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Polymerization of cardanol using soybean peroxidase and its potential application as anti-biofilm coating material
Authors:Yong Hwan Kim  Eun Suk An  Bong Keun Song  Dong Shik Kim  Rahul Chelikani
Affiliation:(1) Korea Research Institute of Chemical Technology, P.O. Box 107, Yusong, Taejon, 305-600, Korea;(2) Department of Chemical & Environmental Engineering, University of Toledo, Toledo, OH 43606-3390, USA
Abstract:
Soybean peroxidase (20 mg) catalyzed the oxidative polymerization of cardanol in 2-propanol/phospate buffer solution (25 ml, 1:1 v/v) and yielded 62% polycardanol over 6 h. Cobalt naphthenate (0.5% w/w) catalyzed the crosslinking of polycardanol and the final hardness of crosslinked polycardanol film exceeded 9 H scale as pencil scratch hardness, which shows a high potential as a commercial coating material. In addition, it showed an excellent anti-biofouling activity to Pseudomonas fluorescens compared to other polymeric materials such as polypropylene.
Keywords:anti-biofouling  cardanol  enzymatic polymerization  soybean peroxidase
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