A rhodamine-deoxylactam based sensor for chromo-fluorogenic detection of nerve agent simulant |
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| Authors: | Zhisheng Wu Xuanjun Wu Yuhui Yang Ting-bin Wen Shoufa Han |
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| Affiliation: | Department of Chemical Biology, College of Chemistry and Chemical Engineering and the Key Laboratory for Chemical Biology of Fujian Province Xiamen University, 361005 Xiamen, China |
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| Abstract: | N-(rhodamine B)-deoxylactam-5-amino-1-pentanol (dRB-APOH) was designed and prepared as the chromo-fluorogenic sensor for detection of a nerve agent simulant via analyte triggered tandem phosphorylation and opening of the intramolecular deoxylactam. The successful detection of diethyl chlorophosphate suggests the utility of rhodamine-deoxylactams as the chromo-fluorogenic signal reporting platform for design of sensors targeting reactive chemical species via various chemistries. |
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