacid-(28→1)-β-D-glucopyranosyl ester(3), quinovic acid-3-O-β-D-glucopyranosyl( 1→3)-6-deoxy-β-glucopyranoside(4), oleanic acid-3-O-β-D-xylopyranosyl-( 1 → 2 )-β-D-glucopyranoside-28-O-β-D-glucopyranosyl ester ( 5 ), iridoidloganin(6), 7-methoxy-gentiopicroside(7). All of them were isolated from the genus for the first time.
Keywords:Neonauclea sessilifolia  glycoside  spectroscopic methods
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