The structure of (μ3-sulfido)(μ3-p-tolyphosphido)tris(tricarbonyliron)(2FeFe) |
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| Authors: | John P. Fackler Anthony M. Mazany Dietmar Seyferth Howard P. Withers Timothy G. Wood Charles F. Campana |
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| Affiliation: | Department of Chemistry, Texas A & M University, College Station, Tex. 77843, U.S.A;Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Mass. 02139, U.S.A.;Nicolet Magnetics, Fremont, Calif. 94539, U.S.A. |
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| Abstract: | Compounds of the type (μ3-S)(μ3-RP)Fe3(CO)9 have been prepared by the reaction of Fe3(CO)12 with [RP(S)S]2 or RP(S)Cl3. In this paper we report the synthesis of (μ3-S)(μ3-CH3OC6H4P)Fe3(CO)9 using Lawesson's reagents, and the three dimensional structure of (μ3-S)(μ3-p-CH3C6H4P)Fe3(CO)9. This material crystallizes in the space group P21/n with a = 8.558(2) Å, b = 9.022(2) Å, c = 27.506(6) Å, β = 95.40(2)°, Z = 4. The cluster is a nido structure as found commonly for (μ3-X)(μ3-Y)Fe3(CO)9 complexes. |
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| Keywords: | Authors to whom correspondence should be addressed. |
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