Three new 5,10-epoxygermacranolides from Liatris chapmanii and Liatris gracilis |
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Authors: | Werner Herz Inger Wahlberg Charles S Stevens Palaiyur S Kalyanaraman |
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Institution: | Department of Chemistry, The Florida State University, Tallahassee, Florida 32306 U.S.A. |
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Abstract: | Examination of Liatris chapmanii (T + G) Kuntze led to the isolation of two new germacranolides, chapliatrin (1a) and isochapliatrin (1b). Liatris gracilis Pursh gave chapliatrin and acetylchapliatrin 1c). The stereochemistry assigned to C-3, C-4 and C-10 is tentative. All three compounds possess the hitherto-unreported 5,10-oxygen linkage. L. gracilis also gave the benzofuran euparin (2) and the flavones hispidulin (dinatin, 3a and 3′,6-dimethoxy-4′,5,7-trihydroxyflavone (3b). L. chapimanii also gave 5-hydroxy-3′,4′,6,7-tetramethoxyflavone (3c). |
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Keywords: | Compositae sesquiterpene lactones 5 10-epoxygermacranolides benzofuran euparin methylated flavones |
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