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Chiroptical properties of heterotrimetallic ‘wing-tip’ butterflies; synthesis and crystal structure of (μ-H)Ru2Fe2PdC(CO)12 (η-ß-C10H15) |
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| Authors: | S. P. Gubin A. P. Klyagina I. F. Golovaneva T. V. Galuzina O. A. Belyakova Ya. V. Zubavichus Yu. L. Slovokhotov |
| Affiliation: | a Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Ave., Moscow 117907, Russia b Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., Moscow 117813, Russia |
| Abstract: | HRu2Fe2PdC(CO)12 (η3-ß-C10H15) cluster was prepared in the reaction of (Et4N) [HFe2Ru2C(CO)12] with [Pd(η3-ß-C10H15)Cl]2. X-ray structural study of HRu2Fe2PdC(CO)12 (η3-ß-C10H15) (where ß-C10H15 is ß-pinenyl) revealed a wing-tip butterfly geometry of the metal core and (1R, 2S, 3S, 5R) absolute configuration for both crystallography independent molecules in the crystal. Chiroptical properties of this cluster are compared with other clusters containing a Pd(η3-ß-C10H15) fragment and discussed. |
| Keywords: | Crystal structures Ruthenium complexes Iron complexes Palladium complexes Carbide complexes Cluster complexes |
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