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Sesquiterpenes of thalloid liverworts of the genera Conocephalum,Lunularia, Metzgeria and Riccardia
Authors:Niels H Andersen  Yoshimoto Ohta  C-B Liu  C Michael Kramer  Ken Allison  S Huneck
Institution:1. Department of Chemistry, University of Washington, Seattle, WA 98195, U.S.A.;2. Institute of Plant Biochemistry, Research Centre for Molecular Biology and Medicine of the Academy of Sciences of the GDR, DDR-401, Halle/Saale, Weinberg, German Democratic Republic
Abstract:Thalloid liverworts of orders Metzgeriales and Marchantiales elaborate essential oils distinguishable from those of the Jungermanniales by the absence of β-barbatene and anastreptene. Riccardia sinuata elaborates a novel tricyclic exomethylene sesquiterpene of as yet undetermined structure. Conocephalum conicum elaborates cadinene-type sesquiterpenes. β-Cadinene from the latter species is clearly enantiomeric to the same product from vascular plants.
Keywords:Lunularis  Metzgeria  Hepaticae  cadinene  δ-cadinene  
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