Structure of rhodotorucine <span class="math"><math><mtext>A</mtext></math></span>, a novel lipopeptide,inducing mating tube formation in <span class="math"><math><mtext>Rhodosporidium</mtext><mtext>toruloides</mtext></math></span>期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Structure of rhodotorucine $A$ , a novel lipopeptide,inducing mating tube formation in $Rhodosporidium toruloides$

Authors:	Yuji Kamiya Akira Sakurai Saburo Tamura Nobutaka Takahashi Keiko Abe Eiko Tsuchiya Sakuzo Fukui Chieko Kitada Masahiko Fujino

Institution:	The Institute of Physical and Chemical Research, Wako-shi, Saitama-ken, Japan;The Institute of Applied Microbiology, The University of Tokyo Bunkyo-ku, Tokyo, Japan;Central Research Division, Takeda Chemical Industries, Ltd., Yodogawa-ku, Osaka, Japan

Abstract:	Rhodotorucine $A$ is a peptidyl factor which induces mating tube formation in $Rhodosporidium toruloides$ . The amino acid sequence of the factor was determined by Edman degradation and enzymatic hydrolysis. Rhodotorucine $A$ was shown to contain a lipophilic amino acid, S-farnesyl cysteine, at C-terminus by proton magnetic resonance, mass spectrometry and chemical synthesis. We proposed the following structure for rhodotorucine $A$ . H-Tyr-Pro-Glu-Ile-Ser-Trp-Thr-Arg-Asn-Gly-Cys(S-farnesyl)-OH

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