Cd(II)-NCS/NCO complexes of 1-alkyl-2-(arylazo)imidazole: Single crystal X-ray structure of [Cd(HaaiMe)2(SCN)2] |
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| Authors: | Kamal Krishna Sarker Atish Dipankar Jana Chittaranjan Sinha |
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| Affiliation: | a Department of Chemistry, Jadavpur University, Jadavpur, Raja Suboth Mullick Road, Kolkata, West Bengal 700 032, India
b Department of Physics, Jadavpur University, Jadavpur, Raja Suboth Mullick Road, Kolkata, West Bengal 700 032, India |
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| Abstract: | The reaction of Cd(OAc)2 · 4H2O and 1-alkyl-2-(arylazo)imidazole [RaaiR′ where R = H (a), Me (b); R′ = Me (1/3/5), Et (2/4/6)] and NH4NCS/NaNCO in methanol in 1:2:2 mole ratio has afforded [Cd(RaaiR′)2(NCS)2] (3, 4) and [Cd(RaaiR′)2(NCO)2] (5, 6) complexes. The complexes are characterized by different physicochemical methods and in one case, the structure was confirmed by single crystal X-ray diffraction study for title compounds. |
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| Keywords: | Arylazoimidazoles Cadmium(II) complexes Octahedral X-ray |
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