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Ammonia chemical ionization mass spectrometry of lecithins on a gold support
Authors:P. Bisseret  Y. Nakatani  G. Ourisson  R. Hueber  G. Teller
Affiliation:Laboratoire de Chimie Organique des Substances Naturelles, Associé au CNRS et Service de Spectrométrie de Masse, Université Louis Pasteur, Institut de Chimie, 1 rue Blaise Pascal, 67008 Strasbourgh France
Abstract:Lecithins directly introduced on a gold wire near the electron beam under ammonia chemical ionization conditions, give mass spectra showing the (M + 1)+ ion and ions of structurally significant fragments. Of particular interest is the identification of a substitution-like reaction of ammonia on the head group of the phosphatidylcholines. No instrumental modifications is required.
Keywords:ammonia chemical ionization  mass spectrometry  phosphatidylcholines
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