Ammonia chemical ionization mass spectrometry of lecithins on a gold support |
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Authors: | P. Bisseret Y. Nakatani G. Ourisson R. Hueber G. Teller |
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Affiliation: | Laboratoire de Chimie Organique des Substances Naturelles, Associé au CNRS et Service de Spectrométrie de Masse, Université Louis Pasteur, Institut de Chimie, 1 rue Blaise Pascal, 67008 Strasbourgh France |
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Abstract: | Lecithins directly introduced on a gold wire near the electron beam under ammonia chemical ionization conditions, give mass spectra showing the (M + 1)+ ion and ions of structurally significant fragments. Of particular interest is the identification of a substitution-like reaction of ammonia on the head group of the phosphatidylcholines. No instrumental modifications is required. |
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Keywords: | ammonia chemical ionization mass spectrometry phosphatidylcholines |
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