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Three Novel Gibberellins Produced by Gibberella fujikuroi
Authors:Noboru Murofushi  Masahiro Sugimoto  Kunio Itoh  Nobutaka Takahashi
Institution:1. Department of Agricultural Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo, Japan;2. Pharmaceutical Research Laboratory, Kyowa Hakko Co. Ltd., Shimotogari, Nagaizumi-machi, Sunto-gun, Shizuoka-ken, Japan
Abstract:Three novel gibberellins, GA54 (ent-1α, 3α, 10-trihydroxy-20-norgibberell-16-ene-7, 19-dioic acid 19, 10-lactone), GA55 (ent-1α, 3α, 10, 13-tetrahydroxy-20-norgibberell-16-ene-7, 19-dioic acid 19, 10-lactone) and GA56 (ent-2β, 3α, 10, 13-tetrahydroxy-20-norgibberell-16-ene-7, 19-dioic acid 19, 10-lactone) were shown to occur in the culture broth of Gibberella fujikuroi. Their structures were determined mainly by mass spectrometrical comparison of the derivatives with those of authentic compounds prepared from known gibberellins.
Keywords:L-rhamnosidase" target="_blank">α-L-rhamnosidase  Pichia angusta  aroma improvement  monoterpenol
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